Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doce
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Repositório Institucional da UFLA |
Texto Completo: | http://repositorio.ufla.br/jspui/handle/1/42489 |
Resumo: | The objective of this work was to determine the adsorption isotherms of sweet passion-fruit seeds, select the mathematical model that best describes the hygroscopic behavior of these seeds and estimate the integral isosteric heat, the differential entropy and Gibbs free energy to the conditions studied. The equilibrium moisture content of the seeds was obtained by the static-gravimetric method. To condition the equilibrium environment, the seeds were placed in sealed containers containing different saturated saline solutions and placed in chambers type B.O.D. regulated at temperatures of 10, 20, 30 and 40 ºC. Analyzing the results obtained conclude that: The equilibrium moisture content of passion-fruit seeds is directly proportional to water activity and decreases as the temperature increases; Among the models tested, the Chung Pfost model is the one that best represents the hygroscopicity of sweet passion-fruit seeds; With the reduction of the moisture content of the seeds, the integral isosteric heat of adsorption, the differential entropy and the Gibbs free energy increase; The adsorption process of sweet passion-fruit seeds is controlled by enthalpy. |
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Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doceMoisture sorption isotherms and thermodynamic properties of passion fruit seedsIsotermas de sorción y propiedades termodinámicas de semillas de maracuyá DulceEquilíbrio higroscópicoPassifloraCalor isostérico integralEntropia diferencialEnergia livre de GibbsHygroscopic equilibriumIntegral isosteric heatDifferential entropyGibbs free energyThe objective of this work was to determine the adsorption isotherms of sweet passion-fruit seeds, select the mathematical model that best describes the hygroscopic behavior of these seeds and estimate the integral isosteric heat, the differential entropy and Gibbs free energy to the conditions studied. The equilibrium moisture content of the seeds was obtained by the static-gravimetric method. To condition the equilibrium environment, the seeds were placed in sealed containers containing different saturated saline solutions and placed in chambers type B.O.D. regulated at temperatures of 10, 20, 30 and 40 ºC. Analyzing the results obtained conclude that: The equilibrium moisture content of passion-fruit seeds is directly proportional to water activity and decreases as the temperature increases; Among the models tested, the Chung Pfost model is the one that best represents the hygroscopicity of sweet passion-fruit seeds; With the reduction of the moisture content of the seeds, the integral isosteric heat of adsorption, the differential entropy and the Gibbs free energy increase; The adsorption process of sweet passion-fruit seeds is controlled by enthalpy.Objetivou-se com o presente trabalho determinar as isotermas de adsorção de sementes de maracujá doce, selecionar o modelo matemático que melhor descreve o comportamento higroscópico dessas sementes e estimar o calor isostérico integral, a entropia diferencial e a energia livre de Gibbs, para as condições estudadas. O teor de água de equilíbrio das sementes foi obtido pelo método estático-gravimétrico. Para condicionar o ambiente de equilíbrio, as sementes foram inseridas em recipientes herméticos contendo diferentes soluções salinas saturadas e esses recipientes foram colocados em BODs reguladas para as temperaturas de 10, 20, 30 e 40 °C. Analisando-se os resultados obtidos pode-se concluir que: O teor de água de equilíbrio higroscópico das sementes de maracujá é diretamente proporcional à atividade de água e decresce com o aumento de temperatura; Dentre os modelos testados, o modelo de Chung Pfost é aquele que melhor representa a higroscopicidade das sementes de maracujá doce; Com a redução do teor de água das sementes ocorre um aumento do calor isostérico integral de adsorção, da entropia diferencial e da energia livre de Gibbs; O processo de adsorção das sementes de maracujá doce é controlado pela entalpia.CDRR Editors2020-08-19T17:31:51Z2020-08-19T17:31:51Z2020info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfISQUIERDO, E. P. et al. Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doce. Research, Society and Development, Vargem Grande Paulista, v. 9, n. 5, p. e44952884, 2020. DOI: 10.33448/rsd-v9i5.2884.http://repositorio.ufla.br/jspui/handle/1/42489Research, Society and Developmentreponame:Repositório Institucional da UFLAinstname:Universidade Federal de Lavras (UFLA)instacron:UFLAhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessIsquierdo, Eder PedrozaSiqueira, Valdiney CambuyBorém, Flávio MeiraAndrade, Ednilton Tavares deLuz, Petterson Baptista daQuequeto, Wellytton Darcipor2023-05-02T18:07:49Zoai:localhost:1/42489Repositório InstitucionalPUBhttp://repositorio.ufla.br/oai/requestnivaldo@ufla.br || repositorio.biblioteca@ufla.bropendoar:2023-05-02T18:07:49Repositório Institucional da UFLA - Universidade Federal de Lavras (UFLA)false |
dc.title.none.fl_str_mv |
Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doce Moisture sorption isotherms and thermodynamic properties of passion fruit seeds Isotermas de sorción y propiedades termodinámicas de semillas de maracuyá Dulce |
title |
Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doce |
spellingShingle |
Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doce Isquierdo, Eder Pedroza Equilíbrio higroscópico Passiflora Calor isostérico integral Entropia diferencial Energia livre de Gibbs Hygroscopic equilibrium Integral isosteric heat Differential entropy Gibbs free energy |
title_short |
Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doce |
title_full |
Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doce |
title_fullStr |
Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doce |
title_full_unstemmed |
Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doce |
title_sort |
Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doce |
author |
Isquierdo, Eder Pedroza |
author_facet |
Isquierdo, Eder Pedroza Siqueira, Valdiney Cambuy Borém, Flávio Meira Andrade, Ednilton Tavares de Luz, Petterson Baptista da Quequeto, Wellytton Darci |
author_role |
author |
author2 |
Siqueira, Valdiney Cambuy Borém, Flávio Meira Andrade, Ednilton Tavares de Luz, Petterson Baptista da Quequeto, Wellytton Darci |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Isquierdo, Eder Pedroza Siqueira, Valdiney Cambuy Borém, Flávio Meira Andrade, Ednilton Tavares de Luz, Petterson Baptista da Quequeto, Wellytton Darci |
dc.subject.por.fl_str_mv |
Equilíbrio higroscópico Passiflora Calor isostérico integral Entropia diferencial Energia livre de Gibbs Hygroscopic equilibrium Integral isosteric heat Differential entropy Gibbs free energy |
topic |
Equilíbrio higroscópico Passiflora Calor isostérico integral Entropia diferencial Energia livre de Gibbs Hygroscopic equilibrium Integral isosteric heat Differential entropy Gibbs free energy |
description |
The objective of this work was to determine the adsorption isotherms of sweet passion-fruit seeds, select the mathematical model that best describes the hygroscopic behavior of these seeds and estimate the integral isosteric heat, the differential entropy and Gibbs free energy to the conditions studied. The equilibrium moisture content of the seeds was obtained by the static-gravimetric method. To condition the equilibrium environment, the seeds were placed in sealed containers containing different saturated saline solutions and placed in chambers type B.O.D. regulated at temperatures of 10, 20, 30 and 40 ºC. Analyzing the results obtained conclude that: The equilibrium moisture content of passion-fruit seeds is directly proportional to water activity and decreases as the temperature increases; Among the models tested, the Chung Pfost model is the one that best represents the hygroscopicity of sweet passion-fruit seeds; With the reduction of the moisture content of the seeds, the integral isosteric heat of adsorption, the differential entropy and the Gibbs free energy increase; The adsorption process of sweet passion-fruit seeds is controlled by enthalpy. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-08-19T17:31:51Z 2020-08-19T17:31:51Z 2020 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
ISQUIERDO, E. P. et al. Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doce. Research, Society and Development, Vargem Grande Paulista, v. 9, n. 5, p. e44952884, 2020. DOI: 10.33448/rsd-v9i5.2884. http://repositorio.ufla.br/jspui/handle/1/42489 |
identifier_str_mv |
ISQUIERDO, E. P. et al. Isotermas de sorção e propriedades termodinâmicas de sementes de maracujá doce. Research, Society and Development, Vargem Grande Paulista, v. 9, n. 5, p. e44952884, 2020. DOI: 10.33448/rsd-v9i5.2884. |
url |
http://repositorio.ufla.br/jspui/handle/1/42489 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.rights.driver.fl_str_mv |
http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
http://creativecommons.org/licenses/by/4.0/ |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
CDRR Editors |
publisher.none.fl_str_mv |
CDRR Editors |
dc.source.none.fl_str_mv |
Research, Society and Development reponame:Repositório Institucional da UFLA instname:Universidade Federal de Lavras (UFLA) instacron:UFLA |
instname_str |
Universidade Federal de Lavras (UFLA) |
instacron_str |
UFLA |
institution |
UFLA |
reponame_str |
Repositório Institucional da UFLA |
collection |
Repositório Institucional da UFLA |
repository.name.fl_str_mv |
Repositório Institucional da UFLA - Universidade Federal de Lavras (UFLA) |
repository.mail.fl_str_mv |
nivaldo@ufla.br || repositorio.biblioteca@ufla.br |
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1815439363794796544 |