Use of sugarcane bagasse in natura to removal remazol red dye

Detalhes bibliográficos
Autor(a) principal: Anizelli, Pedro Renato
Data de Publicação: 2021
Outros Autores: Pinto, Victor Lorejan, Abreu, Marcela Breves
Tipo de documento: Artigo
Idioma: por
Título da fonte: Caderno de Ciências Agrárias (Online)
Texto Completo: https://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603
Resumo: In the present article, the feasibility of sugarcane bagasse for the treatment of a synthetic solution of Remazol Vermelho was investigated. For this, a 2² factorial design was performed by varying the pH and mass of the biosorbent in response to the adsorption efficiency, and it was verified that the best adsorption conditions are in acidic pH and lower material mass values. The characterization of the biosorbent was carried out by the pH of the point of zero charge point (PZC), where it was observed that the value was close to 6.00. Infrared spectroscopy (FTIR) data showed the presence of characteristic groups of organic matter and scanning electron microscopy (SEM) showed that the material surface is irregular and porous. A kinetic study was carried out to determine the adsorption mechanism, where the experimental data fit the pseudo-second order model, which indicates that the adsorption occurs by chemosorption. The decontamination percentage reached the value of 72.44% (9.08 ± 0.008 mg g-1) in 30 minutes. In the isotherm study, the experimental data fit the Freundlich model, which indicates a heterogeneous surface. The fixed bed results showed values of 40.63% removal efficiency and 71.38% of column saturation. Therefore, the sugarcane bagasse showed good adsorption capacity for the dye Remazol Vermelho.
id UFMG-1_ea751a8e8fbd9acb20dbc1c9f6f6dea7
oai_identifier_str oai:periodicos.ufmg.br:article/35603
network_acronym_str UFMG-1
network_name_str Caderno de Ciências Agrárias (Online)
repository_id_str
spelling Use of sugarcane bagasse in natura to removal remazol red dyeUso do bagaço de cana-de-açúcar in natura para remoção do corante Remazol VermelhoAdsorptionBiomassSynthetic dyeAdsorçãoBiomassaCorante sintéticoIn the present article, the feasibility of sugarcane bagasse for the treatment of a synthetic solution of Remazol Vermelho was investigated. For this, a 2² factorial design was performed by varying the pH and mass of the biosorbent in response to the adsorption efficiency, and it was verified that the best adsorption conditions are in acidic pH and lower material mass values. The characterization of the biosorbent was carried out by the pH of the point of zero charge point (PZC), where it was observed that the value was close to 6.00. Infrared spectroscopy (FTIR) data showed the presence of characteristic groups of organic matter and scanning electron microscopy (SEM) showed that the material surface is irregular and porous. A kinetic study was carried out to determine the adsorption mechanism, where the experimental data fit the pseudo-second order model, which indicates that the adsorption occurs by chemosorption. The decontamination percentage reached the value of 72.44% (9.08 ± 0.008 mg g-1) in 30 minutes. In the isotherm study, the experimental data fit the Freundlich model, which indicates a heterogeneous surface. The fixed bed results showed values of 40.63% removal efficiency and 71.38% of column saturation. Therefore, the sugarcane bagasse showed good adsorption capacity for the dye Remazol Vermelho.No presente artigo foi investigado a viabilidade do bagaço de cana-de açúcar para o tratamento de uma solução de Remazol Vermelho. Para isso, um panejamento fatorial 2² foi realizado variando o pH e massa do biossorvente tendo como resposta a eficiência de adsorção, onde foi verificado que as melhores condições de adsorção são em pH ácido e menores valores de massa de material. A caracterização do biossorvente foi realizado pelo pH do ponto de carga zero (PCZ), onde foi observado que o valor foi próximo a 6,00. Os dados de espectroscópia no infravermelho (FTIR), mostrou a presença de grupos caracterísiticos de matéria orgânica, e a microscopia eletrônica de varredura (MEV), mostrou que a superfície do material é irregular e porosa. Foi realizado um estudo cinético para determinar o mecanismo de adsorção, onde os dados experimentais se ajustaram ao modelo de pseudo-segunda ordem, que indica que a adsorção ocorre por quimiossorção. O percentual de descontaminação atingiu o valor de 72,44% (9,08 ± 0,008 mg g-1) em 30 minutos. No estudo de isoterma os dados experimentais se ajustaram ao modelo de Freundlich, que indica uma superfície heterogênea. Os resultados de leito fixo apresentaram valores de 40,63% eficiência de remoção e 71,38% de saturação da coluna. Portanto, o bagaço de cana-de-açúcar apresentou boa capacidade para adsorção do corante Remazol Vermelho.Universidade Federal de Minas Gerais2021-12-31info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdftext/htmlhttps://periodicos.ufmg.br/index.php/ccaufmg/article/view/3560310.35699/2447-6218.2021.35603Agrarian Sciences Journal; Vol. 13 (2021); 1-11Caderno de Ciências Agrárias; v. 13 (2021); 1-112447-62181984-6738reponame:Caderno de Ciências Agrárias (Online)instname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGporhttps://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603/29728https://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603/29729Copyright (c) 2021 Caderno de Ciências Agráriashttp://creativecommons.org/licenses/by-nc-nd/4.0info:eu-repo/semantics/openAccessAnizelli, Pedro RenatoPinto, Victor Lorejan Abreu, Marcela Breves 2022-07-20T21:39:31Zoai:periodicos.ufmg.br:article/35603Revistahttps://periodicos.ufmg.br/index.php/ccaufmgPUBhttps://periodicos.ufmg.br/index.php/ccaufmg/oaiccaufmg@ica.ufmg.br2447-62181984-6738opendoar:2022-07-20T21:39:31Caderno de Ciências Agrárias (Online) - Universidade Federal de Minas Gerais (UFMG)false
dc.title.none.fl_str_mv Use of sugarcane bagasse in natura to removal remazol red dye
Uso do bagaço de cana-de-açúcar in natura para remoção do corante Remazol Vermelho
title Use of sugarcane bagasse in natura to removal remazol red dye
spellingShingle Use of sugarcane bagasse in natura to removal remazol red dye
Anizelli, Pedro Renato
Adsorption
Biomass
Synthetic dye
Adsorção
Biomassa
Corante sintético
title_short Use of sugarcane bagasse in natura to removal remazol red dye
title_full Use of sugarcane bagasse in natura to removal remazol red dye
title_fullStr Use of sugarcane bagasse in natura to removal remazol red dye
title_full_unstemmed Use of sugarcane bagasse in natura to removal remazol red dye
title_sort Use of sugarcane bagasse in natura to removal remazol red dye
author Anizelli, Pedro Renato
author_facet Anizelli, Pedro Renato
Pinto, Victor Lorejan
Abreu, Marcela Breves
author_role author
author2 Pinto, Victor Lorejan
Abreu, Marcela Breves
author2_role author
author
dc.contributor.author.fl_str_mv Anizelli, Pedro Renato
Pinto, Victor Lorejan
Abreu, Marcela Breves
dc.subject.por.fl_str_mv Adsorption
Biomass
Synthetic dye
Adsorção
Biomassa
Corante sintético
topic Adsorption
Biomass
Synthetic dye
Adsorção
Biomassa
Corante sintético
description In the present article, the feasibility of sugarcane bagasse for the treatment of a synthetic solution of Remazol Vermelho was investigated. For this, a 2² factorial design was performed by varying the pH and mass of the biosorbent in response to the adsorption efficiency, and it was verified that the best adsorption conditions are in acidic pH and lower material mass values. The characterization of the biosorbent was carried out by the pH of the point of zero charge point (PZC), where it was observed that the value was close to 6.00. Infrared spectroscopy (FTIR) data showed the presence of characteristic groups of organic matter and scanning electron microscopy (SEM) showed that the material surface is irregular and porous. A kinetic study was carried out to determine the adsorption mechanism, where the experimental data fit the pseudo-second order model, which indicates that the adsorption occurs by chemosorption. The decontamination percentage reached the value of 72.44% (9.08 ± 0.008 mg g-1) in 30 minutes. In the isotherm study, the experimental data fit the Freundlich model, which indicates a heterogeneous surface. The fixed bed results showed values of 40.63% removal efficiency and 71.38% of column saturation. Therefore, the sugarcane bagasse showed good adsorption capacity for the dye Remazol Vermelho.
publishDate 2021
dc.date.none.fl_str_mv 2021-12-31
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603
10.35699/2447-6218.2021.35603
url https://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603
identifier_str_mv 10.35699/2447-6218.2021.35603
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv https://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603/29728
https://periodicos.ufmg.br/index.php/ccaufmg/article/view/35603/29729
dc.rights.driver.fl_str_mv Copyright (c) 2021 Caderno de Ciências Agrárias
http://creativecommons.org/licenses/by-nc-nd/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Copyright (c) 2021 Caderno de Ciências Agrárias
http://creativecommons.org/licenses/by-nc-nd/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
text/html
dc.publisher.none.fl_str_mv Universidade Federal de Minas Gerais
publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.source.none.fl_str_mv Agrarian Sciences Journal; Vol. 13 (2021); 1-11
Caderno de Ciências Agrárias; v. 13 (2021); 1-11
2447-6218
1984-6738
reponame:Caderno de Ciências Agrárias (Online)
instname:Universidade Federal de Minas Gerais (UFMG)
instacron:UFMG
instname_str Universidade Federal de Minas Gerais (UFMG)
instacron_str UFMG
institution UFMG
reponame_str Caderno de Ciências Agrárias (Online)
collection Caderno de Ciências Agrárias (Online)
repository.name.fl_str_mv Caderno de Ciências Agrárias (Online) - Universidade Federal de Minas Gerais (UFMG)
repository.mail.fl_str_mv ccaufmg@ica.ufmg.br
_version_ 1797042441997516800