Microwave assisted ultra-fast method to synthesize carbonate-phosphates, Na3MCO3PO4 (M = Mn, Fe, Co, Ni) - relevant materials applied in sodium-ion batteries

Detalhes bibliográficos
Autor(a) principal: Demétrio Abreu Sena Costa
Data de Publicação: 2020
Outros Autores: Lorena Almeida Cadête Costa, João Otávio de Sousa Mendes, Wagner da Nova Mussel, José Domingos Ardisson, Luciano Andrey Montoro
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFMG
Texto Completo: http://dx.doi.org/10.21577/0103-5053.20190154
http://hdl.handle.net/1843/50606
https://orcid.org/0000-0003-3597-2910
https://orcid.org/0000-0002-8632-780X
https://orcid.org/0000-0002-9768-9830
https://orcid.org/0000-0002-5615-3482
https://orcid.org/0000-0002-5157-3971
Resumo: FAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas Gerais
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spelling 2023-03-02T15:32:04Z2023-03-02T15:32:04Z2020-01311175185http://dx.doi.org/10.21577/0103-5053.201901541678-4790http://hdl.handle.net/1843/50606https://orcid.org/0000-0003-3597-2910https://orcid.org/0000-0002-8632-780Xhttps://orcid.org/0000-0002-9768-9830https://orcid.org/0000-0002-5615-3482https://orcid.org/0000-0002-5157-3971FAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas GeraisCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível SuperiorOutra AgênciaAlthough largely used in mobiles and electric vehicles applications, insertion batteries based on Li-ion technology are high-cost devices. These applications require high-performance energy storage systems with high-energy and high-power densities, which are better attained by Li-ion technology. However, stationary applications such as power plants and uninterruptible power supplies (UPS) mainly require low-cost energy storage devices. In this scenario Na-ion insertion batteries feature as a cheaper option for such applications. Among the several compounds for use as cathode in Na-batteries, a largely studied class of compounds are the sodium-carbonate-phosphates, Na3MCO3PO4 (M = Mn, Fe, Co or Ni), with structure analogue to the mineral sidorenkite. In this work, it was developed a new microwave-assisted hydrothermal method as an ultra-fast way to prepare sodium-carbonate-phosphate compounds. This methodology results in high-quality materials with general formula Na3MCO3PO4 (M = Mn, Fe, Co or Ni) upon only 5 min processing time. Characterization techniques indicate highly ordered materials with sidorenkite-like phase and different morphologies or crystal habits, including plates, rods, and a ‘starfruit’ shape. As a proof-of-application the Mn-based material was evaluated from electrochemical tests for Na+ insertion reactions. The obtained results evidence initial discharge capacity of 107 mA h g-¹ with good reversible capacity (65 mA h g -¹) after several charge/discharge cycles.engUniversidade Federal de Minas GeraisUFMGBrasilCOLTEC - COLEGIO TECNICOICX - DEPARTAMENTO DE QUÍMICAQuímica analíticaFísico-químicaAnálise eletroquímicaBateriasMinerais metálicosCompostos de sódioRietveld, Método deRaios X - DifraçãoMicroscopia eletrônica de varreduraAnálise térmicaEspectrometria de massaTermogravimetriaMossbauer, Espectroscopia deMicrowave assistedCarbonate-phosphatesRelevant materials applied in sodium-ion batteriesSidorenkiteSodium-ion insertionMicrowaveSolvothermal methodMicrowave assisted ultra-fast method to synthesize carbonate-phosphates, Na3MCO3PO4 (M = Mn, Fe, Co, Ni) - relevant materials applied in sodium-ion batteriesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://jbcs.sbq.org.br/default.asp?ed=293Demétrio Abreu Sena CostaLorena Almeida Cadête CostaJoão Otávio de Sousa MendesWagner da Nova MusselJosé Domingos ArdissonLuciano Andrey Montoroapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGORIGINALMicrowave assisted ultra-fast method to synthesize carbonate-phosphates.pdfMicrowave assisted ultra-fast method to synthesize carbonate-phosphates.pdfapplication/pdf8795439https://repositorio.ufmg.br/bitstream/1843/50606/2/Microwave%20assisted%20ultra-fast%20method%20to%20synthesize%20carbonate-phosphates.pdf63cc1b58d7bb769f8ca7982afb685ad6MD52LICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/50606/1/License.txtfa505098d172de0bc8864fc1287ffe22MD511843/506062023-03-02 12:32:04.376oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2023-03-02T15:32:04Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false
dc.title.pt_BR.fl_str_mv Microwave assisted ultra-fast method to synthesize carbonate-phosphates, Na3MCO3PO4 (M = Mn, Fe, Co, Ni) - relevant materials applied in sodium-ion batteries
title Microwave assisted ultra-fast method to synthesize carbonate-phosphates, Na3MCO3PO4 (M = Mn, Fe, Co, Ni) - relevant materials applied in sodium-ion batteries
spellingShingle Microwave assisted ultra-fast method to synthesize carbonate-phosphates, Na3MCO3PO4 (M = Mn, Fe, Co, Ni) - relevant materials applied in sodium-ion batteries
Demétrio Abreu Sena Costa
Microwave assisted
Carbonate-phosphates
Relevant materials applied in sodium-ion batteries
Sidorenkite
Sodium-ion insertion
Microwave
Solvothermal method
Química analítica
Físico-química
Análise eletroquímica
Baterias
Minerais metálicos
Compostos de sódio
Rietveld, Método de
Raios X - Difração
Microscopia eletrônica de varredura
Análise térmica
Espectrometria de massa
Termogravimetria
Mossbauer, Espectroscopia de
title_short Microwave assisted ultra-fast method to synthesize carbonate-phosphates, Na3MCO3PO4 (M = Mn, Fe, Co, Ni) - relevant materials applied in sodium-ion batteries
title_full Microwave assisted ultra-fast method to synthesize carbonate-phosphates, Na3MCO3PO4 (M = Mn, Fe, Co, Ni) - relevant materials applied in sodium-ion batteries
title_fullStr Microwave assisted ultra-fast method to synthesize carbonate-phosphates, Na3MCO3PO4 (M = Mn, Fe, Co, Ni) - relevant materials applied in sodium-ion batteries
title_full_unstemmed Microwave assisted ultra-fast method to synthesize carbonate-phosphates, Na3MCO3PO4 (M = Mn, Fe, Co, Ni) - relevant materials applied in sodium-ion batteries
title_sort Microwave assisted ultra-fast method to synthesize carbonate-phosphates, Na3MCO3PO4 (M = Mn, Fe, Co, Ni) - relevant materials applied in sodium-ion batteries
author Demétrio Abreu Sena Costa
author_facet Demétrio Abreu Sena Costa
Lorena Almeida Cadête Costa
João Otávio de Sousa Mendes
Wagner da Nova Mussel
José Domingos Ardisson
Luciano Andrey Montoro
author_role author
author2 Lorena Almeida Cadête Costa
João Otávio de Sousa Mendes
Wagner da Nova Mussel
José Domingos Ardisson
Luciano Andrey Montoro
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Demétrio Abreu Sena Costa
Lorena Almeida Cadête Costa
João Otávio de Sousa Mendes
Wagner da Nova Mussel
José Domingos Ardisson
Luciano Andrey Montoro
dc.subject.por.fl_str_mv Microwave assisted
Carbonate-phosphates
Relevant materials applied in sodium-ion batteries
Sidorenkite
Sodium-ion insertion
Microwave
Solvothermal method
topic Microwave assisted
Carbonate-phosphates
Relevant materials applied in sodium-ion batteries
Sidorenkite
Sodium-ion insertion
Microwave
Solvothermal method
Química analítica
Físico-química
Análise eletroquímica
Baterias
Minerais metálicos
Compostos de sódio
Rietveld, Método de
Raios X - Difração
Microscopia eletrônica de varredura
Análise térmica
Espectrometria de massa
Termogravimetria
Mossbauer, Espectroscopia de
dc.subject.other.pt_BR.fl_str_mv Química analítica
Físico-química
Análise eletroquímica
Baterias
Minerais metálicos
Compostos de sódio
Rietveld, Método de
Raios X - Difração
Microscopia eletrônica de varredura
Análise térmica
Espectrometria de massa
Termogravimetria
Mossbauer, Espectroscopia de
description FAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas Gerais
publishDate 2020
dc.date.issued.fl_str_mv 2020-01
dc.date.accessioned.fl_str_mv 2023-03-02T15:32:04Z
dc.date.available.fl_str_mv 2023-03-02T15:32:04Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1843/50606
dc.identifier.doi.pt_BR.fl_str_mv http://dx.doi.org/10.21577/0103-5053.20190154
dc.identifier.issn.pt_BR.fl_str_mv 1678-4790
dc.identifier.orcid.pt_BR.fl_str_mv https://orcid.org/0000-0003-3597-2910
https://orcid.org/0000-0002-8632-780X
https://orcid.org/0000-0002-9768-9830
https://orcid.org/0000-0002-5615-3482
https://orcid.org/0000-0002-5157-3971
url http://dx.doi.org/10.21577/0103-5053.20190154
http://hdl.handle.net/1843/50606
https://orcid.org/0000-0003-3597-2910
https://orcid.org/0000-0002-8632-780X
https://orcid.org/0000-0002-9768-9830
https://orcid.org/0000-0002-5615-3482
https://orcid.org/0000-0002-5157-3971
identifier_str_mv 1678-4790
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.publisher.initials.fl_str_mv UFMG
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv COLTEC - COLEGIO TECNICO
ICX - DEPARTAMENTO DE QUÍMICA
publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFMG
instname:Universidade Federal de Minas Gerais (UFMG)
instacron:UFMG
instname_str Universidade Federal de Minas Gerais (UFMG)
instacron_str UFMG
institution UFMG
reponame_str Repositório Institucional da UFMG
collection Repositório Institucional da UFMG
bitstream.url.fl_str_mv https://repositorio.ufmg.br/bitstream/1843/50606/2/Microwave%20assisted%20ultra-fast%20method%20to%20synthesize%20carbonate-phosphates.pdf
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