Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil

Detalhes bibliográficos
Autor(a) principal: Júlia de Barros Dias Moreira
Data de Publicação: 2019
Outros Autores: Daniel Bastos de Rezende, Sérgio de Oliveira, Vânya Márcia Duarte Pasa
Tipo de documento: Artigo de conferência
Idioma: eng
Título da fonte: Repositório Institucional da UFMG
Texto Completo: http://hdl.handle.net/1843/55430
https://orcid.org/0000-0002-6635-558X
https://orcid.org/0000-0002-5638-8249
https://orcid.org/0000-0002-2510-3845
Resumo: Drop-in biofuels are composed by synthetic bio-hydrocarbons and are the only alternative to substitute fossil jet fuel, since they can meet to rigid specifications required to aviation fuels. This type of biofuels can be produced by different routes. Hydroprocessing can produce bio-hydrocarbons from vegetable oils and animal fats, in the presence of a catalyst, at high temperatures and pressures. The efficiency and cost of this process is related to the utilization of an efficient catalyst and a cheap raw material. In this work, it was investigated the utilization of a carbon nanotube supported platinum (Pt/MWCNT) catalyst to convert poultry viscera oil, a waste from chicken meat production, into bio hydrocarbons. The results of reactions with 5 wt% of catalyst, at 350°C and under 30 bar H2 showed the Pt/MWCNT efficiency to promote deoxygenation reactions, while MWCNTs appear to have catalytic activity to triglycerides cracking reactions. Therefore, the use of this nanocatalyst and poultry oil seems to be a promising alternative to produce biojet fuels. However, to achieve higher degree of deoxygenation, it is necessary to study the influence of some process variables, such as pressure, time reaction and H2/raw material ratio.
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spelling 2023-06-27T18:51:03Z2023-06-27T18:51:03Z20191http://hdl.handle.net/1843/55430https://orcid.org/0000-0002-6635-558Xhttps://orcid.org/0000-0002-5638-8249https://orcid.org/0000-0002-2510-3845Drop-in biofuels are composed by synthetic bio-hydrocarbons and are the only alternative to substitute fossil jet fuel, since they can meet to rigid specifications required to aviation fuels. This type of biofuels can be produced by different routes. Hydroprocessing can produce bio-hydrocarbons from vegetable oils and animal fats, in the presence of a catalyst, at high temperatures and pressures. The efficiency and cost of this process is related to the utilization of an efficient catalyst and a cheap raw material. In this work, it was investigated the utilization of a carbon nanotube supported platinum (Pt/MWCNT) catalyst to convert poultry viscera oil, a waste from chicken meat production, into bio hydrocarbons. The results of reactions with 5 wt% of catalyst, at 350°C and under 30 bar H2 showed the Pt/MWCNT efficiency to promote deoxygenation reactions, while MWCNTs appear to have catalytic activity to triglycerides cracking reactions. Therefore, the use of this nanocatalyst and poultry oil seems to be a promising alternative to produce biojet fuels. However, to achieve higher degree of deoxygenation, it is necessary to study the influence of some process variables, such as pressure, time reaction and H2/raw material ratio.engUniversidade Federal de Minas GeraisUFMGBrasilENG - DEPARTAMENTO DE ENGENHARIA QUÍMICAICX - DEPARTAMENTO DE FÍSICAICX - DEPARTAMENTO DE QUÍMICACongresso da Rede Brasileira de Bioquerosene e Hidrocarbonetos Renováveis para AviaçãoNanotubos de carbonoOleos e gordurasBiocombustíveisAviões - CombustíveisCatalisadores de platinaHidrocarbonetosBio-hydrocarbonsDrop-in biofuelsDeoxygenationPoultry oilCarbon nanotubesEvaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oilAvaliação do desempenho de Pt/NTCPM como catalisador para produção de bio hidrocarbonetos a partir de óleo de vísceras de frangoinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjecthttp://www.monferrer.com.br/METALLUM/bioquerose/PDF/02-027.pdfJúlia de Barros Dias MoreiraDaniel Bastos de RezendeSérgio de OliveiraVânya Márcia Duarte Pasaapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/55430/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALEVALUATION OF PT-MWCNT AS CATALYST TO PRODUCE.pdfEVALUATION OF PT-MWCNT AS CATALYST TO PRODUCE.pdfapplication/pdf333449https://repositorio.ufmg.br/bitstream/1843/55430/2/EVALUATION%20OF%20PT-MWCNT%20AS%20CATALYST%20TO%20PRODUCE.pdfbfe0d858feea0ba2bd6bdf47cab39f94MD521843/554302023-07-12 19:04:01.265oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2023-07-12T22:04:01Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false
dc.title.pt_BR.fl_str_mv Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil
dc.title.alternative.pt_BR.fl_str_mv Avaliação do desempenho de Pt/NTCPM como catalisador para produção de bio hidrocarbonetos a partir de óleo de vísceras de frango
title Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil
spellingShingle Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil
Júlia de Barros Dias Moreira
Bio-hydrocarbons
Drop-in biofuels
Deoxygenation
Poultry oil
Carbon nanotubes
Nanotubos de carbono
Oleos e gorduras
Biocombustíveis
Aviões - Combustíveis
Catalisadores de platina
Hidrocarbonetos
title_short Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil
title_full Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil
title_fullStr Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil
title_full_unstemmed Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil
title_sort Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil
author Júlia de Barros Dias Moreira
author_facet Júlia de Barros Dias Moreira
Daniel Bastos de Rezende
Sérgio de Oliveira
Vânya Márcia Duarte Pasa
author_role author
author2 Daniel Bastos de Rezende
Sérgio de Oliveira
Vânya Márcia Duarte Pasa
author2_role author
author
author
dc.contributor.author.fl_str_mv Júlia de Barros Dias Moreira
Daniel Bastos de Rezende
Sérgio de Oliveira
Vânya Márcia Duarte Pasa
dc.subject.por.fl_str_mv Bio-hydrocarbons
Drop-in biofuels
Deoxygenation
Poultry oil
Carbon nanotubes
topic Bio-hydrocarbons
Drop-in biofuels
Deoxygenation
Poultry oil
Carbon nanotubes
Nanotubos de carbono
Oleos e gorduras
Biocombustíveis
Aviões - Combustíveis
Catalisadores de platina
Hidrocarbonetos
dc.subject.other.pt_BR.fl_str_mv Nanotubos de carbono
Oleos e gorduras
Biocombustíveis
Aviões - Combustíveis
Catalisadores de platina
Hidrocarbonetos
description Drop-in biofuels are composed by synthetic bio-hydrocarbons and are the only alternative to substitute fossil jet fuel, since they can meet to rigid specifications required to aviation fuels. This type of biofuels can be produced by different routes. Hydroprocessing can produce bio-hydrocarbons from vegetable oils and animal fats, in the presence of a catalyst, at high temperatures and pressures. The efficiency and cost of this process is related to the utilization of an efficient catalyst and a cheap raw material. In this work, it was investigated the utilization of a carbon nanotube supported platinum (Pt/MWCNT) catalyst to convert poultry viscera oil, a waste from chicken meat production, into bio hydrocarbons. The results of reactions with 5 wt% of catalyst, at 350°C and under 30 bar H2 showed the Pt/MWCNT efficiency to promote deoxygenation reactions, while MWCNTs appear to have catalytic activity to triglycerides cracking reactions. Therefore, the use of this nanocatalyst and poultry oil seems to be a promising alternative to produce biojet fuels. However, to achieve higher degree of deoxygenation, it is necessary to study the influence of some process variables, such as pressure, time reaction and H2/raw material ratio.
publishDate 2019
dc.date.issued.fl_str_mv 2019
dc.date.accessioned.fl_str_mv 2023-06-27T18:51:03Z
dc.date.available.fl_str_mv 2023-06-27T18:51:03Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/conferenceObject
format conferenceObject
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1843/55430
dc.identifier.orcid.pt_BR.fl_str_mv https://orcid.org/0000-0002-6635-558X
https://orcid.org/0000-0002-5638-8249
https://orcid.org/0000-0002-2510-3845
url http://hdl.handle.net/1843/55430
https://orcid.org/0000-0002-6635-558X
https://orcid.org/0000-0002-5638-8249
https://orcid.org/0000-0002-2510-3845
dc.language.iso.fl_str_mv eng
language eng
dc.relation.ispartof.none.fl_str_mv Congresso da Rede Brasileira de Bioquerosene e Hidrocarbonetos Renováveis para Aviação
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.publisher.initials.fl_str_mv UFMG
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv ENG - DEPARTAMENTO DE ENGENHARIA QUÍMICA
ICX - DEPARTAMENTO DE FÍSICA
ICX - DEPARTAMENTO DE QUÍMICA
publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFMG
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