Study of liquid-liquid extraction for methyl biodiesel purification process

Detalhes bibliográficos
Autor(a) principal: Regiane Silva Pinheiro
Data de Publicação: 2013
Tipo de documento: Dissertação
Idioma: por
Título da fonte: Biblioteca Digital de Teses e Dissertações da UFC
Texto Completo: http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=14103
Resumo: In the process of purification of biodiesel is of extreme importance washing methyl or ethyl ester rich- phase, since in conventional processes there is a great amount of water. During the washing is extracted primarily excess alcohol. Composition data for the washing process of biodiesel is still scarce in the literature and the study of liquid-liquid equilibrium provides the means to develop equipment and to optimize the extraction processes. Thus the main goal of this work is to determine equilibrium data for three different ternary systems: water - methanol - soybean biodiesel; corn biodiesel â methanol â water; methanol - coconut biodiesel - water at 20 Â C and 40 Â C. The experiments were carried out in equilibrium cells where the temperature was kept constant by thermostat control. The experimental determination was made by the method of densimetry. The consistency of data obtained for the tie lines was verified by correlations. It was verified by the ternary graphs, little influence of temperature on the systems studied. The equilibrium data were correlated liquid-liquid models for the activity coefficient NRTL, UNIQUAC and UNIFAC and proved quite satisfactory.
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spelling info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisStudy of liquid-liquid extraction for methyl biodiesel purification processEstudo da extraÃÃo lÃquido-lÃquido para o processo de purificaÃÃo de biodiesel metÃlico2013-02-22RÃlvia Saraiva de Santiago Aguiar83900098387Hosiberto Batista de Sant'Ana55184820434MÃnica Castelo GuimarÃes Albuquerque76062929300http://lattes.cnpq.br/6879360000944259Silvana Mattedi35424010563http://lattes.cnpq.br/874112436424607502519236302http://lattes.cnpq.br/3444570605688961Regiane Silva PinheiroUniversidade Federal do CearÃPrograma de PÃs-GraduaÃÃo em Engenharia QuÃmicaUFCBR Biodiesel ÃguaBiodiesel waterliquid-liquid equilibriumENGENHARIA QUIMICAIn the process of purification of biodiesel is of extreme importance washing methyl or ethyl ester rich- phase, since in conventional processes there is a great amount of water. During the washing is extracted primarily excess alcohol. Composition data for the washing process of biodiesel is still scarce in the literature and the study of liquid-liquid equilibrium provides the means to develop equipment and to optimize the extraction processes. Thus the main goal of this work is to determine equilibrium data for three different ternary systems: water - methanol - soybean biodiesel; corn biodiesel â methanol â water; methanol - coconut biodiesel - water at 20  C and 40  C. The experiments were carried out in equilibrium cells where the temperature was kept constant by thermostat control. The experimental determination was made by the method of densimetry. The consistency of data obtained for the tie lines was verified by correlations. It was verified by the ternary graphs, little influence of temperature on the systems studied. The equilibrium data were correlated liquid-liquid models for the activity coefficient NRTL, UNIQUAC and UNIFAC and proved quite satisfactory. No processo de purificaÃÃo do biodiesel, a lavagem da fase rica em metil ou etil Ãster à de extrema importÃncia, visto que nos processos convencionais hà um grande gasto de Ãgua. Durante a lavagem à extraÃdo principalmente Ãlcool em excesso. Dados de composiÃÃes para a lavagem de biodiesel ainda sÃo escassos na literatura e o estudo do equilÃbrio lÃquido-lÃquido pode fornecer meios para o desenvolvimento de equipamentos e otimizaÃÃo dos processos de extraÃÃo. Dessa forma, o principal objetivo dessa dissertaÃÃo foi determinar dados de equilÃbrio lÃquido- lÃquido para os sistemas ternÃrios contendo biodiesel de soja + metanol + Ãgua, biodiesel de milho + metanol e Ãgua e biodiesel de coco + metanol + Ãgua, a 20 ÂC e 40 ÂC. Os experimentos foram feitos em cÃlulas de equilÃbrio mantendo a temperatura constante. A determinaÃÃo experimental das misturas ternÃrias foi feita pelos mÃtodos de titulaÃÃo e densimetria. A consistÃncia dos dados das linhas de amarraÃÃo foi verificada pelas correlaÃÃes de Othmer-Tobias e Hand. Verificou-se por meio de grÃficos ternÃrios, pouca influÃncia da temperatura sobre os sistemas estudados. Os dados de equilÃbrio lÃquido-lÃquido foram correlacionados pelos modelos para coeficiente de atividade NRTL, UNIQUAC e UNIFAC e mostraram-se bastante satisfatÃrios.CoordenaÃÃo de AperfeÃoamento de Pessoal de NÃvel Superior http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=14103application/pdfinfo:eu-repo/semantics/openAccessporreponame:Biblioteca Digital de Teses e Dissertações da UFCinstname:Universidade Federal do Cearáinstacron:UFC2019-01-21T11:27:18Zmail@mail.com -
dc.title.en.fl_str_mv Study of liquid-liquid extraction for methyl biodiesel purification process
dc.title.alternative.pt.fl_str_mv Estudo da extraÃÃo lÃquido-lÃquido para o processo de purificaÃÃo de biodiesel metÃlico
title Study of liquid-liquid extraction for methyl biodiesel purification process
spellingShingle Study of liquid-liquid extraction for methyl biodiesel purification process
Regiane Silva Pinheiro
Biodiesel
Ãgua
Biodiesel
water
liquid-liquid equilibrium
ENGENHARIA QUIMICA
title_short Study of liquid-liquid extraction for methyl biodiesel purification process
title_full Study of liquid-liquid extraction for methyl biodiesel purification process
title_fullStr Study of liquid-liquid extraction for methyl biodiesel purification process
title_full_unstemmed Study of liquid-liquid extraction for methyl biodiesel purification process
title_sort Study of liquid-liquid extraction for methyl biodiesel purification process
author Regiane Silva Pinheiro
author_facet Regiane Silva Pinheiro
author_role author
dc.contributor.advisor1.fl_str_mv RÃlvia Saraiva de Santiago Aguiar
dc.contributor.advisor1ID.fl_str_mv 83900098387
dc.contributor.advisor-co1.fl_str_mv Hosiberto Batista de Sant'Ana
dc.contributor.advisor-co1ID.fl_str_mv 55184820434
dc.contributor.referee1.fl_str_mv MÃnica Castelo GuimarÃes Albuquerque
dc.contributor.referee1ID.fl_str_mv 76062929300
dc.contributor.referee1Lattes.fl_str_mv http://lattes.cnpq.br/6879360000944259
dc.contributor.referee2.fl_str_mv Silvana Mattedi
dc.contributor.referee2ID.fl_str_mv 35424010563
dc.contributor.referee2Lattes.fl_str_mv http://lattes.cnpq.br/8741124364246075
dc.contributor.authorID.fl_str_mv 02519236302
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/3444570605688961
dc.contributor.author.fl_str_mv Regiane Silva Pinheiro
contributor_str_mv RÃlvia Saraiva de Santiago Aguiar
Hosiberto Batista de Sant'Ana
MÃnica Castelo GuimarÃes Albuquerque
Silvana Mattedi
dc.subject.por.fl_str_mv Biodiesel
Ãgua
topic Biodiesel
Ãgua
Biodiesel
water
liquid-liquid equilibrium
ENGENHARIA QUIMICA
dc.subject.eng.fl_str_mv Biodiesel
water
liquid-liquid equilibrium
dc.subject.cnpq.fl_str_mv ENGENHARIA QUIMICA
dc.description.sponsorship.fl_txt_mv CoordenaÃÃo de AperfeÃoamento de Pessoal de NÃvel Superior
dc.description.abstract.por.fl_txt_mv In the process of purification of biodiesel is of extreme importance washing methyl or ethyl ester rich- phase, since in conventional processes there is a great amount of water. During the washing is extracted primarily excess alcohol. Composition data for the washing process of biodiesel is still scarce in the literature and the study of liquid-liquid equilibrium provides the means to develop equipment and to optimize the extraction processes. Thus the main goal of this work is to determine equilibrium data for three different ternary systems: water - methanol - soybean biodiesel; corn biodiesel â methanol â water; methanol - coconut biodiesel - water at 20 Â C and 40 Â C. The experiments were carried out in equilibrium cells where the temperature was kept constant by thermostat control. The experimental determination was made by the method of densimetry. The consistency of data obtained for the tie lines was verified by correlations. It was verified by the ternary graphs, little influence of temperature on the systems studied. The equilibrium data were correlated liquid-liquid models for the activity coefficient NRTL, UNIQUAC and UNIFAC and proved quite satisfactory.
No processo de purificaÃÃo do biodiesel, a lavagem da fase rica em metil ou etil Ãster à de extrema importÃncia, visto que nos processos convencionais hà um grande gasto de Ãgua. Durante a lavagem à extraÃdo principalmente Ãlcool em excesso. Dados de composiÃÃes para a lavagem de biodiesel ainda sÃo escassos na literatura e o estudo do equilÃbrio lÃquido-lÃquido pode fornecer meios para o desenvolvimento de equipamentos e otimizaÃÃo dos processos de extraÃÃo. Dessa forma, o principal objetivo dessa dissertaÃÃo foi determinar dados de equilÃbrio lÃquido- lÃquido para os sistemas ternÃrios contendo biodiesel de soja + metanol + Ãgua, biodiesel de milho + metanol e Ãgua e biodiesel de coco + metanol + Ãgua, a 20 ÂC e 40 ÂC. Os experimentos foram feitos em cÃlulas de equilÃbrio mantendo a temperatura constante. A determinaÃÃo experimental das misturas ternÃrias foi feita pelos mÃtodos de titulaÃÃo e densimetria. A consistÃncia dos dados das linhas de amarraÃÃo foi verificada pelas correlaÃÃes de Othmer-Tobias e Hand. Verificou-se por meio de grÃficos ternÃrios, pouca influÃncia da temperatura sobre os sistemas estudados. Os dados de equilÃbrio lÃquido-lÃquido foram correlacionados pelos modelos para coeficiente de atividade NRTL, UNIQUAC e UNIFAC e mostraram-se bastante satisfatÃrios.
description In the process of purification of biodiesel is of extreme importance washing methyl or ethyl ester rich- phase, since in conventional processes there is a great amount of water. During the washing is extracted primarily excess alcohol. Composition data for the washing process of biodiesel is still scarce in the literature and the study of liquid-liquid equilibrium provides the means to develop equipment and to optimize the extraction processes. Thus the main goal of this work is to determine equilibrium data for three different ternary systems: water - methanol - soybean biodiesel; corn biodiesel â methanol â water; methanol - coconut biodiesel - water at 20 Â C and 40 Â C. The experiments were carried out in equilibrium cells where the temperature was kept constant by thermostat control. The experimental determination was made by the method of densimetry. The consistency of data obtained for the tie lines was verified by correlations. It was verified by the ternary graphs, little influence of temperature on the systems studied. The equilibrium data were correlated liquid-liquid models for the activity coefficient NRTL, UNIQUAC and UNIFAC and proved quite satisfactory.
publishDate 2013
dc.date.issued.fl_str_mv 2013-02-22
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/masterThesis
status_str publishedVersion
format masterThesis
dc.identifier.uri.fl_str_mv http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=14103
url http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=14103
dc.language.iso.fl_str_mv por
language por
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal do CearÃ
dc.publisher.program.fl_str_mv Programa de PÃs-GraduaÃÃo em Engenharia QuÃmica
dc.publisher.initials.fl_str_mv UFC
dc.publisher.country.fl_str_mv BR
publisher.none.fl_str_mv Universidade Federal do CearÃ
dc.source.none.fl_str_mv reponame:Biblioteca Digital de Teses e Dissertações da UFC
instname:Universidade Federal do Ceará
instacron:UFC
reponame_str Biblioteca Digital de Teses e Dissertações da UFC
collection Biblioteca Digital de Teses e Dissertações da UFC
instname_str Universidade Federal do Ceará
instacron_str UFC
institution UFC
repository.name.fl_str_mv -
repository.mail.fl_str_mv mail@mail.com
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