Avaliação da remoção de bisfenol-a por adsorção em carvão ativado produzido da borra de café
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Tipo de documento: | Dissertação |
Idioma: | por |
Título da fonte: | Repositório Institucional da UFG |
Texto Completo: | http://repositorio.bc.ufg.br/tede/handle/tede/8390 |
Resumo: | Bisphenol-A (BPA) is an emerging pollutant potentially capable of interfering with the endocrine system of living things. Employed mainly in the industry, in the production of resins, packaging and polycarbonate monomers, its main sources in the environment are effluent discharges. Since the conventional treatment systems used in Brazil can’t remove a series of pollutants, the use of activated carbon is one of the alternatives fairly used for this purpose. Its production from alternative materials is becoming more and more frequent, as agroindustrial wastes, object of numerous studies of the production of activated carbon. The coffee grounds are one of these residues that has been used generating good carbonaceous adsorbents. Thus, the objective of this work was to evaluate the efficiency of the activated carbon produced from the coffee grounds, in the adsorption of BPA in aqueous medium. Water vapor (CAH), KOH (CAK), K2CO3 (CAKC) and ZnCl2 (CAZn) were used as the activating agente characterized by analysis of X-ray diffraction (XRD), Fourier transform infrared (FTIR), N2 adsorption and desorption, elemental composition (CHNS-O) and determination of zero charge potential. For the selection of the best coal, a preliminary adsorption test was carried out with the adsorbents produced, with the coffee grounds and a commercial coal for comparative purposes. The effect of the initial pH of the solution was also evaluated. The kinetic adsorption studies at the concentrations of 5, 20 and 30 mg/L of BPA were adjusted to the pseudo-firstorder and pseudo-second order models. The nature of the process was studied by the Langmuir and Freundlich isotherm models. Among the developed coals, the CAK and CAKC presented low production yield and were not submitted to the adsorption tests. The CHNS-O, XRD, FTIR and N2 adsorption/desorption analyzes of CAH and CAZn generated results close to those reported in the literature. In terms of specific surface area, the CAH proved to be out of the expected. The CAZn had an area of 1,038.51 m²/g. Of the materials tested, the CAH didn’t present adsorptive capacity, while the CAZn was the one with the best performance, with little variation in efficiency when the pH of the medium changed. The use of coffee grounds as bioadsorbent wasn’t promising, being 86 percentage points below the efficiency of CAZn. Adsorption kinetics revealed a relatively slow process at the concentrations studied, reaching equilibrium after 720 minutes. The kinetic data for the three systems presented a fractional order close to 2, thus indicating a better fit for the pseudo-second order model. The equilibrium data were better adjusted to the Langmuir model, assuming that the CAZn has a homogeneous surface with adsorption occurring in monolayer. The maximum adsorption capacity of BPA according to the same model was 123.22 mg/g. The results showed that CAZn can be considered a promising promoter in the removal of BPA, indicating coffee grounds as an alternative raw material for the production of activated carbon with the potential to remove emerging pollutants such as BPA in water. |
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Scalize, Paulo Sérgiohttp://lattes.cnpq.br/0957896448117207Oliveira, Sérgio Botelho dehttp://lattes.cnpq.br/3447406257464639Scalize, Paulo SérgioOstroski, Indianara ConceiçãoGil, Eric de Souzahttp://lattes.cnpq.br/2481528027682306Alves, Andreia Cristina Fonseca2018-04-26T11:17:44Z2018-02-26ALVES, A. C. F. Avaliação da remoção de bisfenol-a por adsorção em carvão ativado produzido da borra de café. 2018. 71 f. Dissertação (Mestrado em Engenharia Ambiental e Sanitária) - Universidade Federal de Goiás, Goiânia, 2018.http://repositorio.bc.ufg.br/tede/handle/tede/8390ark:/38995/0013000001567Bisphenol-A (BPA) is an emerging pollutant potentially capable of interfering with the endocrine system of living things. Employed mainly in the industry, in the production of resins, packaging and polycarbonate monomers, its main sources in the environment are effluent discharges. Since the conventional treatment systems used in Brazil can’t remove a series of pollutants, the use of activated carbon is one of the alternatives fairly used for this purpose. Its production from alternative materials is becoming more and more frequent, as agroindustrial wastes, object of numerous studies of the production of activated carbon. The coffee grounds are one of these residues that has been used generating good carbonaceous adsorbents. Thus, the objective of this work was to evaluate the efficiency of the activated carbon produced from the coffee grounds, in the adsorption of BPA in aqueous medium. Water vapor (CAH), KOH (CAK), K2CO3 (CAKC) and ZnCl2 (CAZn) were used as the activating agente characterized by analysis of X-ray diffraction (XRD), Fourier transform infrared (FTIR), N2 adsorption and desorption, elemental composition (CHNS-O) and determination of zero charge potential. For the selection of the best coal, a preliminary adsorption test was carried out with the adsorbents produced, with the coffee grounds and a commercial coal for comparative purposes. The effect of the initial pH of the solution was also evaluated. The kinetic adsorption studies at the concentrations of 5, 20 and 30 mg/L of BPA were adjusted to the pseudo-firstorder and pseudo-second order models. The nature of the process was studied by the Langmuir and Freundlich isotherm models. Among the developed coals, the CAK and CAKC presented low production yield and were not submitted to the adsorption tests. The CHNS-O, XRD, FTIR and N2 adsorption/desorption analyzes of CAH and CAZn generated results close to those reported in the literature. In terms of specific surface area, the CAH proved to be out of the expected. The CAZn had an area of 1,038.51 m²/g. Of the materials tested, the CAH didn’t present adsorptive capacity, while the CAZn was the one with the best performance, with little variation in efficiency when the pH of the medium changed. The use of coffee grounds as bioadsorbent wasn’t promising, being 86 percentage points below the efficiency of CAZn. Adsorption kinetics revealed a relatively slow process at the concentrations studied, reaching equilibrium after 720 minutes. The kinetic data for the three systems presented a fractional order close to 2, thus indicating a better fit for the pseudo-second order model. The equilibrium data were better adjusted to the Langmuir model, assuming that the CAZn has a homogeneous surface with adsorption occurring in monolayer. The maximum adsorption capacity of BPA according to the same model was 123.22 mg/g. The results showed that CAZn can be considered a promising promoter in the removal of BPA, indicating coffee grounds as an alternative raw material for the production of activated carbon with the potential to remove emerging pollutants such as BPA in water.O Bisfenol-A (BPA) é um poluente emergente potencialmente capaz de interferir no sistema endócrino dos seres vivos. Empregado principalmente na indústria, na produção de resinas, embalagens e monômeros de policarbonato, suas principais fontes no meio ambiente são as descargas de efluentes. Uma vez que os sistemas de tratamento convencionais empregados no Brasil não conseguem remover uma série de poluentes, o uso de carvão ativado é uma das alternativas bastante empregada para esta finalidade. Sua produção a partir de materiais alternativos vem-se tornando cada vez mais frequente, como resíduos agroindustriais, objeto de inúmeros estudos de produção de carvão ativado. A borra de café é um destes resíduos que vem sendo utilizado gerando adsorventes carbonáceos de bons desempenhos. Dessa forma, o objetivo deste trabalho foi avaliar a eficiência do carvão ativado produzido da borra de café, na adsorção de BPA em meio aquoso. Foram utilizados como agente ativante vapor d’água (CAH), KOH (CAK), K2CO3 (CAKC) e ZnCl2 (CAZn), caracterizados por análises de difratometria de raios X (DRX) e de infravermelho por transformada de Fourier (FTIR), adsorção e dessorção de N2, composição elementar (CHNS-O) e determinação do potencial de carga zero. Para seleção do melhor carvão, um ensaio preliminar de adsorção foi realizado com os adsorventes produzidos, com a borra de café e um carvão comercial para fins comparativos. O efeito do pH inicial da solução também foi avaliado. Os estudos cinéticos de adsorção nas concentrações de 5, 20 e 30 mg/L de BPA foram ajustados os modelos de pseudo-primeira ordem e pseudo-segunda ordem. A natureza do processo foi estudada pelos modelos de isoterma de Langmuir e Freundlich. Dentre os carvões desenvolvidos, o CAK e CAKC apresentaram baixo rendimento de produção, não sendo então submetidos aos ensaios de adsorção. As análises CHNS-O, DRX, FTIR e adsorção/desorção de N2 do CAH e CAZn geraram resultados próximos aos relatados na literatura. Em termos de área superficial específica, o CAH mostrou-se fora do esperado. Já o CAZn apresentou uma área de 1.038,51 m²/g. Dos materiais testados, o CAH não apresentou capacidade adsortiva enquanto que o CAZn foi o de melhor desempenho, com pouca variação na eficiência quando alterado o pH do meio. O emprego da borra de café como bioadsorvente não foi promissor, ficando 86 pontos percentuais abaixo da eficiência do CAZn. A cinética de adsorção revelou um processo relativamente lento para as concentrações estudadas, atingindo o equilíbrio após 720 minutos. Os dados cinéticos, para os três sistemas, apresentaram ordem fracionária próxima de 2, indicando assim um melhor ajuste pelo modelo de pseudo-segunda ordem. Os dados de equilíbrio foram melhores ajustados ao modelo de Langmuir, pressupondo que o CAZn possui uma superfície homogênea com a adsorção ocorrendo em monocamada. A capacidade máxima de adsorção de BPA segundo o mesmo modelo foi de 123,22 mg/g. Os resultados mostraram que o CAZn pode ser considerado um adorvente promissor na remoção de BPA, indicando a borra de café como uma matéria-prima alternativa para produção de carvão ativado com potencial de remoção de poluentes emergentes, como o BPA, em água.Submitted by Liliane Ferreira (ljuvencia30@gmail.com) on 2018-04-26T10:56:51Z No. of bitstreams: 2 Dissertação - Andreia Cristina Fonseca Alves - 2018.pdf: 2077715 bytes, checksum: 014c09b110640921afd1122a8c288520 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5)Approved for entry into archive by Luciana Ferreira (lucgeral@gmail.com) on 2018-04-26T11:17:44Z (GMT) No. of bitstreams: 2 Dissertação - Andreia Cristina Fonseca Alves - 2018.pdf: 2077715 bytes, checksum: 014c09b110640921afd1122a8c288520 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5)Made available in DSpace on 2018-04-26T11:17:44Z (GMT). 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dc.title.eng.fl_str_mv |
Avaliação da remoção de bisfenol-a por adsorção em carvão ativado produzido da borra de café |
title |
Avaliação da remoção de bisfenol-a por adsorção em carvão ativado produzido da borra de café |
spellingShingle |
Avaliação da remoção de bisfenol-a por adsorção em carvão ativado produzido da borra de café Alves, Andreia Cristina Fonseca Poluentes emergentes Disruptores endócrinos Carvão microporoso BPA ENGENHARIA SANITARIA::SANEAMENTO AMBIENTAL |
title_short |
Avaliação da remoção de bisfenol-a por adsorção em carvão ativado produzido da borra de café |
title_full |
Avaliação da remoção de bisfenol-a por adsorção em carvão ativado produzido da borra de café |
title_fullStr |
Avaliação da remoção de bisfenol-a por adsorção em carvão ativado produzido da borra de café |
title_full_unstemmed |
Avaliação da remoção de bisfenol-a por adsorção em carvão ativado produzido da borra de café |
title_sort |
Avaliação da remoção de bisfenol-a por adsorção em carvão ativado produzido da borra de café |
author |
Alves, Andreia Cristina Fonseca |
author_facet |
Alves, Andreia Cristina Fonseca |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
Scalize, Paulo Sérgio |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/0957896448117207 |
dc.contributor.advisor-co1.fl_str_mv |
Oliveira, Sérgio Botelho de |
dc.contributor.advisor-co1Lattes.fl_str_mv |
http://lattes.cnpq.br/3447406257464639 |
dc.contributor.referee1.fl_str_mv |
Scalize, Paulo Sérgio |
dc.contributor.referee2.fl_str_mv |
Ostroski, Indianara Conceição |
dc.contributor.referee3.fl_str_mv |
Gil, Eric de Souza |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/2481528027682306 |
dc.contributor.author.fl_str_mv |
Alves, Andreia Cristina Fonseca |
contributor_str_mv |
Scalize, Paulo Sérgio Oliveira, Sérgio Botelho de Scalize, Paulo Sérgio Ostroski, Indianara Conceição Gil, Eric de Souza |
dc.subject.por.fl_str_mv |
Poluentes emergentes Disruptores endócrinos Carvão microporoso BPA |
topic |
Poluentes emergentes Disruptores endócrinos Carvão microporoso BPA ENGENHARIA SANITARIA::SANEAMENTO AMBIENTAL |
dc.subject.cnpq.fl_str_mv |
ENGENHARIA SANITARIA::SANEAMENTO AMBIENTAL |
description |
Bisphenol-A (BPA) is an emerging pollutant potentially capable of interfering with the endocrine system of living things. Employed mainly in the industry, in the production of resins, packaging and polycarbonate monomers, its main sources in the environment are effluent discharges. Since the conventional treatment systems used in Brazil can’t remove a series of pollutants, the use of activated carbon is one of the alternatives fairly used for this purpose. Its production from alternative materials is becoming more and more frequent, as agroindustrial wastes, object of numerous studies of the production of activated carbon. The coffee grounds are one of these residues that has been used generating good carbonaceous adsorbents. Thus, the objective of this work was to evaluate the efficiency of the activated carbon produced from the coffee grounds, in the adsorption of BPA in aqueous medium. Water vapor (CAH), KOH (CAK), K2CO3 (CAKC) and ZnCl2 (CAZn) were used as the activating agente characterized by analysis of X-ray diffraction (XRD), Fourier transform infrared (FTIR), N2 adsorption and desorption, elemental composition (CHNS-O) and determination of zero charge potential. For the selection of the best coal, a preliminary adsorption test was carried out with the adsorbents produced, with the coffee grounds and a commercial coal for comparative purposes. The effect of the initial pH of the solution was also evaluated. The kinetic adsorption studies at the concentrations of 5, 20 and 30 mg/L of BPA were adjusted to the pseudo-firstorder and pseudo-second order models. The nature of the process was studied by the Langmuir and Freundlich isotherm models. Among the developed coals, the CAK and CAKC presented low production yield and were not submitted to the adsorption tests. The CHNS-O, XRD, FTIR and N2 adsorption/desorption analyzes of CAH and CAZn generated results close to those reported in the literature. In terms of specific surface area, the CAH proved to be out of the expected. The CAZn had an area of 1,038.51 m²/g. Of the materials tested, the CAH didn’t present adsorptive capacity, while the CAZn was the one with the best performance, with little variation in efficiency when the pH of the medium changed. The use of coffee grounds as bioadsorbent wasn’t promising, being 86 percentage points below the efficiency of CAZn. Adsorption kinetics revealed a relatively slow process at the concentrations studied, reaching equilibrium after 720 minutes. The kinetic data for the three systems presented a fractional order close to 2, thus indicating a better fit for the pseudo-second order model. The equilibrium data were better adjusted to the Langmuir model, assuming that the CAZn has a homogeneous surface with adsorption occurring in monolayer. The maximum adsorption capacity of BPA according to the same model was 123.22 mg/g. The results showed that CAZn can be considered a promising promoter in the removal of BPA, indicating coffee grounds as an alternative raw material for the production of activated carbon with the potential to remove emerging pollutants such as BPA in water. |
publishDate |
2018 |
dc.date.accessioned.fl_str_mv |
2018-04-26T11:17:44Z |
dc.date.issued.fl_str_mv |
2018-02-26 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/masterThesis |
format |
masterThesis |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
ALVES, A. C. F. Avaliação da remoção de bisfenol-a por adsorção em carvão ativado produzido da borra de café. 2018. 71 f. Dissertação (Mestrado em Engenharia Ambiental e Sanitária) - Universidade Federal de Goiás, Goiânia, 2018. |
dc.identifier.uri.fl_str_mv |
http://repositorio.bc.ufg.br/tede/handle/tede/8390 |
dc.identifier.dark.fl_str_mv |
ark:/38995/0013000001567 |
identifier_str_mv |
ALVES, A. C. F. Avaliação da remoção de bisfenol-a por adsorção em carvão ativado produzido da borra de café. 2018. 71 f. Dissertação (Mestrado em Engenharia Ambiental e Sanitária) - Universidade Federal de Goiás, Goiânia, 2018. ark:/38995/0013000001567 |
url |
http://repositorio.bc.ufg.br/tede/handle/tede/8390 |
dc.language.iso.fl_str_mv |
por |
language |
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Universidade Federal de Goiás |
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