Análise da presença de surfactante na remoção de microplásticos por eletrocoagulação

Detalhes bibliográficos
Autor(a) principal: Oliveira, Luísa Rodrigues de
Data de Publicação: 2023
Tipo de documento: Dissertação
Idioma: por
Título da fonte: Repositório Institucional da UFG
Texto Completo: http://repositorio.bc.ufg.br/tede/handle/tede/12973
Resumo: Various types of pollutants are found in effluents, which can combine to form even more toxic components or impair the treatments used in effluent purification. Among the emerging contaminants, microplastics and surfactants can be mentioned, which coexist in different types of wastewater. The present work evaluated the effects caused by the anionic surfactant LAS and nonionic Tween 20 in the removal of pristine and aged PVC microplastic, added in synthetic water, by the method of electrocoagulation with aluminum electrodes. For the experiments, a bench reactor was developed, which operated in batches and with synthetic water, in order to avoid interference from other substances. For the analyses, counting was used with the aid of a magnifying glass, gravimetry and scanning electron microscopy. The results showed that there was a reduction in the removal of plastic microparticles when surfactant was added, the only one that showed improvement was with the new microplastic in the presence of LAS at a concentration of 10 ppm. The worst removal percentages were for the concentration of 100 ppm, and when adding Tween 20 there was a decrease of 23% and 45% for pristine and aged microplastic, respectively, while for LAS the decrease was 6% and 24 %, for intact and deteriorated microplastic, respectively. Therefore, it is clear that the drop in removal was greater for degraded microplastics, both for the tests with Tween 20 and for the LAS. Comparing the decrease in removal between the two types of surfactant, it is observed that the non-ionic one reduces microplastic removal to a greater extent.
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spelling Cuba Teran, Francisco Javierhttp://lattes.cnpq.br/3433455726987770Cuba Teran, Francisco JavierCarissimi, ElvisRuggeri Júnior, Humberto Carloshttp://lattes.cnpq.br/9001420943220457Oliveira, Luísa Rodrigues de2023-08-01T11:29:04Z2023-08-01T11:29:04Z2023-06-05OLIVEIRA, L. R. Análise da presença de surfactante na remoção de microplásticos por eletrocoagulação. 2023. 84 f. Dissertação (Mestrado em Engenharia Ambiental e Sanitária) - Universidade Federal de Goiás, Goiânia, 2023.http://repositorio.bc.ufg.br/tede/handle/tede/12973Various types of pollutants are found in effluents, which can combine to form even more toxic components or impair the treatments used in effluent purification. Among the emerging contaminants, microplastics and surfactants can be mentioned, which coexist in different types of wastewater. The present work evaluated the effects caused by the anionic surfactant LAS and nonionic Tween 20 in the removal of pristine and aged PVC microplastic, added in synthetic water, by the method of electrocoagulation with aluminum electrodes. For the experiments, a bench reactor was developed, which operated in batches and with synthetic water, in order to avoid interference from other substances. For the analyses, counting was used with the aid of a magnifying glass, gravimetry and scanning electron microscopy. The results showed that there was a reduction in the removal of plastic microparticles when surfactant was added, the only one that showed improvement was with the new microplastic in the presence of LAS at a concentration of 10 ppm. The worst removal percentages were for the concentration of 100 ppm, and when adding Tween 20 there was a decrease of 23% and 45% for pristine and aged microplastic, respectively, while for LAS the decrease was 6% and 24 %, for intact and deteriorated microplastic, respectively. Therefore, it is clear that the drop in removal was greater for degraded microplastics, both for the tests with Tween 20 and for the LAS. Comparing the decrease in removal between the two types of surfactant, it is observed that the non-ionic one reduces microplastic removal to a greater extent.Nos efluentes são encontrados variados tipos de poluentes, os quais podem se combinar formando componentes ainda mais tóxicos ou prejudicar os tratamentos usados na depuração de efluentes. Dentre os contaminantes emergentes pode-se citar os microplásticos e os surfactantes, que coexistem nos diversos tipos de águas residuais. O presente trabalho avaliou os efeitos ocasionados pelo tensoativo aniônico LAS e não iônico Tween 20 na remoção de microplástico de PVC pristinos e envelhecidos, adicionados em água sintética, pelo método da eletrocoagulação com eletrodos de alumínio. Para os experimentos desenvolveu-se um reator de bancada, o qual funcionava em batelada e com água sintética, a fim de evitar interferências de outras substâncias. Para as análises, utilizou-se contagem com o auxílio de uma Lupa, gravimetria e microscopia eletrônica de varredura. Os resultados mostraram que houve redução na remoção das micropartículas plásticas quando adicionado surfactante, o único que apresentou melhora foi com o microplástico novo na presença de LAS na concentração de 10 ppm. As piores porcentagens de remoção foram para a concentração de 100 ppm, sendo que ao adicionar Tween 20 ocorreu uma queda de 23% e de 45% para o microplástico pristino e envelhecido, respectivamente, já para o LAS a diminuição foi de 6% e 24%, para o microplástico pristino e envelhecido, respectivamente. Logo, percebe-se que a queda na remoção foi maior para os microplásticos degradados, tanto para os ensaios com Tween 20 quanto para o LAS. Comparando a diminuição da remoção entre os dois tipos de tensoativo, observa-se que o não iônico reduz em maior proporção a remoção de microplástico.Submitted by Marlene Santos (marlene.bc.ufg@gmail.com) on 2023-07-31T19:08:44Z No. of bitstreams: 2 Dissertação - Luísa Rodrigues de Oliveira - 2023.pdf: 1380945 bytes, checksum: ff5da090332cd3eb949b2f8830ac9768 (MD5) license_rdf: 805 bytes, checksum: 4460e5956bc1d1639be9ae6146a50347 (MD5)Approved for entry into archive by Luciana Ferreira (lucgeral@gmail.com) on 2023-08-01T11:29:04Z (GMT) No. of bitstreams: 2 Dissertação - Luísa Rodrigues de Oliveira - 2023.pdf: 1380945 bytes, checksum: ff5da090332cd3eb949b2f8830ac9768 (MD5) license_rdf: 805 bytes, checksum: 4460e5956bc1d1639be9ae6146a50347 (MD5)Made available in DSpace on 2023-08-01T11:29:04Z (GMT). No. of bitstreams: 2 Dissertação - Luísa Rodrigues de Oliveira - 2023.pdf: 1380945 bytes, checksum: ff5da090332cd3eb949b2f8830ac9768 (MD5) license_rdf: 805 bytes, checksum: 4460e5956bc1d1639be9ae6146a50347 (MD5) Previous issue date: 2023-06-05porUniversidade Federal de GoiásPrograma de Pós-graduação em Engenharia Ambiental e Sanitária (EECA)UFGBrasilEscola de Engenharia Civil e Ambiental - EECA (RMG)Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessPoluentes emergentesPlásticoTensoativoEmerging pollutantsPlasticSurfactantENGENHARIAS::ENGENHARIA SANITARIA::SANEAMENTO AMBIENTALAnálise da presença de surfactante na remoção de microplásticos por eletrocoagulaçãoAnalysis of the presence of surfactante in the removal of microplastics by electrocoagulationinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesis445005005003465reponame:Repositório Institucional da UFGinstname:Universidade Federal de Goiás (UFG)instacron:UFGLICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://repositorio.bc.ufg.br/tede/bitstreams/3b6a2f31-eb01-4f4a-93e5-f191b9f2d7e9/download8a4605be74aa9ea9d79846c1fba20a33MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8805http://repositorio.bc.ufg.br/tede/bitstreams/1458a306-808a-4be4-a1f1-f5ae899a30bf/download4460e5956bc1d1639be9ae6146a50347MD52ORIGINALDissertação - Luísa Rodrigues de Oliveira - 2023.pdfDissertação - Luísa Rodrigues de Oliveira - 2023.pdfapplication/pdf1380945http://repositorio.bc.ufg.br/tede/bitstreams/33fe7fc7-3ab9-4935-af1d-c0dd2d6ec5ee/downloadff5da090332cd3eb949b2f8830ac9768MD53tede/129732023-08-01 08:30:05.904http://creativecommons.org/licenses/by-nc-nd/4.0/Attribution-NonCommercial-NoDerivatives 4.0 Internationalopen.accessoai:repositorio.bc.ufg.br:tede/12973http://repositorio.bc.ufg.br/tedeRepositório InstitucionalPUBhttp://repositorio.bc.ufg.br/oai/requesttasesdissertacoes.bc@ufg.bropendoar:2023-08-01T11:30:05Repositório Institucional da UFG - Universidade Federal de Goiás (UFG)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
dc.title.pt_BR.fl_str_mv Análise da presença de surfactante na remoção de microplásticos por eletrocoagulação
dc.title.alternative.eng.fl_str_mv Analysis of the presence of surfactante in the removal of microplastics by electrocoagulation
title Análise da presença de surfactante na remoção de microplásticos por eletrocoagulação
spellingShingle Análise da presença de surfactante na remoção de microplásticos por eletrocoagulação
Oliveira, Luísa Rodrigues de
Poluentes emergentes
Plástico
Tensoativo
Emerging pollutants
Plastic
Surfactant
ENGENHARIAS::ENGENHARIA SANITARIA::SANEAMENTO AMBIENTAL
title_short Análise da presença de surfactante na remoção de microplásticos por eletrocoagulação
title_full Análise da presença de surfactante na remoção de microplásticos por eletrocoagulação
title_fullStr Análise da presença de surfactante na remoção de microplásticos por eletrocoagulação
title_full_unstemmed Análise da presença de surfactante na remoção de microplásticos por eletrocoagulação
title_sort Análise da presença de surfactante na remoção de microplásticos por eletrocoagulação
author Oliveira, Luísa Rodrigues de
author_facet Oliveira, Luísa Rodrigues de
author_role author
dc.contributor.advisor1.fl_str_mv Cuba Teran, Francisco Javier
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/3433455726987770
dc.contributor.referee1.fl_str_mv Cuba Teran, Francisco Javier
dc.contributor.referee2.fl_str_mv Carissimi, Elvis
dc.contributor.referee3.fl_str_mv Ruggeri Júnior, Humberto Carlos
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/9001420943220457
dc.contributor.author.fl_str_mv Oliveira, Luísa Rodrigues de
contributor_str_mv Cuba Teran, Francisco Javier
Cuba Teran, Francisco Javier
Carissimi, Elvis
Ruggeri Júnior, Humberto Carlos
dc.subject.por.fl_str_mv Poluentes emergentes
Plástico
Tensoativo
topic Poluentes emergentes
Plástico
Tensoativo
Emerging pollutants
Plastic
Surfactant
ENGENHARIAS::ENGENHARIA SANITARIA::SANEAMENTO AMBIENTAL
dc.subject.eng.fl_str_mv Emerging pollutants
Plastic
Surfactant
dc.subject.cnpq.fl_str_mv ENGENHARIAS::ENGENHARIA SANITARIA::SANEAMENTO AMBIENTAL
description Various types of pollutants are found in effluents, which can combine to form even more toxic components or impair the treatments used in effluent purification. Among the emerging contaminants, microplastics and surfactants can be mentioned, which coexist in different types of wastewater. The present work evaluated the effects caused by the anionic surfactant LAS and nonionic Tween 20 in the removal of pristine and aged PVC microplastic, added in synthetic water, by the method of electrocoagulation with aluminum electrodes. For the experiments, a bench reactor was developed, which operated in batches and with synthetic water, in order to avoid interference from other substances. For the analyses, counting was used with the aid of a magnifying glass, gravimetry and scanning electron microscopy. The results showed that there was a reduction in the removal of plastic microparticles when surfactant was added, the only one that showed improvement was with the new microplastic in the presence of LAS at a concentration of 10 ppm. The worst removal percentages were for the concentration of 100 ppm, and when adding Tween 20 there was a decrease of 23% and 45% for pristine and aged microplastic, respectively, while for LAS the decrease was 6% and 24 %, for intact and deteriorated microplastic, respectively. Therefore, it is clear that the drop in removal was greater for degraded microplastics, both for the tests with Tween 20 and for the LAS. Comparing the decrease in removal between the two types of surfactant, it is observed that the non-ionic one reduces microplastic removal to a greater extent.
publishDate 2023
dc.date.accessioned.fl_str_mv 2023-08-01T11:29:04Z
dc.date.available.fl_str_mv 2023-08-01T11:29:04Z
dc.date.issued.fl_str_mv 2023-06-05
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/masterThesis
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dc.identifier.citation.fl_str_mv OLIVEIRA, L. R. Análise da presença de surfactante na remoção de microplásticos por eletrocoagulação. 2023. 84 f. Dissertação (Mestrado em Engenharia Ambiental e Sanitária) - Universidade Federal de Goiás, Goiânia, 2023.
dc.identifier.uri.fl_str_mv http://repositorio.bc.ufg.br/tede/handle/tede/12973
identifier_str_mv OLIVEIRA, L. R. Análise da presença de surfactante na remoção de microplásticos por eletrocoagulação. 2023. 84 f. Dissertação (Mestrado em Engenharia Ambiental e Sanitária) - Universidade Federal de Goiás, Goiânia, 2023.
url http://repositorio.bc.ufg.br/tede/handle/tede/12973
dc.language.iso.fl_str_mv por
language por
dc.relation.program.fl_str_mv 44
dc.relation.confidence.fl_str_mv 500
500
500
dc.relation.department.fl_str_mv 3
dc.relation.cnpq.fl_str_mv 465
dc.rights.driver.fl_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Universidade Federal de Goiás
dc.publisher.program.fl_str_mv Programa de Pós-graduação em Engenharia Ambiental e Sanitária (EECA)
dc.publisher.initials.fl_str_mv UFG
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv Escola de Engenharia Civil e Ambiental - EECA (RMG)
publisher.none.fl_str_mv Universidade Federal de Goiás
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFG
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