Fine Fraction of Iron Ore Tailings as Mineral Addition in Self-Compacting Mixtures
Autor(a) principal: | |
---|---|
Data de Publicação: | 2024 |
Tipo de documento: | Dissertação |
Idioma: | eng |
Título da fonte: | Repositório Institucional da Universidade Federal do Espírito Santo (riUfes) |
Texto Completo: | http://repositorio.ufes.br/handle/10/17443 |
Resumo: | Global mining generates approximately 60 billion tons of waste each year, mostly stored in tailings dams, causing environmental damage and threatening nearby communities. To address this issue in alignment with circular economy principles, this study explored using the fine fraction of iron ore tailings (<0.075 mm) as a mineral addition for producing self-compacting mixtures, which require a substantial fines content. The study assessed mortars with 10%, 20%, and 30% mining filler (MF) replacing cement, comparing them to equivalent limestone filler (LF) mixtures and a reference without additives. The properties of the additions were assessed using X-ray diffraction, X-ray fluorescence, laser granulometry, scanning electron microscopy, methylene blue test, R3 test, and furnace-based gravimetry test. Fresh state analysis on mortars included specific gravity, flow table, and mini V-funnel tests. In the hardened state, tests covered compressive and flexural strength, ultrasonic pulse velocity, porosity, scanning electron microscopy, and mercury intrusion porosimetry (MIP). Isothermal calorimetry was also conducted on pastes to evaluate the cement hydration kinetics. It was found that the additions anticipated the induction period compared to the reference, with minimal impact on its duration. Otherwise, the heat release was most affected, with LF increasing it by 8%, 14%, and 17% at 10%, 20%, and 30% content, and MF rising it by 9%, 13%, and 22%. Mortars with additions showed improved spreading compared to the reference, with MF enhancing it by approximately 8%, 10%, and 15% at 10%, 20%, and 30% replacements, surpassing limestone filler at the same levels. MF, at 10%, 20%, and 30% replacements, reduced V-funnel times by around 30%, 31%, and 27% respectively compared to LF. At 28 days, mortars with MF showed around 6%, 4%, and 2% higher compressive strength than mLF at 10%, 20%, and 30% substitutions respectively. The mortar with 20% of MF incorporation had a cement index almost 13% lower than the reference mixture, implying a reduction of 65 kg of cement and the incorporation of 133 kg of tailing for a mortar with a strength of 50 MPa. MIP results showed that this same mixture had a pore volume >200 nm 50% smaller than that with 20% of LF, with a slightly lower total porosity. Overall, the use of the fine fraction of iron ore tailings as mineral addition in self-compacting mixtures is feasible for contents up to 30% and environmentally advantageous compared to the use of LF. |
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124Schankoski, Rudiele Aparecidahttps://orcid.org/0000-0003-1306-3986http://lattes.cnpq.br/3391191554375710Cipriano, Marcelly Pires de Sousa Ramoshttps://orcid.org/0000-0002-1106-1787http://lattes.cnpq.br/3168058256380210Oliveira, Alexandre Lima dehttps://orcid.org/0000-0002-1908-6479http://lattes.cnpq.br/6588306695770934Bezerra, Augusto Cesar da Silvahttps://orcid.org/0000-0003-1670-2376http://lattes.cnpq.br/0783179484317105Matos, Paulo Ricardo dehttps://orcid.org/0000-0002-3695-1356http://lattes.cnpq.br/51220299728167672024-06-21T11:17:11Z2024-06-21T11:17:11Z2024-02-08Global mining generates approximately 60 billion tons of waste each year, mostly stored in tailings dams, causing environmental damage and threatening nearby communities. To address this issue in alignment with circular economy principles, this study explored using the fine fraction of iron ore tailings (<0.075 mm) as a mineral addition for producing self-compacting mixtures, which require a substantial fines content. The study assessed mortars with 10%, 20%, and 30% mining filler (MF) replacing cement, comparing them to equivalent limestone filler (LF) mixtures and a reference without additives. The properties of the additions were assessed using X-ray diffraction, X-ray fluorescence, laser granulometry, scanning electron microscopy, methylene blue test, R3 test, and furnace-based gravimetry test. Fresh state analysis on mortars included specific gravity, flow table, and mini V-funnel tests. In the hardened state, tests covered compressive and flexural strength, ultrasonic pulse velocity, porosity, scanning electron microscopy, and mercury intrusion porosimetry (MIP). Isothermal calorimetry was also conducted on pastes to evaluate the cement hydration kinetics. It was found that the additions anticipated the induction period compared to the reference, with minimal impact on its duration. Otherwise, the heat release was most affected, with LF increasing it by 8%, 14%, and 17% at 10%, 20%, and 30% content, and MF rising it by 9%, 13%, and 22%. Mortars with additions showed improved spreading compared to the reference, with MF enhancing it by approximately 8%, 10%, and 15% at 10%, 20%, and 30% replacements, surpassing limestone filler at the same levels. MF, at 10%, 20%, and 30% replacements, reduced V-funnel times by around 30%, 31%, and 27% respectively compared to LF. At 28 days, mortars with MF showed around 6%, 4%, and 2% higher compressive strength than mLF at 10%, 20%, and 30% substitutions respectively. The mortar with 20% of MF incorporation had a cement index almost 13% lower than the reference mixture, implying a reduction of 65 kg of cement and the incorporation of 133 kg of tailing for a mortar with a strength of 50 MPa. MIP results showed that this same mixture had a pore volume >200 nm 50% smaller than that with 20% of LF, with a slightly lower total porosity. Overall, the use of the fine fraction of iron ore tailings as mineral addition in self-compacting mixtures is feasible for contents up to 30% and environmentally advantageous compared to the use of LF.resumoFAPESTexthttp://repositorio.ufes.br/handle/10/17443engenUniversidade Federal do Espírito SantoMestrado em Engenharia CivilPrograma de Pós-Graduação Engenharia Civil UFESBRCentro Tecnológicosubject.br-rjbnÁrea(s) do conhecimento do documento (Tabela CNPq)Iron ore tailingself-compacting mortarssupplementary cementitious materialmechanical propertiesworkabilitysustainabilityFine Fraction of Iron Ore Tailings as Mineral Addition in Self-Compacting Mixturestitle.alternativeinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da Universidade Federal do Espírito Santo (riUfes)instname:Universidade Federal do Espírito Santo (UFES)instacron:UFESemail@ufes.brORIGINALMarcellyPiresdeSousaRamosCipriano-2024-dissertacao.pdfMarcellyPiresdeSousaRamosCipriano-2024-dissertacao.pdfapplication/pdf5842841http://repositorio.ufes.br/bitstreams/b93ea83a-8481-41e3-a561-30ba106efaa6/download2ddab6ddc6b372a93928d9576fd86714MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://repositorio.ufes.br/bitstreams/16fce643-ab3f-42a7-81cf-b5ff41704054/download8a4605be74aa9ea9d79846c1fba20a33MD5210/174432024-08-29 11:25:08.826oai:repositorio.ufes.br:10/17443http://repositorio.ufes.brRepositório InstitucionalPUBhttp://repositorio.ufes.br/oai/requestopendoar:21082024-10-15T17:59:11.582067Repositório Institucional da Universidade Federal do Espírito Santo (riUfes) - Universidade Federal do Espírito Santo (UFES)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 |
dc.title.none.fl_str_mv |
Fine Fraction of Iron Ore Tailings as Mineral Addition in Self-Compacting Mixtures |
dc.title.alternative.none.fl_str_mv |
title.alternative |
title |
Fine Fraction of Iron Ore Tailings as Mineral Addition in Self-Compacting Mixtures |
spellingShingle |
Fine Fraction of Iron Ore Tailings as Mineral Addition in Self-Compacting Mixtures Cipriano, Marcelly Pires de Sousa Ramos Área(s) do conhecimento do documento (Tabela CNPq) Iron ore tailing self-compacting mortars supplementary cementitious material mechanical properties workability sustainability subject.br-rjbn |
title_short |
Fine Fraction of Iron Ore Tailings as Mineral Addition in Self-Compacting Mixtures |
title_full |
Fine Fraction of Iron Ore Tailings as Mineral Addition in Self-Compacting Mixtures |
title_fullStr |
Fine Fraction of Iron Ore Tailings as Mineral Addition in Self-Compacting Mixtures |
title_full_unstemmed |
Fine Fraction of Iron Ore Tailings as Mineral Addition in Self-Compacting Mixtures |
title_sort |
Fine Fraction of Iron Ore Tailings as Mineral Addition in Self-Compacting Mixtures |
author |
Cipriano, Marcelly Pires de Sousa Ramos |
author_facet |
Cipriano, Marcelly Pires de Sousa Ramos |
author_role |
author |
dc.contributor.authorID.none.fl_str_mv |
https://orcid.org/0000-0002-1106-1787 |
dc.contributor.authorLattes.none.fl_str_mv |
http://lattes.cnpq.br/3168058256380210 |
dc.contributor.advisor1.fl_str_mv |
Schankoski, Rudiele Aparecida |
dc.contributor.advisor1ID.fl_str_mv |
https://orcid.org/0000-0003-1306-3986 |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/3391191554375710 |
dc.contributor.author.fl_str_mv |
Cipriano, Marcelly Pires de Sousa Ramos |
dc.contributor.referee1.fl_str_mv |
Oliveira, Alexandre Lima de |
dc.contributor.referee1ID.fl_str_mv |
https://orcid.org/0000-0002-1908-6479 |
dc.contributor.referee1Lattes.fl_str_mv |
http://lattes.cnpq.br/6588306695770934 |
dc.contributor.referee2.fl_str_mv |
Bezerra, Augusto Cesar da Silva |
dc.contributor.referee2ID.fl_str_mv |
https://orcid.org/0000-0003-1670-2376 |
dc.contributor.referee2Lattes.fl_str_mv |
http://lattes.cnpq.br/0783179484317105 |
dc.contributor.referee3.fl_str_mv |
Matos, Paulo Ricardo de |
dc.contributor.referee3ID.fl_str_mv |
https://orcid.org/0000-0002-3695-1356 |
dc.contributor.referee3Lattes.fl_str_mv |
http://lattes.cnpq.br/5122029972816767 |
contributor_str_mv |
Schankoski, Rudiele Aparecida Oliveira, Alexandre Lima de Bezerra, Augusto Cesar da Silva Matos, Paulo Ricardo de |
dc.subject.cnpq.fl_str_mv |
Área(s) do conhecimento do documento (Tabela CNPq) |
topic |
Área(s) do conhecimento do documento (Tabela CNPq) Iron ore tailing self-compacting mortars supplementary cementitious material mechanical properties workability sustainability subject.br-rjbn |
dc.subject.por.fl_str_mv |
Iron ore tailing self-compacting mortars supplementary cementitious material mechanical properties workability sustainability |
dc.subject.br-rjbn.none.fl_str_mv |
subject.br-rjbn |
description |
Global mining generates approximately 60 billion tons of waste each year, mostly stored in tailings dams, causing environmental damage and threatening nearby communities. To address this issue in alignment with circular economy principles, this study explored using the fine fraction of iron ore tailings (<0.075 mm) as a mineral addition for producing self-compacting mixtures, which require a substantial fines content. The study assessed mortars with 10%, 20%, and 30% mining filler (MF) replacing cement, comparing them to equivalent limestone filler (LF) mixtures and a reference without additives. The properties of the additions were assessed using X-ray diffraction, X-ray fluorescence, laser granulometry, scanning electron microscopy, methylene blue test, R3 test, and furnace-based gravimetry test. Fresh state analysis on mortars included specific gravity, flow table, and mini V-funnel tests. In the hardened state, tests covered compressive and flexural strength, ultrasonic pulse velocity, porosity, scanning electron microscopy, and mercury intrusion porosimetry (MIP). Isothermal calorimetry was also conducted on pastes to evaluate the cement hydration kinetics. It was found that the additions anticipated the induction period compared to the reference, with minimal impact on its duration. Otherwise, the heat release was most affected, with LF increasing it by 8%, 14%, and 17% at 10%, 20%, and 30% content, and MF rising it by 9%, 13%, and 22%. Mortars with additions showed improved spreading compared to the reference, with MF enhancing it by approximately 8%, 10%, and 15% at 10%, 20%, and 30% replacements, surpassing limestone filler at the same levels. MF, at 10%, 20%, and 30% replacements, reduced V-funnel times by around 30%, 31%, and 27% respectively compared to LF. At 28 days, mortars with MF showed around 6%, 4%, and 2% higher compressive strength than mLF at 10%, 20%, and 30% substitutions respectively. The mortar with 20% of MF incorporation had a cement index almost 13% lower than the reference mixture, implying a reduction of 65 kg of cement and the incorporation of 133 kg of tailing for a mortar with a strength of 50 MPa. MIP results showed that this same mixture had a pore volume >200 nm 50% smaller than that with 20% of LF, with a slightly lower total porosity. Overall, the use of the fine fraction of iron ore tailings as mineral addition in self-compacting mixtures is feasible for contents up to 30% and environmentally advantageous compared to the use of LF. |
publishDate |
2024 |
dc.date.accessioned.fl_str_mv |
2024-06-21T11:17:11Z |
dc.date.available.fl_str_mv |
2024-06-21T11:17:11Z |
dc.date.issued.fl_str_mv |
2024-02-08 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/masterThesis |
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masterThesis |
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http://repositorio.ufes.br/handle/10/17443 |
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eng en |
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eng |
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en |
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openAccess |
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Text |
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Universidade Federal do Espírito Santo Mestrado em Engenharia Civil |
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Programa de Pós-Graduação Engenharia Civil |
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UFES |
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BR |
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Centro Tecnológico |
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Universidade Federal do Espírito Santo Mestrado em Engenharia Civil |
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