Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , |
Tipo de documento: | Artigo de conferência |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFMG |
Texto Completo: | http://hdl.handle.net/1843/55430 https://orcid.org/0000-0002-6635-558X https://orcid.org/0000-0002-5638-8249 https://orcid.org/0000-0002-2510-3845 |
Resumo: | Drop-in biofuels are composed by synthetic bio-hydrocarbons and are the only alternative to substitute fossil jet fuel, since they can meet to rigid specifications required to aviation fuels. This type of biofuels can be produced by different routes. Hydroprocessing can produce bio-hydrocarbons from vegetable oils and animal fats, in the presence of a catalyst, at high temperatures and pressures. The efficiency and cost of this process is related to the utilization of an efficient catalyst and a cheap raw material. In this work, it was investigated the utilization of a carbon nanotube supported platinum (Pt/MWCNT) catalyst to convert poultry viscera oil, a waste from chicken meat production, into bio hydrocarbons. The results of reactions with 5 wt% of catalyst, at 350°C and under 30 bar H2 showed the Pt/MWCNT efficiency to promote deoxygenation reactions, while MWCNTs appear to have catalytic activity to triglycerides cracking reactions. Therefore, the use of this nanocatalyst and poultry oil seems to be a promising alternative to produce biojet fuels. However, to achieve higher degree of deoxygenation, it is necessary to study the influence of some process variables, such as pressure, time reaction and H2/raw material ratio. |
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2023-06-27T18:51:03Z2023-06-27T18:51:03Z20191http://hdl.handle.net/1843/55430https://orcid.org/0000-0002-6635-558Xhttps://orcid.org/0000-0002-5638-8249https://orcid.org/0000-0002-2510-3845Drop-in biofuels are composed by synthetic bio-hydrocarbons and are the only alternative to substitute fossil jet fuel, since they can meet to rigid specifications required to aviation fuels. This type of biofuels can be produced by different routes. Hydroprocessing can produce bio-hydrocarbons from vegetable oils and animal fats, in the presence of a catalyst, at high temperatures and pressures. The efficiency and cost of this process is related to the utilization of an efficient catalyst and a cheap raw material. In this work, it was investigated the utilization of a carbon nanotube supported platinum (Pt/MWCNT) catalyst to convert poultry viscera oil, a waste from chicken meat production, into bio hydrocarbons. The results of reactions with 5 wt% of catalyst, at 350°C and under 30 bar H2 showed the Pt/MWCNT efficiency to promote deoxygenation reactions, while MWCNTs appear to have catalytic activity to triglycerides cracking reactions. Therefore, the use of this nanocatalyst and poultry oil seems to be a promising alternative to produce biojet fuels. However, to achieve higher degree of deoxygenation, it is necessary to study the influence of some process variables, such as pressure, time reaction and H2/raw material ratio.engUniversidade Federal de Minas GeraisUFMGBrasilENG - DEPARTAMENTO DE ENGENHARIA QUÍMICAICX - DEPARTAMENTO DE FÍSICAICX - DEPARTAMENTO DE QUÍMICACongresso da Rede Brasileira de Bioquerosene e Hidrocarbonetos Renováveis para AviaçãoNanotubos de carbonoOleos e gordurasBiocombustíveisAviões - CombustíveisCatalisadores de platinaHidrocarbonetosBio-hydrocarbonsDrop-in biofuelsDeoxygenationPoultry oilCarbon nanotubesEvaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oilAvaliação do desempenho de Pt/NTCPM como catalisador para produção de bio hidrocarbonetos a partir de óleo de vísceras de frangoinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/conferenceObjecthttp://www.monferrer.com.br/METALLUM/bioquerose/PDF/02-027.pdfJúlia de Barros Dias MoreiraDaniel Bastos de RezendeSérgio de OliveiraVânya Márcia Duarte Pasaapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/55430/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALEVALUATION OF PT-MWCNT AS CATALYST TO PRODUCE.pdfEVALUATION OF PT-MWCNT AS CATALYST TO PRODUCE.pdfapplication/pdf333449https://repositorio.ufmg.br/bitstream/1843/55430/2/EVALUATION%20OF%20PT-MWCNT%20AS%20CATALYST%20TO%20PRODUCE.pdfbfe0d858feea0ba2bd6bdf47cab39f94MD521843/554302023-07-12 19:04:01.265oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2023-07-12T22:04:01Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false |
dc.title.pt_BR.fl_str_mv |
Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil |
dc.title.alternative.pt_BR.fl_str_mv |
Avaliação do desempenho de Pt/NTCPM como catalisador para produção de bio hidrocarbonetos a partir de óleo de vísceras de frango |
title |
Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil |
spellingShingle |
Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil Júlia de Barros Dias Moreira Bio-hydrocarbons Drop-in biofuels Deoxygenation Poultry oil Carbon nanotubes Nanotubos de carbono Oleos e gorduras Biocombustíveis Aviões - Combustíveis Catalisadores de platina Hidrocarbonetos |
title_short |
Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil |
title_full |
Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil |
title_fullStr |
Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil |
title_full_unstemmed |
Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil |
title_sort |
Evaluation of Pt/MWCNT as catalyst to produce bio-hydrocarbons from poultry viscera oil |
author |
Júlia de Barros Dias Moreira |
author_facet |
Júlia de Barros Dias Moreira Daniel Bastos de Rezende Sérgio de Oliveira Vânya Márcia Duarte Pasa |
author_role |
author |
author2 |
Daniel Bastos de Rezende Sérgio de Oliveira Vânya Márcia Duarte Pasa |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Júlia de Barros Dias Moreira Daniel Bastos de Rezende Sérgio de Oliveira Vânya Márcia Duarte Pasa |
dc.subject.por.fl_str_mv |
Bio-hydrocarbons Drop-in biofuels Deoxygenation Poultry oil Carbon nanotubes |
topic |
Bio-hydrocarbons Drop-in biofuels Deoxygenation Poultry oil Carbon nanotubes Nanotubos de carbono Oleos e gorduras Biocombustíveis Aviões - Combustíveis Catalisadores de platina Hidrocarbonetos |
dc.subject.other.pt_BR.fl_str_mv |
Nanotubos de carbono Oleos e gorduras Biocombustíveis Aviões - Combustíveis Catalisadores de platina Hidrocarbonetos |
description |
Drop-in biofuels are composed by synthetic bio-hydrocarbons and are the only alternative to substitute fossil jet fuel, since they can meet to rigid specifications required to aviation fuels. This type of biofuels can be produced by different routes. Hydroprocessing can produce bio-hydrocarbons from vegetable oils and animal fats, in the presence of a catalyst, at high temperatures and pressures. The efficiency and cost of this process is related to the utilization of an efficient catalyst and a cheap raw material. In this work, it was investigated the utilization of a carbon nanotube supported platinum (Pt/MWCNT) catalyst to convert poultry viscera oil, a waste from chicken meat production, into bio hydrocarbons. The results of reactions with 5 wt% of catalyst, at 350°C and under 30 bar H2 showed the Pt/MWCNT efficiency to promote deoxygenation reactions, while MWCNTs appear to have catalytic activity to triglycerides cracking reactions. Therefore, the use of this nanocatalyst and poultry oil seems to be a promising alternative to produce biojet fuels. However, to achieve higher degree of deoxygenation, it is necessary to study the influence of some process variables, such as pressure, time reaction and H2/raw material ratio. |
publishDate |
2019 |
dc.date.issued.fl_str_mv |
2019 |
dc.date.accessioned.fl_str_mv |
2023-06-27T18:51:03Z |
dc.date.available.fl_str_mv |
2023-06-27T18:51:03Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/conferenceObject |
format |
conferenceObject |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1843/55430 |
dc.identifier.orcid.pt_BR.fl_str_mv |
https://orcid.org/0000-0002-6635-558X https://orcid.org/0000-0002-5638-8249 https://orcid.org/0000-0002-2510-3845 |
url |
http://hdl.handle.net/1843/55430 https://orcid.org/0000-0002-6635-558X https://orcid.org/0000-0002-5638-8249 https://orcid.org/0000-0002-2510-3845 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartof.none.fl_str_mv |
Congresso da Rede Brasileira de Bioquerosene e Hidrocarbonetos Renováveis para Aviação |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
dc.publisher.initials.fl_str_mv |
UFMG |
dc.publisher.country.fl_str_mv |
Brasil |
dc.publisher.department.fl_str_mv |
ENG - DEPARTAMENTO DE ENGENHARIA QUÍMICA ICX - DEPARTAMENTO DE FÍSICA ICX - DEPARTAMENTO DE QUÍMICA |
publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFMG instname:Universidade Federal de Minas Gerais (UFMG) instacron:UFMG |
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Universidade Federal de Minas Gerais (UFMG) |
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UFMG |
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