Preparação e cracterização de compósitos de CoFe2O4/ZrO2
Autor(a) principal: | |
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Data de Publicação: | 2016 |
Tipo de documento: | Dissertação |
Idioma: | por |
Título da fonte: | Repositório Institucional da UFG |
Texto Completo: | http://repositorio.bc.ufg.br/tede/handle/tede/5738 |
Resumo: | In this work, structural, morphological and magnetic properties of cobalt ferrite/zirconium oxide composites prepared via mechanical mixing of the powders were evaluated. Cobalt ferrite powders were obtained by coprecipitation, and some synthesis parameters were optimized, such as the speed of stirring , the concentration of base and metal solutions, in order to obtain stoichiometric ferrites (Fe3+/Co2+ = 2: 1) or near to it. Zirconium oxide powders were synthesized via sol-gel. The composites were analyzed by Atomic Absorption, Field Emission Scanning Electron Microscopy and Spectroscopy Dispersive Energy, Diffraction of X-rays, Infrared Spectroscopy and Vibranting Sample Magnetometry. It was observed the migration of cations between the ferrite and zirconia structures as a result of high diffusion between phases due to heat treatment. The analysis by Field Emission Scanning Electron Microscopy and Spectroscopy Dispersive Energy showed the different microstructures of aggregates present in the composites and the average diameter of the grains. The insertion of a magnetic phase on a non-magnetic matrix caused an increase in the saturation magnetization and the remanent magnetization, and decrease in coercivity as the cobalt ferrite content increases. |
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Satoratto, Patrícia Pommé Confessorihttp://lattes.cnpq.br/9777959525393785Franco Júnior, Adolfohttp://lattes.cnpq.br/0187547195548392Sartoratto, Patrícia Pommé ConfessoriFranco Júnior, AdolfoGomes, Danielle Cangussu de CastroSilva, Sebastião William dahttp://lattes.cnpq.br/1306874827204440Maciel, Sara Alves2016-07-25T11:13:28Z2016-04-05MACIEL, S. A. Preparação e cracterização de compósitos de CoFe2O4/ZrO2. 2016. 84 f. Dissertação (Mestrado em Química) - Universidade Federal de Goiás, Goiânia, 2016.http://repositorio.bc.ufg.br/tede/handle/tede/5738In this work, structural, morphological and magnetic properties of cobalt ferrite/zirconium oxide composites prepared via mechanical mixing of the powders were evaluated. Cobalt ferrite powders were obtained by coprecipitation, and some synthesis parameters were optimized, such as the speed of stirring , the concentration of base and metal solutions, in order to obtain stoichiometric ferrites (Fe3+/Co2+ = 2: 1) or near to it. Zirconium oxide powders were synthesized via sol-gel. The composites were analyzed by Atomic Absorption, Field Emission Scanning Electron Microscopy and Spectroscopy Dispersive Energy, Diffraction of X-rays, Infrared Spectroscopy and Vibranting Sample Magnetometry. It was observed the migration of cations between the ferrite and zirconia structures as a result of high diffusion between phases due to heat treatment. The analysis by Field Emission Scanning Electron Microscopy and Spectroscopy Dispersive Energy showed the different microstructures of aggregates present in the composites and the average diameter of the grains. The insertion of a magnetic phase on a non-magnetic matrix caused an increase in the saturation magnetization and the remanent magnetization, and decrease in coercivity as the cobalt ferrite content increases.Neste trabalho, foram avaliadas propriedades estruturais, morfológicas e magnéticas de compósitos de ferrita de cobalto/óxido de zircônio, preparados via mistura mecânica dos pós. Os pós de ferrita de cobalto foram obtidos pelo método da coprecipitação, tendo seus parâmetros de síntese otimizados, tais como velocidade de agitação, concentração das soluções de base e dos metais, a fim de se obter ferritas estequiométricas (Fe3+/Co2+ = 2:1) ou próximas disso. Os pós de óxido de zircônio foram sintetizados via sol-gel. Os compósitos foram analisados por Absorção Atômica, Microscopia Eletrônica de Varredura com Emissão de Campo e Espectroscopia por Energia Dispersiva, Difratometria de Raios X, Espectroscopia na Região do Infravermelho e por Magnetometria de Amostra Vibrante. Foi observada a migração de cátions entre as estruturas da ferrita e da zircônia como consequência da alta difusão entre as fases devido ao tratamento térmico. A análise por Microscopia Eletrônica de Varredura com Emissão de Campo e Espectroscopia por Energia Dispersiva permitiu verificar as diferentes microestruturas dos agregados presentes nos compósitos e o diâmetro médio dos grãos. A inserção de uma fase magnética em uma matriz não magnética provocou aumento na magnetização de saturação e na magnetização remanescente, além de uma diminuição na coercividade à medida que o teor de ferrita de cobalto aumenta.Submitted by Luciana Ferreira (lucgeral@gmail.com) on 2016-07-25T10:59:35Z No. of bitstreams: 2 Dissertação - Sara Alves Maciel - 2016.pdf: 11054901 bytes, checksum: 8cddf79cb5700731533eb7125fe234a3 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5)Approved for entry into archive by Luciana Ferreira (lucgeral@gmail.com) on 2016-07-25T11:13:28Z (GMT) No. of bitstreams: 2 Dissertação - Sara Alves Maciel - 2016.pdf: 11054901 bytes, checksum: 8cddf79cb5700731533eb7125fe234a3 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5)Made available in DSpace on 2016-07-25T11:13:28Z (GMT). No. of bitstreams: 2 Dissertação - Sara Alves Maciel - 2016.pdf: 11054901 bytes, checksum: 8cddf79cb5700731533eb7125fe234a3 (MD5) license_rdf: 0 bytes, checksum: d41d8cd98f00b204e9800998ecf8427e (MD5) Previous issue date: 2016-04-05Fundação de Amparo à Pesquisa do Estado de Goiás - FAPEGapplication/pdfporUniversidade Federal de GoiásPrograma de Pós-graduação em Química (IQ)UFGBrasilInstituto de Química - IQ (RG)http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessMateriais magnéticosCompósitosFerrita de cobaltoÓxido de zircônioNanopartículasMagnetic materialsCompositesCbaltferritesZircon oxideNanoparticlesCIENCIAS EXATAS E DA TERRA::QUIMICAPreparação e cracterização de compósitos de CoFe2O4/ZrO2Preparation and characterization of CoFe2O4/ZrO2 compositesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesis66369392132541515860060060060078260667437411972781571700325303117195-961409807440757778reponame:Repositório Institucional da UFGinstname:Universidade Federal de Goiás (UFG)instacron:UFGLICENSElicense.txtlicense.txttext/plain; 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dc.title.por.fl_str_mv |
Preparação e cracterização de compósitos de CoFe2O4/ZrO2 |
dc.title.alternative.eng.fl_str_mv |
Preparation and characterization of CoFe2O4/ZrO2 composites |
title |
Preparação e cracterização de compósitos de CoFe2O4/ZrO2 |
spellingShingle |
Preparação e cracterização de compósitos de CoFe2O4/ZrO2 Maciel, Sara Alves Materiais magnéticos Compósitos Ferrita de cobalto Óxido de zircônio Nanopartículas Magnetic materials Composites Cbaltferrites Zircon oxide Nanoparticles CIENCIAS EXATAS E DA TERRA::QUIMICA |
title_short |
Preparação e cracterização de compósitos de CoFe2O4/ZrO2 |
title_full |
Preparação e cracterização de compósitos de CoFe2O4/ZrO2 |
title_fullStr |
Preparação e cracterização de compósitos de CoFe2O4/ZrO2 |
title_full_unstemmed |
Preparação e cracterização de compósitos de CoFe2O4/ZrO2 |
title_sort |
Preparação e cracterização de compósitos de CoFe2O4/ZrO2 |
author |
Maciel, Sara Alves |
author_facet |
Maciel, Sara Alves |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
Satoratto, Patrícia Pommé Confessori |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/9777959525393785 |
dc.contributor.advisor-co1.fl_str_mv |
Franco Júnior, Adolfo |
dc.contributor.advisor-co1Lattes.fl_str_mv |
http://lattes.cnpq.br/0187547195548392 |
dc.contributor.referee1.fl_str_mv |
Sartoratto, Patrícia Pommé Confessori |
dc.contributor.referee2.fl_str_mv |
Franco Júnior, Adolfo |
dc.contributor.referee3.fl_str_mv |
Gomes, Danielle Cangussu de Castro |
dc.contributor.referee4.fl_str_mv |
Silva, Sebastião William da |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/1306874827204440 |
dc.contributor.author.fl_str_mv |
Maciel, Sara Alves |
contributor_str_mv |
Satoratto, Patrícia Pommé Confessori Franco Júnior, Adolfo Sartoratto, Patrícia Pommé Confessori Franco Júnior, Adolfo Gomes, Danielle Cangussu de Castro Silva, Sebastião William da |
dc.subject.por.fl_str_mv |
Materiais magnéticos Compósitos Ferrita de cobalto Óxido de zircônio Nanopartículas |
topic |
Materiais magnéticos Compósitos Ferrita de cobalto Óxido de zircônio Nanopartículas Magnetic materials Composites Cbaltferrites Zircon oxide Nanoparticles CIENCIAS EXATAS E DA TERRA::QUIMICA |
dc.subject.eng.fl_str_mv |
Magnetic materials Composites Cbaltferrites Zircon oxide Nanoparticles |
dc.subject.cnpq.fl_str_mv |
CIENCIAS EXATAS E DA TERRA::QUIMICA |
description |
In this work, structural, morphological and magnetic properties of cobalt ferrite/zirconium oxide composites prepared via mechanical mixing of the powders were evaluated. Cobalt ferrite powders were obtained by coprecipitation, and some synthesis parameters were optimized, such as the speed of stirring , the concentration of base and metal solutions, in order to obtain stoichiometric ferrites (Fe3+/Co2+ = 2: 1) or near to it. Zirconium oxide powders were synthesized via sol-gel. The composites were analyzed by Atomic Absorption, Field Emission Scanning Electron Microscopy and Spectroscopy Dispersive Energy, Diffraction of X-rays, Infrared Spectroscopy and Vibranting Sample Magnetometry. It was observed the migration of cations between the ferrite and zirconia structures as a result of high diffusion between phases due to heat treatment. The analysis by Field Emission Scanning Electron Microscopy and Spectroscopy Dispersive Energy showed the different microstructures of aggregates present in the composites and the average diameter of the grains. The insertion of a magnetic phase on a non-magnetic matrix caused an increase in the saturation magnetization and the remanent magnetization, and decrease in coercivity as the cobalt ferrite content increases. |
publishDate |
2016 |
dc.date.accessioned.fl_str_mv |
2016-07-25T11:13:28Z |
dc.date.issued.fl_str_mv |
2016-04-05 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/masterThesis |
format |
masterThesis |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
MACIEL, S. A. Preparação e cracterização de compósitos de CoFe2O4/ZrO2. 2016. 84 f. Dissertação (Mestrado em Química) - Universidade Federal de Goiás, Goiânia, 2016. |
dc.identifier.uri.fl_str_mv |
http://repositorio.bc.ufg.br/tede/handle/tede/5738 |
identifier_str_mv |
MACIEL, S. A. Preparação e cracterização de compósitos de CoFe2O4/ZrO2. 2016. 84 f. Dissertação (Mestrado em Química) - Universidade Federal de Goiás, Goiânia, 2016. |
url |
http://repositorio.bc.ufg.br/tede/handle/tede/5738 |
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por |
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por |
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600 600 600 600 |
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1571700325303117195 |
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http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess |
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http://creativecommons.org/licenses/by-nc-nd/4.0/ |
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openAccess |
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Universidade Federal de Goiás |
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UFG |
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Brasil |
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Instituto de Química - IQ (RG) |
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Universidade Federal de Goiás |
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