Properties of post-consumer polyethylene terephthalate coating mechanically deposited on mild steels

Detalhes bibliográficos
Autor(a) principal: Elisângela Aparecida da Silva
Data de Publicação: 2019
Outros Autores: Michele Fedel, Flavio Deflorian, Fernando Cotting, Vanessa de Freitas Cunha Lins
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFMG
Texto Completo: https://doi.org/10.3390/coatings9010028
http://hdl.handle.net/1843/57146
https://orcid.org/0000-0001-6994-0816
https://orcid.org/0000-0002-3849-4988
https://orcid.org/0000-0001-5980-0078
https://orcid.org/0000-0002-6357-9553
Resumo: An anticorrosive coating of post-consumer polyethylene terephthalate (PET) was applied on carbon steel by using an industrial press. The PET layer showed a good adhesion on the substrate, evaluated by using a pull off test, when compared with the traditional organic coatings. In addition, scanning electron microscopy (SEM) analysis showed that the PET layer was uniform, homogeneous, and free of cracks or defects. The Fourier-transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC) proved that the PET properties were not affected by the deposition process. The PET organic coating is a promising coating, due to its corrosion resistance evaluated by using salt spray tests, even though the applied thickness of 65 µm was considered thin for a high-performance coating. The electrochemical impedance spectroscopy (EIS) showed that the PET coating has a capacitive effect and its electrochemical behavior was not affected as the exposure time increased, resulting in an impedance modulus value of 1010 Ω·cm2, after 576 h of immersion in an aqueous solution of NaCl 3.0 wt %.
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spelling 2023-07-28T18:03:38Z2023-07-28T18:03:38Z2019-01-0591https://doi.org/10.3390/coatings90100282079-6412http://hdl.handle.net/1843/57146https://orcid.org/0000-0001-6994-0816https://orcid.org/0000-0002-3849-4988https://orcid.org/0000-0001-5980-0078https://orcid.org/0000-0002-6357-9553An anticorrosive coating of post-consumer polyethylene terephthalate (PET) was applied on carbon steel by using an industrial press. The PET layer showed a good adhesion on the substrate, evaluated by using a pull off test, when compared with the traditional organic coatings. In addition, scanning electron microscopy (SEM) analysis showed that the PET layer was uniform, homogeneous, and free of cracks or defects. The Fourier-transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC) proved that the PET properties were not affected by the deposition process. The PET organic coating is a promising coating, due to its corrosion resistance evaluated by using salt spray tests, even though the applied thickness of 65 µm was considered thin for a high-performance coating. The electrochemical impedance spectroscopy (EIS) showed that the PET coating has a capacitive effect and its electrochemical behavior was not affected as the exposure time increased, resulting in an impedance modulus value of 1010 Ω·cm2, after 576 h of immersion in an aqueous solution of NaCl 3.0 wt %.Um revestimento anticorrosivo de polietileno tereftalato (PET) pós-consumo foi aplicado em aço carbono usando uma prensa industrial. A camada de PET apresentou boa adesão ao substrato, avaliada pelo teste de arrancamento, quando comparada com os revestimentos orgânicos tradicionais. Além disso, a análise por microscopia eletrônica de varredura (MEV) mostrou que a camada de PET era uniforme, homogênea e livre de rachaduras ou defeitos. A espectroscopia de infravermelho com transformada de Fourier (FTIR) e a calorimetria exploratória diferencial (DSC) provaram que as propriedades do PET não foram afetadas pelo processo de deposição. O revestimento orgânico PET é um revestimento promissor, devido à sua resistência à corrosão avaliada por testes de névoa salina, embora a espessura aplicada de 65 µm tenha sido considerada fina para um revestimento de alto desempenho. A espectroscopia de impedância eletroquímica (EIS) mostrou que o revestimento de PET tem efeito capacitivo e seu comportamento eletroquímico não foi afetado com o aumento do tempo de exposição, resultando em um valor de módulo de impedância de 1010 Ω·cm2, após 576 h de imersão em solução aquosa de NaCl 3,0% em peso.CAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível SuperiorengUniversidade Federal de Minas GeraisUFMGBrasilENG - DEPARTAMENTO DE ENGENHARIA QUÍMICACoatingsRevestimentosRevestimento plásticoAço-carbono - CorrosãoCorrosionOrganic coatingsCarbon steelEISElectrochemical impedance spectroscopyPETPolyethylene terephthalateProperties of post-consumer polyethylene terephthalate coating mechanically deposited on mild steelsPropriedades do revestimento de tereftalato de polietileno pós-consumo depositado mecanicamente sobre aços maciosinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://www.mdpi.com/2079-6412/9/1/28Elisângela Aparecida da SilvaMichele FedelFlavio DeflorianFernando CottingVanessa de Freitas Cunha Linsapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/57146/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALProperties of post-consumer polyethylene terephthalate coating mechanically deposited on mild steels.pdfProperties of post-consumer polyethylene terephthalate coating mechanically deposited on mild steels.pdfapplication/pdf3307241https://repositorio.ufmg.br/bitstream/1843/57146/2/Properties%20of%20post-consumer%20polyethylene%20terephthalate%20coating%20mechanically%20deposited%20on%20mild%20steels.pdfe321899b2ddc635b7830a73876f5c775MD521843/571462023-07-28 15:03:38.747oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2023-07-28T18:03:38Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false
dc.title.pt_BR.fl_str_mv Properties of post-consumer polyethylene terephthalate coating mechanically deposited on mild steels
dc.title.alternative.pt_BR.fl_str_mv Propriedades do revestimento de tereftalato de polietileno pós-consumo depositado mecanicamente sobre aços macios
title Properties of post-consumer polyethylene terephthalate coating mechanically deposited on mild steels
spellingShingle Properties of post-consumer polyethylene terephthalate coating mechanically deposited on mild steels
Elisângela Aparecida da Silva
Corrosion
Organic coatings
Carbon steel
EIS
Electrochemical impedance spectroscopy
PET
Polyethylene terephthalate
Revestimentos
Revestimento plástico
Aço-carbono - Corrosão
title_short Properties of post-consumer polyethylene terephthalate coating mechanically deposited on mild steels
title_full Properties of post-consumer polyethylene terephthalate coating mechanically deposited on mild steels
title_fullStr Properties of post-consumer polyethylene terephthalate coating mechanically deposited on mild steels
title_full_unstemmed Properties of post-consumer polyethylene terephthalate coating mechanically deposited on mild steels
title_sort Properties of post-consumer polyethylene terephthalate coating mechanically deposited on mild steels
author Elisângela Aparecida da Silva
author_facet Elisângela Aparecida da Silva
Michele Fedel
Flavio Deflorian
Fernando Cotting
Vanessa de Freitas Cunha Lins
author_role author
author2 Michele Fedel
Flavio Deflorian
Fernando Cotting
Vanessa de Freitas Cunha Lins
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Elisângela Aparecida da Silva
Michele Fedel
Flavio Deflorian
Fernando Cotting
Vanessa de Freitas Cunha Lins
dc.subject.por.fl_str_mv Corrosion
Organic coatings
Carbon steel
EIS
Electrochemical impedance spectroscopy
PET
Polyethylene terephthalate
topic Corrosion
Organic coatings
Carbon steel
EIS
Electrochemical impedance spectroscopy
PET
Polyethylene terephthalate
Revestimentos
Revestimento plástico
Aço-carbono - Corrosão
dc.subject.other.pt_BR.fl_str_mv Revestimentos
Revestimento plástico
Aço-carbono - Corrosão
description An anticorrosive coating of post-consumer polyethylene terephthalate (PET) was applied on carbon steel by using an industrial press. The PET layer showed a good adhesion on the substrate, evaluated by using a pull off test, when compared with the traditional organic coatings. In addition, scanning electron microscopy (SEM) analysis showed that the PET layer was uniform, homogeneous, and free of cracks or defects. The Fourier-transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC) proved that the PET properties were not affected by the deposition process. The PET organic coating is a promising coating, due to its corrosion resistance evaluated by using salt spray tests, even though the applied thickness of 65 µm was considered thin for a high-performance coating. The electrochemical impedance spectroscopy (EIS) showed that the PET coating has a capacitive effect and its electrochemical behavior was not affected as the exposure time increased, resulting in an impedance modulus value of 1010 Ω·cm2, after 576 h of immersion in an aqueous solution of NaCl 3.0 wt %.
publishDate 2019
dc.date.issued.fl_str_mv 2019-01-05
dc.date.accessioned.fl_str_mv 2023-07-28T18:03:38Z
dc.date.available.fl_str_mv 2023-07-28T18:03:38Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1843/57146
dc.identifier.doi.pt_BR.fl_str_mv https://doi.org/10.3390/coatings9010028
dc.identifier.issn.pt_BR.fl_str_mv 2079-6412
dc.identifier.orcid.pt_BR.fl_str_mv https://orcid.org/0000-0001-6994-0816
https://orcid.org/0000-0002-3849-4988
https://orcid.org/0000-0001-5980-0078
https://orcid.org/0000-0002-6357-9553
url https://doi.org/10.3390/coatings9010028
http://hdl.handle.net/1843/57146
https://orcid.org/0000-0001-6994-0816
https://orcid.org/0000-0002-3849-4988
https://orcid.org/0000-0001-5980-0078
https://orcid.org/0000-0002-6357-9553
identifier_str_mv 2079-6412
dc.language.iso.fl_str_mv eng
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dc.relation.ispartof.pt_BR.fl_str_mv Coatings
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dc.publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.publisher.initials.fl_str_mv UFMG
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv ENG - DEPARTAMENTO DE ENGENHARIA QUÍMICA
publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFMG
instname:Universidade Federal de Minas Gerais (UFMG)
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