Synthesis and thermophysical properties of two new protic long-chain ionic liquids with the oleate anion
Autor(a) principal: | |
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Data de Publicação: | 2010 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFBA |
Texto Completo: | http://www.repositorio.ufba.br/ri/handle/ri/5593 |
Resumo: | Acesso restrito: Texto completo. p. 42-50. |
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Alvarez, Víctor H.Silva, Silvana Mattedi eMartin-Pastor, ManuelAznar, MartinDuro, Miguel Angel IglesiasAlvarez, Víctor H.Silva, Silvana Mattedi eMartin-Pastor, ManuelAznar, MartinDuro, Miguel Angel Iglesias2012-04-11T18:46:55Z2010-120378-3812http://www.repositorio.ufba.br/ri/handle/ri/5593v. 299, n. 1.Acesso restrito: Texto completo. p. 42-50.This work reports the synthesis of 2-hydroxy ethylammonium oleate and bis(2-hydroxy ethyl)ammonium oleate ionic liquids, which have a long aliphatic chain as well as the study of some of their physical properties, in particular the effect of temperature on their density, speed of sound, viscosity, and refractive index. 1H and 13C NMR spectra were used to characterize the chemical structure of the species in concordance with FT-IR spectra. DOSY NMR spectra were used to determine the self-diffusion coefficients of 2-hydroxy ethylammonium oleate ionic liquid, which were consistent with the formation of a lamellar or micellar liquid crystal phase; due the similar structure, a similar aggregation in the bis(2-hydroxy ethyl)ammonium oleate ionic liquid it is expected.Submitted by JURANDI DE SOUZA SILVA (jssufba@hotmail.com) on 2012-04-11T18:46:55Z No. of bitstreams: 1 __ac.els-cdn.com_S037838...0dfe6e4912bc01a3cd535479e22a9.pdf: 560799 bytes, checksum: c4346d52b99a775cb6f5fc1ced5912e9 (MD5)Made available in DSpace on 2012-04-11T18:46:55Z (GMT). No. of bitstreams: 1 __ac.els-cdn.com_S037838...0dfe6e4912bc01a3cd535479e22a9.pdf: 560799 bytes, checksum: c4346d52b99a775cb6f5fc1ced5912e9 (MD5) Previous issue date: 2010-12DOI: 10.1016/j.fluid.2010.08.022reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBAIonic liquidSynthesisThermodynamicsAggregation equilibriumSynthesis and thermophysical properties of two new protic long-chain ionic liquids with the oleate anionFluid Phase EquilibriaArtigo de Periódicoinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion10000-01-01enginfo:eu-repo/semantics/openAccessORIGINAL__ac.els-cdn.com_S037838...0dfe6e4912bc01a3cd535479e22a9.pdf__ac.els-cdn.com_S037838...0dfe6e4912bc01a3cd535479e22a9.pdfapplication/pdf560799https://repositorio.ufba.br/bitstream/ri/5593/1/__ac.els-cdn.com_S037838...0dfe6e4912bc01a3cd535479e22a9.pdfc4346d52b99a775cb6f5fc1ced5912e9MD51LICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/5593/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52TEXT__ac.els-cdn.com_S037838...0dfe6e4912bc01a3cd535479e22a9.pdf.txt__ac.els-cdn.com_S037838...0dfe6e4912bc01a3cd535479e22a9.pdf.txtExtracted texttext/plain35349https://repositorio.ufba.br/bitstream/ri/5593/3/__ac.els-cdn.com_S037838...0dfe6e4912bc01a3cd535479e22a9.pdf.txta2b7fe84012ee5691d5ae49ab69647e6MD53ri/55932022-08-26 11:47:05.934oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-08-26T14:47:05Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false |
dc.title.pt_BR.fl_str_mv |
Synthesis and thermophysical properties of two new protic long-chain ionic liquids with the oleate anion |
dc.title.alternative.pt_BR.fl_str_mv |
Fluid Phase Equilibria |
title |
Synthesis and thermophysical properties of two new protic long-chain ionic liquids with the oleate anion |
spellingShingle |
Synthesis and thermophysical properties of two new protic long-chain ionic liquids with the oleate anion Alvarez, Víctor H. Ionic liquid Synthesis Thermodynamics Aggregation equilibrium |
title_short |
Synthesis and thermophysical properties of two new protic long-chain ionic liquids with the oleate anion |
title_full |
Synthesis and thermophysical properties of two new protic long-chain ionic liquids with the oleate anion |
title_fullStr |
Synthesis and thermophysical properties of two new protic long-chain ionic liquids with the oleate anion |
title_full_unstemmed |
Synthesis and thermophysical properties of two new protic long-chain ionic liquids with the oleate anion |
title_sort |
Synthesis and thermophysical properties of two new protic long-chain ionic liquids with the oleate anion |
author |
Alvarez, Víctor H. |
author_facet |
Alvarez, Víctor H. Silva, Silvana Mattedi e Martin-Pastor, Manuel Aznar, Martin Duro, Miguel Angel Iglesias |
author_role |
author |
author2 |
Silva, Silvana Mattedi e Martin-Pastor, Manuel Aznar, Martin Duro, Miguel Angel Iglesias |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Alvarez, Víctor H. Silva, Silvana Mattedi e Martin-Pastor, Manuel Aznar, Martin Duro, Miguel Angel Iglesias Alvarez, Víctor H. Silva, Silvana Mattedi e Martin-Pastor, Manuel Aznar, Martin Duro, Miguel Angel Iglesias |
dc.subject.por.fl_str_mv |
Ionic liquid Synthesis Thermodynamics Aggregation equilibrium |
topic |
Ionic liquid Synthesis Thermodynamics Aggregation equilibrium |
description |
Acesso restrito: Texto completo. p. 42-50. |
publishDate |
2010 |
dc.date.issued.fl_str_mv |
2010-12 |
dc.date.accessioned.fl_str_mv |
2012-04-11T18:46:55Z |
dc.type.driver.fl_str_mv |
Artigo de Periódico info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.repositorio.ufba.br/ri/handle/ri/5593 |
dc.identifier.issn.none.fl_str_mv |
0378-3812 |
dc.identifier.number.pt_BR.fl_str_mv |
v. 299, n. 1. |
identifier_str_mv |
0378-3812 v. 299, n. 1. |
url |
http://www.repositorio.ufba.br/ri/handle/ri/5593 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.pt_BR.fl_str_mv |
DOI: 10.1016/j.fluid.2010.08.022 |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFBA instname:Universidade Federal da Bahia (UFBA) instacron:UFBA |
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Universidade Federal da Bahia (UFBA) |
instacron_str |
UFBA |
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UFBA |
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Repositório Institucional da UFBA |
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Repositório Institucional da UFBA |
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