Improving the stability and efficiency of perovskite solar cells by a bidentate anilinium salt
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2022 |
| Outros Autores: | , , , , , , , |
| Tipo de documento: | Artigo |
| Idioma: | eng |
| Título da fonte: | Repositório Institucional da UFMG |
| Texto Completo: | https://doi.org/10.1021/jacsau.2c00151 http://hdl.handle.net/1843/68398 https://orcid.org/0000-0002-1819-0266 https://orcid.org/0000-0001-9253-0401 https://orcid.org/0000-0002-6662-660X https://orcid.org/0000-0002-0024-1651 https://orcid.org/0000-0003-0722-5352 https://orcid.org/0000-0002-0838-7962 |
Resumo: | CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico |
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2024-05-16T13:46:59Z2024-05-16T13:46:59Z20222613061312https://doi.org/10.1021/jacsau.2c001512691-3704http://hdl.handle.net/1843/68398https://orcid.org/0000-0002-1819-0266https://orcid.org/0000-0001-9253-0401https://orcid.org/0000-0002-6662-660Xhttps://orcid.org/0000-0002-0024-1651https://orcid.org/0000-0003-0722-5352https://orcid.org/0000-0002-0838-7962CNPq - Conselho Nacional de Desenvolvimento Científico e TecnológicoFAPESP - Fundação de Amparo à Pesquisa do Estado de São PauloOutra AgênciaWe report improvement in the perovskite solar cell efficiency and stability after passivation with an organic molecule decorated with two anilinium cations. We compare this salt with its neutral analog and found that the change in the electron density distribution upon protonation and the presence of the halide anion are key to explaining the better passivation ability of the salt. In addition, we show that the counteranion has a significant impact on the performance of the device.engUniversidade Federal de Minas GeraisUFMGBrasilICX - DEPARTAMENTO DE QUÍMICAJACS AuCélulas solaresFuncionais de densidadeMoléculasSalDefect passivationStable perovskite solar cellsAggregation-induced luminogenDFT calculationRational synthesisImproving the stability and efficiency of perovskite solar cells by a bidentate anilinium saltinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://pubs.acs.org/doi/10.1021/jacsau.2c00151Lucas ScalonRodrigo SzostakFrancineide Lopes de AraújoKarla Furtado AndrianiJulian Francisco Rama Vieira SilveiraWillian Xerxes Coelho OliveiraJuarez Lopes Ferreira da SilvaCaio Costa OliveiraAna Flávia Nogueiraapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/68398/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALImproving the stability and efficiency of perovskite solar cells by a bidentate anilinium salt.pdfImproving the stability and efficiency of perovskite solar cells by a bidentate anilinium salt.pdfapplication/pdf3322277https://repositorio.ufmg.br/bitstream/1843/68398/2/Improving%20the%20stability%20and%20efficiency%20of%20perovskite%20solar%20cells%20by%20a%20bidentate%20anilinium%20salt.pdfe74b2178ccbd9b3bfb768e9a97ac741cMD521843/683982024-05-16 10:46:59.846oai:repositorio.ufmg.br:1843/68398TElDRU7vv71BIERFIERJU1RSSUJVSe+/ve+/vU8gTu+/vU8tRVhDTFVTSVZBIERPIFJFUE9TSVTvv71SSU8gSU5TVElUVUNJT05BTCBEQSBVRk1HCiAKCkNvbSBhIGFwcmVzZW50Ye+/ve+/vW8gZGVzdGEgbGljZW7vv71hLCB2b2Pvv70gKG8gYXV0b3IgKGVzKSBvdSBvIHRpdHVsYXIgZG9zIGRpcmVpdG9zIGRlIGF1dG9yKSBjb25jZWRlIGFvIFJlcG9zaXTvv71yaW8gSW5zdGl0dWNpb25hbCBkYSBVRk1HIChSSS1VRk1HKSBvIGRpcmVpdG8gbu+/vW8gZXhjbHVzaXZvIGUgaXJyZXZvZ++/vXZlbCBkZSByZXByb2R1emlyIGUvb3UgZGlzdHJpYnVpciBhIHN1YSBwdWJsaWNh77+977+9byAoaW5jbHVpbmRvIG8gcmVzdW1vKSBwb3IgdG9kbyBvIG11bmRvIG5vIGZvcm1hdG8gaW1wcmVzc28gZSBlbGV0cu+/vW5pY28gZSBlbSBxdWFscXVlciBtZWlvLCBpbmNsdWluZG8gb3MgZm9ybWF0b3Mg77+9dWRpbyBvdSB277+9ZGVvLgoKVm9j77+9IGRlY2xhcmEgcXVlIGNvbmhlY2UgYSBwb2zvv710aWNhIGRlIGNvcHlyaWdodCBkYSBlZGl0b3JhIGRvIHNldSBkb2N1bWVudG8gZSBxdWUgY29uaGVjZSBlIGFjZWl0YSBhcyBEaXJldHJpemVzIGRvIFJJLVVGTUcuCgpWb2Pvv70gY29uY29yZGEgcXVlIG8gUmVwb3NpdO+/vXJpbyBJbnN0aXR1Y2lvbmFsIGRhIFVGTUcgcG9kZSwgc2VtIGFsdGVyYXIgbyBjb250Ze+/vWRvLCB0cmFuc3BvciBhIHN1YSBwdWJsaWNh77+977+9byBwYXJhIHF1YWxxdWVyIG1laW8gb3UgZm9ybWF0byBwYXJhIGZpbnMgZGUgcHJlc2VydmHvv73vv71vLgoKVm9j77+9IHRhbWLvv71tIGNvbmNvcmRhIHF1ZSBvIFJlcG9zaXTvv71yaW8gSW5zdGl0dWNpb25hbCBkYSBVRk1HIHBvZGUgbWFudGVyIG1haXMgZGUgdW1hIGPvv71waWEgZGUgc3VhIHB1YmxpY2Hvv73vv71vIHBhcmEgZmlucyBkZSBzZWd1cmFu77+9YSwgYmFjay11cCBlIHByZXNlcnZh77+977+9by4KClZvY++/vSBkZWNsYXJhIHF1ZSBhIHN1YSBwdWJsaWNh77+977+9byDvv70gb3JpZ2luYWwgZSBxdWUgdm9j77+9IHRlbSBvIHBvZGVyIGRlIGNvbmNlZGVyIG9zIGRpcmVpdG9zIGNvbnRpZG9zIG5lc3RhIGxpY2Vu77+9YS4gVm9j77+9IHRhbWLvv71tIGRlY2xhcmEgcXVlIG8gZGVw77+9c2l0byBkZSBzdWEgcHVibGljYe+/ve+/vW8gbu+/vW8sIHF1ZSBzZWphIGRlIHNldSBjb25oZWNpbWVudG8sIGluZnJpbmdlIGRpcmVpdG9zIGF1dG9yYWlzIGRlIG5pbmd177+9bS4KCkNhc28gYSBzdWEgcHVibGljYe+/ve+/vW8gY29udGVuaGEgbWF0ZXJpYWwgcXVlIHZvY++/vSBu77+9byBwb3NzdWkgYSB0aXR1bGFyaWRhZGUgZG9zIGRpcmVpdG9zIGF1dG9yYWlzLCB2b2Pvv70gZGVjbGFyYSBxdWUgb2J0ZXZlIGEgcGVybWlzc++/vW8gaXJyZXN0cml0YSBkbyBkZXRlbnRvciBkb3MgZGlyZWl0b3MgYXV0b3JhaXMgcGFyYSBjb25jZWRlciBhbyBSZXBvc2l077+9cmlvIEluc3RpdHVjaW9uYWwgZGEgVUZNRyBvcyBkaXJlaXRvcyBhcHJlc2VudGFkb3MgbmVzdGEgbGljZW7vv71hLCBlIHF1ZSBlc3NlIG1hdGVyaWFsIGRlIHByb3ByaWVkYWRlIGRlIHRlcmNlaXJvcyBlc3Tvv70gY2xhcmFtZW50ZSBpZGVudGlmaWNhZG8gZSByZWNvbmhlY2lkbyBubyB0ZXh0byBvdSBubyBjb250Ze+/vWRvIGRhIHB1YmxpY2Hvv73vv71vIG9yYSBkZXBvc2l0YWRhLgoKQ0FTTyBBIFBVQkxJQ0Hvv73vv71PIE9SQSBERVBPU0lUQURBIFRFTkhBIFNJRE8gUkVTVUxUQURPIERFIFVNIFBBVFJPQ++/vU5JTyBPVSBBUE9JTyBERSBVTUEgQUfvv71OQ0lBIERFIEZPTUVOVE8gT1UgT1VUUk8gT1JHQU5JU01PLCBWT0Pvv70gREVDTEFSQSBRVUUgUkVTUEVJVE9VIFRPRE9TIEUgUVVBSVNRVUVSIERJUkVJVE9TIERFIFJFVklT77+9TyBDT01PIFRBTULvv71NIEFTIERFTUFJUyBPQlJJR0Hvv73vv71FUyBFWElHSURBUyBQT1IgQ09OVFJBVE8gT1UgQUNPUkRPLgoKTyBSZXBvc2l077+9cmlvIEluc3RpdHVjaW9uYWwgZGEgVUZNRyBzZSBjb21wcm9tZXRlIGEgaWRlbnRpZmljYXIgY2xhcmFtZW50ZSBvIHNldSBub21lKHMpIG91IG8ocykgbm9tZXMocykgZG8ocykgZGV0ZW50b3IoZXMpIGRvcyBkaXJlaXRvcyBhdXRvcmFpcyBkYSBwdWJsaWNh77+977+9bywgZSBu77+9byBmYXLvv70gcXVhbHF1ZXIgYWx0ZXJh77+977+9bywgYWzvv71tIGRhcXVlbGFzIGNvbmNlZGlkYXMgcG9yIGVzdGEgbGljZW7vv71hLgo=Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2024-05-16T13:46:59Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false |
| dc.title.pt_BR.fl_str_mv |
Improving the stability and efficiency of perovskite solar cells by a bidentate anilinium salt |
| title |
Improving the stability and efficiency of perovskite solar cells by a bidentate anilinium salt |
| spellingShingle |
Improving the stability and efficiency of perovskite solar cells by a bidentate anilinium salt Lucas Scalon Defect passivation Stable perovskite solar cells Aggregation-induced luminogen DFT calculation Rational synthesis Células solares Funcionais de densidade Moléculas Sal |
| title_short |
Improving the stability and efficiency of perovskite solar cells by a bidentate anilinium salt |
| title_full |
Improving the stability and efficiency of perovskite solar cells by a bidentate anilinium salt |
| title_fullStr |
Improving the stability and efficiency of perovskite solar cells by a bidentate anilinium salt |
| title_full_unstemmed |
Improving the stability and efficiency of perovskite solar cells by a bidentate anilinium salt |
| title_sort |
Improving the stability and efficiency of perovskite solar cells by a bidentate anilinium salt |
| author |
Lucas Scalon |
| author_facet |
Lucas Scalon Rodrigo Szostak Francineide Lopes de Araújo Karla Furtado Andriani Julian Francisco Rama Vieira Silveira Willian Xerxes Coelho Oliveira Juarez Lopes Ferreira da Silva Caio Costa Oliveira Ana Flávia Nogueira |
| author_role |
author |
| author2 |
Rodrigo Szostak Francineide Lopes de Araújo Karla Furtado Andriani Julian Francisco Rama Vieira Silveira Willian Xerxes Coelho Oliveira Juarez Lopes Ferreira da Silva Caio Costa Oliveira Ana Flávia Nogueira |
| author2_role |
author author author author author author author author |
| dc.contributor.author.fl_str_mv |
Lucas Scalon Rodrigo Szostak Francineide Lopes de Araújo Karla Furtado Andriani Julian Francisco Rama Vieira Silveira Willian Xerxes Coelho Oliveira Juarez Lopes Ferreira da Silva Caio Costa Oliveira Ana Flávia Nogueira |
| dc.subject.por.fl_str_mv |
Defect passivation Stable perovskite solar cells Aggregation-induced luminogen DFT calculation Rational synthesis |
| topic |
Defect passivation Stable perovskite solar cells Aggregation-induced luminogen DFT calculation Rational synthesis Células solares Funcionais de densidade Moléculas Sal |
| dc.subject.other.pt_BR.fl_str_mv |
Células solares Funcionais de densidade Moléculas Sal |
| description |
CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico |
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2022 |
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2022 |
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2024-05-16T13:46:59Z |
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2024-05-16T13:46:59Z |
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info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/article |
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https://doi.org/10.1021/jacsau.2c00151 |
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2691-3704 |
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https://orcid.org/0000-0002-1819-0266 https://orcid.org/0000-0001-9253-0401 https://orcid.org/0000-0002-6662-660X https://orcid.org/0000-0002-0024-1651 https://orcid.org/0000-0003-0722-5352 https://orcid.org/0000-0002-0838-7962 |
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