How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils?
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFLA |
Texto Completo: | http://repositorio.ufla.br/jspui/handle/1/46917 |
Resumo: | Sorption of selenate (SeO 4 2- ) and selenite (SeO 3 2- ) is poorly understood in Brazilian agroecosystems, especially in soils from agricultural areas containing different contents of competing anions, such as sulfate (SO 4 2- ). This study aimed to assess the sorption behavior of selenate and selenite at different soil layers of a tropical soil treated with different rates of agricultural gypsum (thus, containing different contents of sulfate), collected under a coffee plantation. Soil samples from an experimental area where phosphogypsum has been previously applied at different rates (0, 7, 14, and 56 t ha -1 ) were taken at the following soil layers: 0.15-0.25, 0.35-0.45, and 1.25-1.35 m. Adsorption experiments were carried out adding 20 mL of solutions containing 100 and 500 μg L -1 of selenate and 10 and 15 mg L -1 of selenite to 2 grams of soil. Desorption experiments were also performed using a soil:solution ratio of 1:10. Adsorption of selenate increased with soil depth and decreased upon increasing sulfate contents in the soil, by contrast, selenite was consistently adsorbed at higher contents - when compared with selenate - at any soil depth and its sorptive behavior was not affected by the presence of sulfate. Furthermore, selenite was less desorbed than selenate under all conditions. In conclusion, selenite is much more retained in tropical soils and less available to plants than selenate. Also, although sulfate has shown to be able to hinder selenate retention, it has no substantial effect on the sorption behavior of selenite in tropical agroecosystems. |
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How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils?SeleniumAdsorption/desorptionPhosphogypsumCompetitive anionsRetention/availabilitySelênio - SorçãoAdsorção/dessorçãoFosfogessoÂnions competitivosSolos tropicaisSorption of selenate (SeO 4 2- ) and selenite (SeO 3 2- ) is poorly understood in Brazilian agroecosystems, especially in soils from agricultural areas containing different contents of competing anions, such as sulfate (SO 4 2- ). This study aimed to assess the sorption behavior of selenate and selenite at different soil layers of a tropical soil treated with different rates of agricultural gypsum (thus, containing different contents of sulfate), collected under a coffee plantation. Soil samples from an experimental area where phosphogypsum has been previously applied at different rates (0, 7, 14, and 56 t ha -1 ) were taken at the following soil layers: 0.15-0.25, 0.35-0.45, and 1.25-1.35 m. Adsorption experiments were carried out adding 20 mL of solutions containing 100 and 500 μg L -1 of selenate and 10 and 15 mg L -1 of selenite to 2 grams of soil. Desorption experiments were also performed using a soil:solution ratio of 1:10. Adsorption of selenate increased with soil depth and decreased upon increasing sulfate contents in the soil, by contrast, selenite was consistently adsorbed at higher contents - when compared with selenate - at any soil depth and its sorptive behavior was not affected by the presence of sulfate. Furthermore, selenite was less desorbed than selenate under all conditions. In conclusion, selenite is much more retained in tropical soils and less available to plants than selenate. Also, although sulfate has shown to be able to hinder selenate retention, it has no substantial effect on the sorption behavior of selenite in tropical agroecosystems.Sociedade Brasileira de Ciência do Solo2021-08-20T19:12:54Z2021-08-20T19:12:54Z2020-11info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfARAUJO, A. M. et al. How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils? Revista Brasileira de Ciência do Solo, Viçosa, MG, v. 44, e0200087, 2020. DOI: https://doi.org/10.36783/18069657rbcs20200087.http://repositorio.ufla.br/jspui/handle/1/46917Revista Brasileira de Ciência do Soloreponame:Repositório Institucional da UFLAinstname:Universidade Federal de Lavras (UFLA)instacron:UFLAhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessAraujo, Anderson MendesLessa, Josimar Henrique de LimaChanavat, Luiz GustavoCuri, NiltonGuilherme, Luiz Roberto GuimarãesLopes, Guilhermeeng2021-08-20T19:13:12Zoai:localhost:1/46917Repositório InstitucionalPUBhttp://repositorio.ufla.br/oai/requestnivaldo@ufla.br || repositorio.biblioteca@ufla.bropendoar:2021-08-20T19:13:12Repositório Institucional da UFLA - Universidade Federal de Lavras (UFLA)false |
dc.title.none.fl_str_mv |
How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils? |
title |
How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils? |
spellingShingle |
How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils? Araujo, Anderson Mendes Selenium Adsorption/desorption Phosphogypsum Competitive anions Retention/availability Selênio - Sorção Adsorção/dessorção Fosfogesso Ânions competitivos Solos tropicais |
title_short |
How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils? |
title_full |
How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils? |
title_fullStr |
How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils? |
title_full_unstemmed |
How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils? |
title_sort |
How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils? |
author |
Araujo, Anderson Mendes |
author_facet |
Araujo, Anderson Mendes Lessa, Josimar Henrique de Lima Chanavat, Luiz Gustavo Curi, Nilton Guilherme, Luiz Roberto Guimarães Lopes, Guilherme |
author_role |
author |
author2 |
Lessa, Josimar Henrique de Lima Chanavat, Luiz Gustavo Curi, Nilton Guilherme, Luiz Roberto Guimarães Lopes, Guilherme |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Araujo, Anderson Mendes Lessa, Josimar Henrique de Lima Chanavat, Luiz Gustavo Curi, Nilton Guilherme, Luiz Roberto Guimarães Lopes, Guilherme |
dc.subject.por.fl_str_mv |
Selenium Adsorption/desorption Phosphogypsum Competitive anions Retention/availability Selênio - Sorção Adsorção/dessorção Fosfogesso Ânions competitivos Solos tropicais |
topic |
Selenium Adsorption/desorption Phosphogypsum Competitive anions Retention/availability Selênio - Sorção Adsorção/dessorção Fosfogesso Ânions competitivos Solos tropicais |
description |
Sorption of selenate (SeO 4 2- ) and selenite (SeO 3 2- ) is poorly understood in Brazilian agroecosystems, especially in soils from agricultural areas containing different contents of competing anions, such as sulfate (SO 4 2- ). This study aimed to assess the sorption behavior of selenate and selenite at different soil layers of a tropical soil treated with different rates of agricultural gypsum (thus, containing different contents of sulfate), collected under a coffee plantation. Soil samples from an experimental area where phosphogypsum has been previously applied at different rates (0, 7, 14, and 56 t ha -1 ) were taken at the following soil layers: 0.15-0.25, 0.35-0.45, and 1.25-1.35 m. Adsorption experiments were carried out adding 20 mL of solutions containing 100 and 500 μg L -1 of selenate and 10 and 15 mg L -1 of selenite to 2 grams of soil. Desorption experiments were also performed using a soil:solution ratio of 1:10. Adsorption of selenate increased with soil depth and decreased upon increasing sulfate contents in the soil, by contrast, selenite was consistently adsorbed at higher contents - when compared with selenate - at any soil depth and its sorptive behavior was not affected by the presence of sulfate. Furthermore, selenite was less desorbed than selenate under all conditions. In conclusion, selenite is much more retained in tropical soils and less available to plants than selenate. Also, although sulfate has shown to be able to hinder selenate retention, it has no substantial effect on the sorption behavior of selenite in tropical agroecosystems. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-11 2021-08-20T19:12:54Z 2021-08-20T19:12:54Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
ARAUJO, A. M. et al. How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils? Revista Brasileira de Ciência do Solo, Viçosa, MG, v. 44, e0200087, 2020. DOI: https://doi.org/10.36783/18069657rbcs20200087. http://repositorio.ufla.br/jspui/handle/1/46917 |
identifier_str_mv |
ARAUJO, A. M. et al. How sulfate content and soil depth affect the adsorption/desorption of selenate and selenite in tropical soils? Revista Brasileira de Ciência do Solo, Viçosa, MG, v. 44, e0200087, 2020. DOI: https://doi.org/10.36783/18069657rbcs20200087. |
url |
http://repositorio.ufla.br/jspui/handle/1/46917 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by/4.0/ |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Ciência do Solo |
publisher.none.fl_str_mv |
Sociedade Brasileira de Ciência do Solo |
dc.source.none.fl_str_mv |
Revista Brasileira de Ciência do Solo reponame:Repositório Institucional da UFLA instname:Universidade Federal de Lavras (UFLA) instacron:UFLA |
instname_str |
Universidade Federal de Lavras (UFLA) |
instacron_str |
UFLA |
institution |
UFLA |
reponame_str |
Repositório Institucional da UFLA |
collection |
Repositório Institucional da UFLA |
repository.name.fl_str_mv |
Repositório Institucional da UFLA - Universidade Federal de Lavras (UFLA) |
repository.mail.fl_str_mv |
nivaldo@ufla.br || repositorio.biblioteca@ufla.br |
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1784550158195752960 |