Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) Less

Detalhes bibliográficos
Autor(a) principal: Martins, Larissa Rodrigues Jales
Data de Publicação: 2023
Tipo de documento: Trabalho de conclusão de curso
Idioma: por
Título da fonte: Repositório Institucional da Universidade Federal do Ceará (UFC)
Texto Completo: http://www.repositorio.ufc.br/handle/riufc/73969
Resumo: Egletes viscosa (L.) Less, belonging to the Asteraceae family, is a herb popularly known as macela-da-terra or macela-do-sertão that occurs spontaneously near dams and lakes in the northeastern hinterland. Its floral chapters are used in traditional medicine for gastrointestinal problems. This part of the plant also yields a very aromatic essential oil, which has aroused the interest of the aroma and fragrance industry. However, although the aerial part also produces essential oil, it does not have any commercial appeal. In view of the scarcity of chemical studies on the aerial part of E. viscosa, the objective of the present work was to determine the yield and the chemical composition of the essential oil of the aerial parts and to compare them to those of the floral capitula. The investigated material was cultivated under controlled conditions and harvested after 5 months of planting. The floral chapters were manually separated from the aerial part (leaves and branches), dried in an air circulation oven and submitted to hydrodistillation in a Clevenger type apparatus. Essential oils obtained from shoots (OE-EVPA) and floral capitula (OE-EVCF) were analyzed by Gas Chromatography coupled to Mass Spectrometry (GC-MS). EO-EVPA was constituted by 9 constituents, being 29.43% monoterpenes, 4.3% sesquiterpenes and 36.81% diterpenes, while EO-EVCF was constituted by 8 constituents, being 5.79% monoterpenes and 94.21 % of monoterpenoids. The major compound for OE-EVPA was 9-cis-retinal and for OE-EVCF was cis-isopinocarveyl. In each of the parts, a new compound for the species was identified, namely sylvestrene and 9-cis-retinal. The essential oil of chemotype B, rich in cis-isopinocarveyl acetate, presented a content of 4.74% (m/v) for the floral portion and 0.25% (m/v) for the leaf portion, a difference of 19 times. Based on this work, there was a significant difference in the profile and yield between the two plant organs, which may have been amplified by the attack of insect pests on the plant, especially in the aerial part. Therefore, new analyzes will be necessary to determine the chemical composition of the essential oil of the aerial part in healthy plants of E. viscosa and, thus, to evaluate its possibility of industrial use, such as the floral capitula.
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spelling Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) LessÓleo essencialEgletes viscosaAsteraceaeCG-EMAromaEgletes viscosa (L.) Less, belonging to the Asteraceae family, is a herb popularly known as macela-da-terra or macela-do-sertão that occurs spontaneously near dams and lakes in the northeastern hinterland. Its floral chapters are used in traditional medicine for gastrointestinal problems. This part of the plant also yields a very aromatic essential oil, which has aroused the interest of the aroma and fragrance industry. However, although the aerial part also produces essential oil, it does not have any commercial appeal. In view of the scarcity of chemical studies on the aerial part of E. viscosa, the objective of the present work was to determine the yield and the chemical composition of the essential oil of the aerial parts and to compare them to those of the floral capitula. The investigated material was cultivated under controlled conditions and harvested after 5 months of planting. The floral chapters were manually separated from the aerial part (leaves and branches), dried in an air circulation oven and submitted to hydrodistillation in a Clevenger type apparatus. Essential oils obtained from shoots (OE-EVPA) and floral capitula (OE-EVCF) were analyzed by Gas Chromatography coupled to Mass Spectrometry (GC-MS). EO-EVPA was constituted by 9 constituents, being 29.43% monoterpenes, 4.3% sesquiterpenes and 36.81% diterpenes, while EO-EVCF was constituted by 8 constituents, being 5.79% monoterpenes and 94.21 % of monoterpenoids. The major compound for OE-EVPA was 9-cis-retinal and for OE-EVCF was cis-isopinocarveyl. In each of the parts, a new compound for the species was identified, namely sylvestrene and 9-cis-retinal. The essential oil of chemotype B, rich in cis-isopinocarveyl acetate, presented a content of 4.74% (m/v) for the floral portion and 0.25% (m/v) for the leaf portion, a difference of 19 times. Based on this work, there was a significant difference in the profile and yield between the two plant organs, which may have been amplified by the attack of insect pests on the plant, especially in the aerial part. Therefore, new analyzes will be necessary to determine the chemical composition of the essential oil of the aerial part in healthy plants of E. viscosa and, thus, to evaluate its possibility of industrial use, such as the floral capitula.Egletes viscosa (L.) Less, pertencente à família Asteraceae, é uma erva conhecida popularmente como macela-da-terra ou macela-do-sertão que ocorre espontaneamente próximo a barragens e lagoas no sertão nordestino. Seus capítulos florais são utilizados na medicina tradicional para problemas gastrointestinais. Essa parte da planta também rende um óleo essencial muito aromático, que tem despertado o interesse da indústria de aroma e fragrâncias. Entretanto, apesar da parte aérea também produzir óleo essencial, ela não possui qualquer apelo comercial. Tendo em vista a escassez de estudos químicos sobre a parte aérea de E. viscosa, o objetivo do presente trabalho foi determinar o rendimento e a composição química do óleo essencial das partes aéreas e compará-los aos dos capítulos florais. O material investigado foi cultivado sob condições controladas e colhido com 5 meses de plantio. Os capítulos florais foram separados manualmente da parte aérea (folhas e galhos), secos em estufa de circulação de ar e submetidos à hidrodestilação em aparelho tipo Clevenger. Os óleos essenciais obtidos da parte aérea (OE-EVPA) e dos capítulos florais (OE-EVCF) foram analisados por Cromatografia Gasosa acoplada à Espectrometria de Massa (CG-EM). OE-EVPA foi constituídos por 9 constituintes, sendo 29,43% monoterpenos, 4,3% de sesquiterpenos e 36,81% de diterpenos, enquanto OE-EVCF foi constituído por 8 constituintes, sendo 5,79% monoterpenos e 94,21% de monoterpenóides. O composto majoritário para OE-EVPA foi o 9-cis-retinal e para OE-EVCF foi o cis-isopinocarveíla. Em cada uma das partes, foi identificado um composto inédito para a espécie, sendo eles o silvestreno e o 9-cis-retinal. O óleo essencial do quimiotipo B, rico em acetato de cis-isopinocarveíla, apresentou um teor de 4,74% (m/v) para a porção floral e de 0,25% (m/v) para a foliar, uma diferença de 19 vezes. Com base neste trabalho, evidenciou-se uma diferença significativa no perfil e no rendimento entre os dois órgãos vegetais, que pode ter sido amplificada pelo ataque de insetos-praga à planta, especialmente na parte aérea. Por isso, novas análises serão necessárias para se determinar a composição química do óleo essencial da parte aérea em plantas sadias de E. viscosa e, assim, avaliar sua possibilidade de aproveitamento industrial, tal como os capítulos florais.Barbosa, Francisco GeraldoCanuto, Kirley MarquesMartins, Larissa Rodrigues Jales2023-08-11T20:54:23Z2023-08-11T20:54:23Z2023info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/bachelorThesisapplication/pdfMARTINS, Larissa Rodrigues Jales. Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) Less. 2023. 70 f. Trabalho de Conclusão de Curso (Bacharelado em Química) - Universidade Federal do Ceará, Fortaleza, 2023.http://www.repositorio.ufc.br/handle/riufc/73969porreponame:Repositório Institucional da Universidade Federal do Ceará (UFC)instname:Universidade Federal do Ceará (UFC)instacron:UFCinfo:eu-repo/semantics/openAccess2023-08-11T20:54:42Zoai:repositorio.ufc.br:riufc/73969Repositório InstitucionalPUBhttp://www.repositorio.ufc.br/ri-oai/requestbu@ufc.br || repositorio@ufc.bropendoar:2023-08-11T20:54:42Repositório Institucional da Universidade Federal do Ceará (UFC) - Universidade Federal do Ceará (UFC)false
dc.title.none.fl_str_mv Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) Less
title Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) Less
spellingShingle Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) Less
Martins, Larissa Rodrigues Jales
Óleo essencial
Egletes viscosa
Asteraceae
CG-EM
Aroma
title_short Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) Less
title_full Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) Less
title_fullStr Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) Less
title_full_unstemmed Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) Less
title_sort Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) Less
author Martins, Larissa Rodrigues Jales
author_facet Martins, Larissa Rodrigues Jales
author_role author
dc.contributor.none.fl_str_mv Barbosa, Francisco Geraldo
Canuto, Kirley Marques
dc.contributor.author.fl_str_mv Martins, Larissa Rodrigues Jales
dc.subject.por.fl_str_mv Óleo essencial
Egletes viscosa
Asteraceae
CG-EM
Aroma
topic Óleo essencial
Egletes viscosa
Asteraceae
CG-EM
Aroma
description Egletes viscosa (L.) Less, belonging to the Asteraceae family, is a herb popularly known as macela-da-terra or macela-do-sertão that occurs spontaneously near dams and lakes in the northeastern hinterland. Its floral chapters are used in traditional medicine for gastrointestinal problems. This part of the plant also yields a very aromatic essential oil, which has aroused the interest of the aroma and fragrance industry. However, although the aerial part also produces essential oil, it does not have any commercial appeal. In view of the scarcity of chemical studies on the aerial part of E. viscosa, the objective of the present work was to determine the yield and the chemical composition of the essential oil of the aerial parts and to compare them to those of the floral capitula. The investigated material was cultivated under controlled conditions and harvested after 5 months of planting. The floral chapters were manually separated from the aerial part (leaves and branches), dried in an air circulation oven and submitted to hydrodistillation in a Clevenger type apparatus. Essential oils obtained from shoots (OE-EVPA) and floral capitula (OE-EVCF) were analyzed by Gas Chromatography coupled to Mass Spectrometry (GC-MS). EO-EVPA was constituted by 9 constituents, being 29.43% monoterpenes, 4.3% sesquiterpenes and 36.81% diterpenes, while EO-EVCF was constituted by 8 constituents, being 5.79% monoterpenes and 94.21 % of monoterpenoids. The major compound for OE-EVPA was 9-cis-retinal and for OE-EVCF was cis-isopinocarveyl. In each of the parts, a new compound for the species was identified, namely sylvestrene and 9-cis-retinal. The essential oil of chemotype B, rich in cis-isopinocarveyl acetate, presented a content of 4.74% (m/v) for the floral portion and 0.25% (m/v) for the leaf portion, a difference of 19 times. Based on this work, there was a significant difference in the profile and yield between the two plant organs, which may have been amplified by the attack of insect pests on the plant, especially in the aerial part. Therefore, new analyzes will be necessary to determine the chemical composition of the essential oil of the aerial part in healthy plants of E. viscosa and, thus, to evaluate its possibility of industrial use, such as the floral capitula.
publishDate 2023
dc.date.none.fl_str_mv 2023-08-11T20:54:23Z
2023-08-11T20:54:23Z
2023
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/bachelorThesis
format bachelorThesis
status_str publishedVersion
dc.identifier.uri.fl_str_mv MARTINS, Larissa Rodrigues Jales. Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) Less. 2023. 70 f. Trabalho de Conclusão de Curso (Bacharelado em Química) - Universidade Federal do Ceará, Fortaleza, 2023.
http://www.repositorio.ufc.br/handle/riufc/73969
identifier_str_mv MARTINS, Larissa Rodrigues Jales. Estudo químico do óleo essencial da parte aérea de Egletes viscosa (L.) Less. 2023. 70 f. Trabalho de Conclusão de Curso (Bacharelado em Química) - Universidade Federal do Ceará, Fortaleza, 2023.
url http://www.repositorio.ufc.br/handle/riufc/73969
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dc.source.none.fl_str_mv reponame:Repositório Institucional da Universidade Federal do Ceará (UFC)
instname:Universidade Federal do Ceará (UFC)
instacron:UFC
instname_str Universidade Federal do Ceará (UFC)
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institution UFC
reponame_str Repositório Institucional da Universidade Federal do Ceará (UFC)
collection Repositório Institucional da Universidade Federal do Ceará (UFC)
repository.name.fl_str_mv Repositório Institucional da Universidade Federal do Ceará (UFC) - Universidade Federal do Ceará (UFC)
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