GENERAL EQUATIONS OF CARBONIZATION OF Eucalyptus spp KINETIC MECHANISMS

• Autor(a) principal: Raad, Túlio Jardim
• Data de Publicação: 2015
• Outros Autores: Pinheiro, Paulo César da C., Yoshida, Maria Irene
• Tipo de documento: Artigo
• Idioma: por
• Título da fonte: Cerne (Online)
• Texto Completo: https://cerne.ufla.br/site/index.php/CERNE/article/view/405
• topic: Kinetic mechanism; carbonization; thermogravimetry; eucalyptus; hemicellulose; cellulose and lignin

In the present work, a set of general equations related to kinetic mechanism of wood compound carbonization: hemicelluloses, cellulose and lignin was obtained by Avrami-Eroffev and Arrhenius equations and Thermogravimetry of Eucalyptus cloeziana, Eucalyptus camaldulensis, Corymbia citriodora, Eucalyptus urophylla and Eucalyptus grandis samples, TG-Isothermal and TG-Dynamic. The different thermal stabilities and decomposition temperature bands of those species compounds were applied as strategy to obtain the kinetic parameters: activation energy, exponential factor and reaction order. The kinetic model developed was validated by thermogravimetric curves from carbonization of others biomass such as coconut. The kinetic parameters found were - Hemicelluloses: E=98,6 kJmol, A=3,5x106s-1 n=1,0; - Cellulose: E=182,2 kJmol, A=1,2x1013s-1 n=1,5; - Lignin: E=46,6 kJmol, A=2,01s-1 n=0,41. The set of equations can be implemented in a mathematical model of wood carbonization simulation (with heat and mass transfer equations) with the aim of optimizing the control and charcoal process used to produce pig iron.