Use of sugarcane bagasse in natura to removal remazol red dye
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Caderno de Ciências Agrárias (Online) |
Texto Completo: | https://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603 |
Resumo: | In the present article, the feasibility of sugarcane bagasse for the treatment of a synthetic solution of Remazol Vermelho was investigated. For this, a 2² factorial design was performed by varying the pH and mass of the biosorbent in response to the adsorption efficiency, and it was verified that the best adsorption conditions are in acidic pH and lower material mass values. The characterization of the biosorbent was carried out by the pH of the point of zero charge point (PZC), where it was observed that the value was close to 6.00. Infrared spectroscopy (FTIR) data showed the presence of characteristic groups of organic matter and scanning electron microscopy (SEM) showed that the material surface is irregular and porous. A kinetic study was carried out to determine the adsorption mechanism, where the experimental data fit the pseudo-second order model, which indicates that the adsorption occurs by chemosorption. The decontamination percentage reached the value of 72.44% (9.08 ± 0.008 mg g-1) in 30 minutes. In the isotherm study, the experimental data fit the Freundlich model, which indicates a heterogeneous surface. The fixed bed results showed values of 40.63% removal efficiency and 71.38% of column saturation. Therefore, the sugarcane bagasse showed good adsorption capacity for the dye Remazol Vermelho. |
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Use of sugarcane bagasse in natura to removal remazol red dyeUso do bagaço de cana-de-açúcar in natura para remoção do corante Remazol VermelhoAdsorptionBiomassSynthetic dyeAdsorçãoBiomassaCorante sintéticoIn the present article, the feasibility of sugarcane bagasse for the treatment of a synthetic solution of Remazol Vermelho was investigated. For this, a 2² factorial design was performed by varying the pH and mass of the biosorbent in response to the adsorption efficiency, and it was verified that the best adsorption conditions are in acidic pH and lower material mass values. The characterization of the biosorbent was carried out by the pH of the point of zero charge point (PZC), where it was observed that the value was close to 6.00. Infrared spectroscopy (FTIR) data showed the presence of characteristic groups of organic matter and scanning electron microscopy (SEM) showed that the material surface is irregular and porous. A kinetic study was carried out to determine the adsorption mechanism, where the experimental data fit the pseudo-second order model, which indicates that the adsorption occurs by chemosorption. The decontamination percentage reached the value of 72.44% (9.08 ± 0.008 mg g-1) in 30 minutes. In the isotherm study, the experimental data fit the Freundlich model, which indicates a heterogeneous surface. The fixed bed results showed values of 40.63% removal efficiency and 71.38% of column saturation. Therefore, the sugarcane bagasse showed good adsorption capacity for the dye Remazol Vermelho.No presente artigo foi investigado a viabilidade do bagaço de cana-de açúcar para o tratamento de uma solução de Remazol Vermelho. Para isso, um panejamento fatorial 2² foi realizado variando o pH e massa do biossorvente tendo como resposta a eficiência de adsorção, onde foi verificado que as melhores condições de adsorção são em pH ácido e menores valores de massa de material. A caracterização do biossorvente foi realizado pelo pH do ponto de carga zero (PCZ), onde foi observado que o valor foi próximo a 6,00. Os dados de espectroscópia no infravermelho (FTIR), mostrou a presença de grupos caracterísiticos de matéria orgânica, e a microscopia eletrônica de varredura (MEV), mostrou que a superfície do material é irregular e porosa. Foi realizado um estudo cinético para determinar o mecanismo de adsorção, onde os dados experimentais se ajustaram ao modelo de pseudo-segunda ordem, que indica que a adsorção ocorre por quimiossorção. O percentual de descontaminação atingiu o valor de 72,44% (9,08 ± 0,008 mg g-1) em 30 minutos. No estudo de isoterma os dados experimentais se ajustaram ao modelo de Freundlich, que indica uma superfície heterogênea. Os resultados de leito fixo apresentaram valores de 40,63% eficiência de remoção e 71,38% de saturação da coluna. Portanto, o bagaço de cana-de-açúcar apresentou boa capacidade para adsorção do corante Remazol Vermelho.Universidade Federal de Minas Gerais2021-12-31info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdftext/htmlhttps://periodicos.ufmg.br/index.php/ccaufmg/article/view/3560310.35699/2447-6218.2021.35603Agrarian Sciences Journal; Vol. 13 (2021); 1-11Caderno de Ciências Agrárias; v. 13 (2021); 1-112447-62181984-6738reponame:Caderno de Ciências Agrárias (Online)instname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGporhttps://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603/29728https://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603/29729Copyright (c) 2021 Caderno de Ciências Agráriashttp://creativecommons.org/licenses/by-nc-nd/4.0info:eu-repo/semantics/openAccessAnizelli, Pedro RenatoPinto, Victor Lorejan Abreu, Marcela Breves 2022-07-20T21:39:31Zoai:periodicos.ufmg.br:article/35603Revistahttps://periodicos.ufmg.br/index.php/ccaufmgPUBhttps://periodicos.ufmg.br/index.php/ccaufmg/oaiccaufmg@ica.ufmg.br2447-62181984-6738opendoar:2022-07-20T21:39:31Caderno de Ciências Agrárias (Online) - Universidade Federal de Minas Gerais (UFMG)false |
dc.title.none.fl_str_mv |
Use of sugarcane bagasse in natura to removal remazol red dye Uso do bagaço de cana-de-açúcar in natura para remoção do corante Remazol Vermelho |
title |
Use of sugarcane bagasse in natura to removal remazol red dye |
spellingShingle |
Use of sugarcane bagasse in natura to removal remazol red dye Anizelli, Pedro Renato Adsorption Biomass Synthetic dye Adsorção Biomassa Corante sintético |
title_short |
Use of sugarcane bagasse in natura to removal remazol red dye |
title_full |
Use of sugarcane bagasse in natura to removal remazol red dye |
title_fullStr |
Use of sugarcane bagasse in natura to removal remazol red dye |
title_full_unstemmed |
Use of sugarcane bagasse in natura to removal remazol red dye |
title_sort |
Use of sugarcane bagasse in natura to removal remazol red dye |
author |
Anizelli, Pedro Renato |
author_facet |
Anizelli, Pedro Renato Pinto, Victor Lorejan Abreu, Marcela Breves |
author_role |
author |
author2 |
Pinto, Victor Lorejan Abreu, Marcela Breves |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Anizelli, Pedro Renato Pinto, Victor Lorejan Abreu, Marcela Breves |
dc.subject.por.fl_str_mv |
Adsorption Biomass Synthetic dye Adsorção Biomassa Corante sintético |
topic |
Adsorption Biomass Synthetic dye Adsorção Biomassa Corante sintético |
description |
In the present article, the feasibility of sugarcane bagasse for the treatment of a synthetic solution of Remazol Vermelho was investigated. For this, a 2² factorial design was performed by varying the pH and mass of the biosorbent in response to the adsorption efficiency, and it was verified that the best adsorption conditions are in acidic pH and lower material mass values. The characterization of the biosorbent was carried out by the pH of the point of zero charge point (PZC), where it was observed that the value was close to 6.00. Infrared spectroscopy (FTIR) data showed the presence of characteristic groups of organic matter and scanning electron microscopy (SEM) showed that the material surface is irregular and porous. A kinetic study was carried out to determine the adsorption mechanism, where the experimental data fit the pseudo-second order model, which indicates that the adsorption occurs by chemosorption. The decontamination percentage reached the value of 72.44% (9.08 ± 0.008 mg g-1) in 30 minutes. In the isotherm study, the experimental data fit the Freundlich model, which indicates a heterogeneous surface. The fixed bed results showed values of 40.63% removal efficiency and 71.38% of column saturation. Therefore, the sugarcane bagasse showed good adsorption capacity for the dye Remazol Vermelho. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-12-31 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603 10.35699/2447-6218.2021.35603 |
url |
https://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603 |
identifier_str_mv |
10.35699/2447-6218.2021.35603 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603/29728 https://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603/29729 |
dc.rights.driver.fl_str_mv |
Copyright (c) 2021 Caderno de Ciências Agrárias http://creativecommons.org/licenses/by-nc-nd/4.0 info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Copyright (c) 2021 Caderno de Ciências Agrárias http://creativecommons.org/licenses/by-nc-nd/4.0 |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf text/html |
dc.publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
dc.source.none.fl_str_mv |
Agrarian Sciences Journal; Vol. 13 (2021); 1-11 Caderno de Ciências Agrárias; v. 13 (2021); 1-11 2447-6218 1984-6738 reponame:Caderno de Ciências Agrárias (Online) instname:Universidade Federal de Minas Gerais (UFMG) instacron:UFMG |
instname_str |
Universidade Federal de Minas Gerais (UFMG) |
instacron_str |
UFMG |
institution |
UFMG |
reponame_str |
Caderno de Ciências Agrárias (Online) |
collection |
Caderno de Ciências Agrárias (Online) |
repository.name.fl_str_mv |
Caderno de Ciências Agrárias (Online) - Universidade Federal de Minas Gerais (UFMG) |
repository.mail.fl_str_mv |
ccaufmg@ica.ufmg.br |
_version_ |
1797042441997516800 |