Investigation of polymer-based BaO and rGO nanocomposites for application in low energy X ray attenuation
Autor(a) principal: | |
---|---|
Data de Publicação: | 2019 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFMG |
Texto Completo: | https://doi.org/10.15392/bjrs.v7i2B.431 http://hdl.handle.net/1843/57947 https://orcid.org/0000-0001-6834-7551 |
Resumo: | Polymeric materials can serve as a matrix for the dispersion of nanomaterials with good attenuation features, resulting in lightweight, conformable, flexible, lead-free and easy-to-process materials. Thus, some well-known radiation shielding materials could be used in low proportion as a filler, for the formation of new materials. On the other hand, nanostructured carbon materials, such as graphene oxide (GO) have been reported recently to show enhanced attenua tion properties. For the present work, poly(vinylidene fluoride) [PVDF] homopolymers and its fluorinated copolymers were filled with metallic oxides and nanosized reduced graphene oxides (rGO) in order to produce nanocomposites with increased low energy X-ray attenuation efficiency. This work aims to investigate the X-ray shielding features of multilayered PVDF/rGO and P(VDF-TrFE)/BaO composites. PVDF/rGO overlapped with P(VDF-TrFE)/BaO thin films were sandwiched between two layers of kapton films of different thickness. The linear attenuation coefficients were measured for monochromatic X-ray photons with energy of 8.1 keV. The samples were characterized by Scan ning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Ultraviolet–visible (UV-vis) and FourierTransform Infrared (FTIR) Spectroscopy. The linear attenuation coefficient of the multilayered sample was evaluated and compared with the linear attenuation of the individual constituents. It was observed an increase in the attenuation coefficient of the overlapping samples. It is demonstrated that thin films of rGO nanocomposite with thickness of only 0.32 mm can attenuate up to 50% of X-ray beams with energy of 8.1 keV, justifying further investigation of these nanocomposites as X-ray or gamma radiation attenuators. |
id |
UFMG_542b71cc76431bf29e8e1b702ce6b568 |
---|---|
oai_identifier_str |
oai:repositorio.ufmg.br:1843/57947 |
network_acronym_str |
UFMG |
network_name_str |
Repositório Institucional da UFMG |
repository_id_str |
|
spelling |
2023-08-18T20:12:25Z2023-08-18T20:12:25Z2019-04-2272B115https://doi.org/10.15392/bjrs.v7i2B.4312319-0612http://hdl.handle.net/1843/57947https://orcid.org/0000-0001-6834-7551Polymeric materials can serve as a matrix for the dispersion of nanomaterials with good attenuation features, resulting in lightweight, conformable, flexible, lead-free and easy-to-process materials. Thus, some well-known radiation shielding materials could be used in low proportion as a filler, for the formation of new materials. On the other hand, nanostructured carbon materials, such as graphene oxide (GO) have been reported recently to show enhanced attenua tion properties. For the present work, poly(vinylidene fluoride) [PVDF] homopolymers and its fluorinated copolymers were filled with metallic oxides and nanosized reduced graphene oxides (rGO) in order to produce nanocomposites with increased low energy X-ray attenuation efficiency. This work aims to investigate the X-ray shielding features of multilayered PVDF/rGO and P(VDF-TrFE)/BaO composites. PVDF/rGO overlapped with P(VDF-TrFE)/BaO thin films were sandwiched between two layers of kapton films of different thickness. The linear attenuation coefficients were measured for monochromatic X-ray photons with energy of 8.1 keV. The samples were characterized by Scan ning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Ultraviolet–visible (UV-vis) and FourierTransform Infrared (FTIR) Spectroscopy. The linear attenuation coefficient of the multilayered sample was evaluated and compared with the linear attenuation of the individual constituents. It was observed an increase in the attenuation coefficient of the overlapping samples. It is demonstrated that thin films of rGO nanocomposite with thickness of only 0.32 mm can attenuate up to 50% of X-ray beams with energy of 8.1 keV, justifying further investigation of these nanocomposites as X-ray or gamma radiation attenuators.engUniversidade Federal de Minas GeraisUFMGBrasilMED - DEPARTAMENTO DE ANATOMIA E IMAGEMBrazilian Journal of Radiation SciencesNacompósitosRaio XBaOrGO nanocompositesX-ray AttenuationInvestigation of polymer-based BaO and rGO nanocomposites for application in low energy X ray attenuationinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://www.bjrs.org.br/revista/index.php/REVISTA/article/view/431Liliane Aparecida SilvaAdriana de Souza Medeiros BatistaJefferson NascimentocClascidia FurtadocLuiz Fariaapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/57947/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALInvestigation of polymer-based BaOand rGOnanocomposites forapplication in lowenergy X-rayattenuation pdfa.pdfInvestigation of polymer-based BaOand rGOnanocomposites forapplication in lowenergy X-rayattenuation pdfa.pdfapplication/pdf506355https://repositorio.ufmg.br/bitstream/1843/57947/2/Investigation%20of%20polymer-based%20BaOand%20rGOnanocomposites%20forapplication%20in%20lowenergy%20X-rayattenuation%20pdfa.pdf133806b8c33c4e686db0c783f92c2566MD521843/579472023-08-21 17:31:22.288oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2023-08-21T20:31:22Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false |
dc.title.pt_BR.fl_str_mv |
Investigation of polymer-based BaO and rGO nanocomposites for application in low energy X ray attenuation |
title |
Investigation of polymer-based BaO and rGO nanocomposites for application in low energy X ray attenuation |
spellingShingle |
Investigation of polymer-based BaO and rGO nanocomposites for application in low energy X ray attenuation Liliane Aparecida Silva BaO rGO nanocomposites X-ray Attenuation Nacompósitos Raio X |
title_short |
Investigation of polymer-based BaO and rGO nanocomposites for application in low energy X ray attenuation |
title_full |
Investigation of polymer-based BaO and rGO nanocomposites for application in low energy X ray attenuation |
title_fullStr |
Investigation of polymer-based BaO and rGO nanocomposites for application in low energy X ray attenuation |
title_full_unstemmed |
Investigation of polymer-based BaO and rGO nanocomposites for application in low energy X ray attenuation |
title_sort |
Investigation of polymer-based BaO and rGO nanocomposites for application in low energy X ray attenuation |
author |
Liliane Aparecida Silva |
author_facet |
Liliane Aparecida Silva Adriana de Souza Medeiros Batista Jefferson Nascimentoc Clascidia Furtadoc Luiz Faria |
author_role |
author |
author2 |
Adriana de Souza Medeiros Batista Jefferson Nascimentoc Clascidia Furtadoc Luiz Faria |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Liliane Aparecida Silva Adriana de Souza Medeiros Batista Jefferson Nascimentoc Clascidia Furtadoc Luiz Faria |
dc.subject.por.fl_str_mv |
BaO rGO nanocomposites X-ray Attenuation |
topic |
BaO rGO nanocomposites X-ray Attenuation Nacompósitos Raio X |
dc.subject.other.pt_BR.fl_str_mv |
Nacompósitos Raio X |
description |
Polymeric materials can serve as a matrix for the dispersion of nanomaterials with good attenuation features, resulting in lightweight, conformable, flexible, lead-free and easy-to-process materials. Thus, some well-known radiation shielding materials could be used in low proportion as a filler, for the formation of new materials. On the other hand, nanostructured carbon materials, such as graphene oxide (GO) have been reported recently to show enhanced attenua tion properties. For the present work, poly(vinylidene fluoride) [PVDF] homopolymers and its fluorinated copolymers were filled with metallic oxides and nanosized reduced graphene oxides (rGO) in order to produce nanocomposites with increased low energy X-ray attenuation efficiency. This work aims to investigate the X-ray shielding features of multilayered PVDF/rGO and P(VDF-TrFE)/BaO composites. PVDF/rGO overlapped with P(VDF-TrFE)/BaO thin films were sandwiched between two layers of kapton films of different thickness. The linear attenuation coefficients were measured for monochromatic X-ray photons with energy of 8.1 keV. The samples were characterized by Scan ning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Ultraviolet–visible (UV-vis) and FourierTransform Infrared (FTIR) Spectroscopy. The linear attenuation coefficient of the multilayered sample was evaluated and compared with the linear attenuation of the individual constituents. It was observed an increase in the attenuation coefficient of the overlapping samples. It is demonstrated that thin films of rGO nanocomposite with thickness of only 0.32 mm can attenuate up to 50% of X-ray beams with energy of 8.1 keV, justifying further investigation of these nanocomposites as X-ray or gamma radiation attenuators. |
publishDate |
2019 |
dc.date.issued.fl_str_mv |
2019-04-22 |
dc.date.accessioned.fl_str_mv |
2023-08-18T20:12:25Z |
dc.date.available.fl_str_mv |
2023-08-18T20:12:25Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1843/57947 |
dc.identifier.doi.pt_BR.fl_str_mv |
https://doi.org/10.15392/bjrs.v7i2B.431 |
dc.identifier.issn.pt_BR.fl_str_mv |
2319-0612 |
dc.identifier.orcid.pt_BR.fl_str_mv |
https://orcid.org/0000-0001-6834-7551 |
url |
https://doi.org/10.15392/bjrs.v7i2B.431 http://hdl.handle.net/1843/57947 https://orcid.org/0000-0001-6834-7551 |
identifier_str_mv |
2319-0612 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartof.none.fl_str_mv |
Brazilian Journal of Radiation Sciences |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
dc.publisher.initials.fl_str_mv |
UFMG |
dc.publisher.country.fl_str_mv |
Brasil |
dc.publisher.department.fl_str_mv |
MED - DEPARTAMENTO DE ANATOMIA E IMAGEM |
publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFMG instname:Universidade Federal de Minas Gerais (UFMG) instacron:UFMG |
instname_str |
Universidade Federal de Minas Gerais (UFMG) |
instacron_str |
UFMG |
institution |
UFMG |
reponame_str |
Repositório Institucional da UFMG |
collection |
Repositório Institucional da UFMG |
bitstream.url.fl_str_mv |
https://repositorio.ufmg.br/bitstream/1843/57947/1/License.txt https://repositorio.ufmg.br/bitstream/1843/57947/2/Investigation%20of%20polymer-based%20BaOand%20rGOnanocomposites%20forapplication%20in%20lowenergy%20X-rayattenuation%20pdfa.pdf |
bitstream.checksum.fl_str_mv |
fa505098d172de0bc8864fc1287ffe22 133806b8c33c4e686db0c783f92c2566 |
bitstream.checksumAlgorithm.fl_str_mv |
MD5 MD5 |
repository.name.fl_str_mv |
Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG) |
repository.mail.fl_str_mv |
|
_version_ |
1803589551167373312 |