Assessment of polycyclic aromatic hydrocarbons and derivatives in beer using a new cold fiber-solid phase microextraction system

Detalhes bibliográficos
Autor(a) principal: Rosimeire Resende dos Santos
Data de Publicação: 2021
Outros Autores: Ricardo Mathias Orlando, Zenilda de Lourdes Cardeal, Helvécio Costa Menezes
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFMG
Texto Completo: https://doi.org/10.1016/j.foodcont.2021.108104
http://hdl.handle.net/1843/67846
https://orcid.org/0000-0002-3862-1211
https://orcid.org/0000-0003-1383-6299
https://orcid.org/0000-0002-5759-612X
Resumo: CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
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spelling 2024-04-29T14:40:21Z2024-04-29T14:40:21Z2021126https://doi.org/10.1016/j.foodcont.2021.1081041873-7129http://hdl.handle.net/1843/67846https://orcid.org/0000-0002-3862-1211https://orcid.org/0000-0003-1383-6299https://orcid.org/0000-0002-5759-612XCNPq - Conselho Nacional de Desenvolvimento Científico e TecnológicoCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível SuperiorFAPESP - Fundação de Amparo à Pesquisa do Estado de São PauloOutra AgênciaSample preparation assisted by a cooling system including solid phase microextraction (SPME) has received an increased interest in recent years. In this work, a new cold fiber (CF-SPME) system using thermoelectric cooling is proposed. The system consists of three thermoelectric coolers (Peltier), a heat sink, a recirculation module to dissipate the heat generated on the hot side, and an electric power source to generate the necessary voltage for the system. The Peltier keeps the SPME fiber cool during the extraction process.. This system was used to analyze polycyclic aromatic hydrocarbons (PAHs), and their nitrated (nitro-PAHs) and oxygenated (oxy-PAHs) derivatives, in commercial beers b gas chromatography coupled to mass spectrometry (GC/MS). The analyte's extraction was optimized through Doehlert design. Optimal extraction conditions were obtained with a salt content of 0.6% w/v and beer volume of 700.0 μL. The validated method showed limits of detection (LOD) in the range of 0.003–0.128 μg L−1 and limits of quantification (LOQ) from 0.011 to 0.427 μg L−1. Precision Coefficients of Variation values ranged from 3.0 to 18.7%, and recovery values of the analytes in beer varied between 80.1 and 100.3%. Among the PAHs derivatives evaluated in this study, only 9-fluorenone and 9-nitroanthracene were detected in some samples. Benzo[b]fluoranthene was the most detected analyte in the samples, and at least one PAH was detected in all samples. Principal component analysis (PCA) separated the samples into two groups, mainly due to the high relative concentrations of acenaphthene and chrysene. The cooling approach improved the extraction efficiency and the new system demonstrated high potential for portability and automation.engUniversidade Federal de Minas GeraisUFMGBrasilICX - DEPARTAMENTO DE QUÍMICAFood ControlPreparação de amostra (Química)CervejaHidrocarbonetos policiclicos aromaticosCromatografia de gásCF-SPMEGC/MSBeerPAHs and derivativesSample preparationAssessment of polycyclic aromatic hydrocarbons and derivatives in beer using a new cold fiber-solid phase microextraction systeminfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://www.sciencedirect.com/science/article/pii/S0956713521002425Rosimeire Resende dos SantosRicardo Mathias OrlandoZenilda de Lourdes CardealHelvécio Costa Menezesapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/67846/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALAssessment of polycyclic aromatic hydrocarbons and derivatives in beer using a new cold fiber-solid phase microextraction system (1).pdfAssessment of polycyclic aromatic hydrocarbons and derivatives in beer using a new cold fiber-solid phase microextraction system (1).pdfapplication/pdf827896https://repositorio.ufmg.br/bitstream/1843/67846/2/Assessment%20of%20polycyclic%20aromatic%20hydrocarbons%20and%20derivatives%20in%20beer%20using%20a%20new%20cold%20fiber-solid%20phase%20microextraction%20system%20%281%29.pdf91615d4a772271e2f5cc03366d792063MD521843/678462024-04-29 11:40:21.916oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2024-04-29T14:40:21Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false
dc.title.pt_BR.fl_str_mv Assessment of polycyclic aromatic hydrocarbons and derivatives in beer using a new cold fiber-solid phase microextraction system
title Assessment of polycyclic aromatic hydrocarbons and derivatives in beer using a new cold fiber-solid phase microextraction system
spellingShingle Assessment of polycyclic aromatic hydrocarbons and derivatives in beer using a new cold fiber-solid phase microextraction system
Rosimeire Resende dos Santos
CF-SPME
GC/MS
Beer
PAHs and derivatives
Sample preparation
Preparação de amostra (Química)
Cerveja
Hidrocarbonetos policiclicos aromaticos
Cromatografia de gás
title_short Assessment of polycyclic aromatic hydrocarbons and derivatives in beer using a new cold fiber-solid phase microextraction system
title_full Assessment of polycyclic aromatic hydrocarbons and derivatives in beer using a new cold fiber-solid phase microextraction system
title_fullStr Assessment of polycyclic aromatic hydrocarbons and derivatives in beer using a new cold fiber-solid phase microextraction system
title_full_unstemmed Assessment of polycyclic aromatic hydrocarbons and derivatives in beer using a new cold fiber-solid phase microextraction system
title_sort Assessment of polycyclic aromatic hydrocarbons and derivatives in beer using a new cold fiber-solid phase microextraction system
author Rosimeire Resende dos Santos
author_facet Rosimeire Resende dos Santos
Ricardo Mathias Orlando
Zenilda de Lourdes Cardeal
Helvécio Costa Menezes
author_role author
author2 Ricardo Mathias Orlando
Zenilda de Lourdes Cardeal
Helvécio Costa Menezes
author2_role author
author
author
dc.contributor.author.fl_str_mv Rosimeire Resende dos Santos
Ricardo Mathias Orlando
Zenilda de Lourdes Cardeal
Helvécio Costa Menezes
dc.subject.por.fl_str_mv CF-SPME
GC/MS
Beer
PAHs and derivatives
Sample preparation
topic CF-SPME
GC/MS
Beer
PAHs and derivatives
Sample preparation
Preparação de amostra (Química)
Cerveja
Hidrocarbonetos policiclicos aromaticos
Cromatografia de gás
dc.subject.other.pt_BR.fl_str_mv Preparação de amostra (Química)
Cerveja
Hidrocarbonetos policiclicos aromaticos
Cromatografia de gás
description CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
publishDate 2021
dc.date.issued.fl_str_mv 2021
dc.date.accessioned.fl_str_mv 2024-04-29T14:40:21Z
dc.date.available.fl_str_mv 2024-04-29T14:40:21Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1843/67846
dc.identifier.doi.pt_BR.fl_str_mv https://doi.org/10.1016/j.foodcont.2021.108104
dc.identifier.issn.pt_BR.fl_str_mv 1873-7129
dc.identifier.orcid.pt_BR.fl_str_mv https://orcid.org/0000-0002-3862-1211
https://orcid.org/0000-0003-1383-6299
https://orcid.org/0000-0002-5759-612X
url https://doi.org/10.1016/j.foodcont.2021.108104
http://hdl.handle.net/1843/67846
https://orcid.org/0000-0002-3862-1211
https://orcid.org/0000-0003-1383-6299
https://orcid.org/0000-0002-5759-612X
identifier_str_mv 1873-7129
dc.language.iso.fl_str_mv eng
language eng
dc.relation.ispartof.pt_BR.fl_str_mv Food Control
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.publisher.initials.fl_str_mv UFMG
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv ICX - DEPARTAMENTO DE QUÍMICA
publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFMG
instname:Universidade Federal de Minas Gerais (UFMG)
instacron:UFMG
instname_str Universidade Federal de Minas Gerais (UFMG)
instacron_str UFMG
institution UFMG
reponame_str Repositório Institucional da UFMG
collection Repositório Institucional da UFMG
bitstream.url.fl_str_mv https://repositorio.ufmg.br/bitstream/1843/67846/1/License.txt
https://repositorio.ufmg.br/bitstream/1843/67846/2/Assessment%20of%20polycyclic%20aromatic%20hydrocarbons%20and%20derivatives%20in%20beer%20using%20a%20new%20cold%20fiber-solid%20phase%20microextraction%20system%20%281%29.pdf
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repository.name.fl_str_mv Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)
repository.mail.fl_str_mv
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