Optimization of methodology for determination of inorganic chromium species in sewage sludge samples by HPLC-ICP-MS/MS

Detalhes bibliográficos
Autor(a) principal: Érica Soares Barbosa
Data de Publicação: 2020
Outros Autores: Ane Patrícia Cacique, Gevany Paulino de Pinho, Flaviano Oliveira Silvério
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFMG
Texto Completo: https://doi.org/10.21577/0103-5053.20200124
http://hdl.handle.net/1843/48851
Resumo: CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
id UFMG_799217484b1d346dd3c034ba7b2b4490
oai_identifier_str oai:repositorio.ufmg.br:1843/48851
network_acronym_str UFMG
network_name_str Repositório Institucional da UFMG
repository_id_str
spelling 2023-01-11T11:42:01Z2023-01-11T11:42:01Z2020-12311224912499https://doi.org/10.21577/0103-5053.202001241678-4790http://hdl.handle.net/1843/48851CNPq - Conselho Nacional de Desenvolvimento Científico e TecnológicoFAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas GeraisCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível SuperiorOutra AgênciaThis study developed a methodology for extracting and speciating CrIII and CrVI in sewage sludge by high performance liquid chromatography, inductively coupled plasma tandem mass spectrometry (HPLC-ICP-MS/MS). The optimal procedure was solid-liquid extraction in a water bath with stirring at 50 °C for 16 h and 50 mmol L−1 ethylenediaminetetraacetic acid (EDTA) extraction phase at pH 9.5. In the validated method, the recovery in the fortification experiment was greater than 70% and the relative standard deviation was less than 7%. Speciation analyses showed that all CrVI was spontaneously reduced to CrIII in the sludge sample. The limits of detection and quantification were 0.060 and 0.20 µg L−1, respectively, and the analyses of CrIII by means of ICP-MS/MS were linear from 0.20 to 50 µg L−1. The extraction efficiency of Cr specie in this validated method improved from 4.09 to 53.3% compared to the EPA 1311 method. The methodology was successfully applied to quantify CrIII in a sludge sample with a lower concentration than that established by European legislation 80568/4225/91.engUniversidade Federal de Minas GeraisUFMGBrasilICA - INSTITUTO DE CIÊNCIAS AGRÁRIASJournal of the Brazilian Chemical SocietyLodo de esgotoCromoExtração (Química)Optimization of methodology for determination of inorganic chromium species in sewage sludge samples by HPLC-ICP-MS/MSinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://www.scielo.br/j/jbchs/a/DGzgBBX6m5nJd6MxWMT5K5m/?lang=enÉrica Soares BarbosaAne Patrícia CaciqueGevany Paulino de PinhoFlaviano Oliveira Silvérioinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/48851/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALOptimization of methodology for determination of inorganic chromium species in sewage sludge samples by hplc-icp-ms ms.pdfOptimization of methodology for determination of inorganic chromium species in sewage sludge samples by hplc-icp-ms ms.pdfapplication/pdf428735https://repositorio.ufmg.br/bitstream/1843/48851/2/Optimization%20of%20methodology%20for%20determination%20of%20inorganic%20chromium%20species%20in%20sewage%20sludge%20samples%20by%20hplc-icp-ms%20ms.pdf53765c72f4714fd8dd4e609a67edf0eaMD521843/488512023-01-11 08:42:01.986oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2023-01-11T11:42:01Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false
dc.title.pt_BR.fl_str_mv Optimization of methodology for determination of inorganic chromium species in sewage sludge samples by HPLC-ICP-MS/MS
title Optimization of methodology for determination of inorganic chromium species in sewage sludge samples by HPLC-ICP-MS/MS
spellingShingle Optimization of methodology for determination of inorganic chromium species in sewage sludge samples by HPLC-ICP-MS/MS
Érica Soares Barbosa
Lodo de esgoto
Cromo
Extração (Química)
title_short Optimization of methodology for determination of inorganic chromium species in sewage sludge samples by HPLC-ICP-MS/MS
title_full Optimization of methodology for determination of inorganic chromium species in sewage sludge samples by HPLC-ICP-MS/MS
title_fullStr Optimization of methodology for determination of inorganic chromium species in sewage sludge samples by HPLC-ICP-MS/MS
title_full_unstemmed Optimization of methodology for determination of inorganic chromium species in sewage sludge samples by HPLC-ICP-MS/MS
title_sort Optimization of methodology for determination of inorganic chromium species in sewage sludge samples by HPLC-ICP-MS/MS
author Érica Soares Barbosa
author_facet Érica Soares Barbosa
Ane Patrícia Cacique
Gevany Paulino de Pinho
Flaviano Oliveira Silvério
author_role author
author2 Ane Patrícia Cacique
Gevany Paulino de Pinho
Flaviano Oliveira Silvério
author2_role author
author
author
dc.contributor.author.fl_str_mv Érica Soares Barbosa
Ane Patrícia Cacique
Gevany Paulino de Pinho
Flaviano Oliveira Silvério
dc.subject.other.pt_BR.fl_str_mv Lodo de esgoto
Cromo
Extração (Química)
topic Lodo de esgoto
Cromo
Extração (Química)
description CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
publishDate 2020
dc.date.issued.fl_str_mv 2020-12
dc.date.accessioned.fl_str_mv 2023-01-11T11:42:01Z
dc.date.available.fl_str_mv 2023-01-11T11:42:01Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1843/48851
dc.identifier.doi.pt_BR.fl_str_mv https://doi.org/10.21577/0103-5053.20200124
dc.identifier.issn.pt_BR.fl_str_mv 1678-4790
url https://doi.org/10.21577/0103-5053.20200124
http://hdl.handle.net/1843/48851
identifier_str_mv 1678-4790
dc.language.iso.fl_str_mv eng
language eng
dc.relation.ispartof.pt_BR.fl_str_mv Journal of the Brazilian Chemical Society
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.publisher.initials.fl_str_mv UFMG
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv ICA - INSTITUTO DE CIÊNCIAS AGRÁRIAS
publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFMG
instname:Universidade Federal de Minas Gerais (UFMG)
instacron:UFMG
instname_str Universidade Federal de Minas Gerais (UFMG)
instacron_str UFMG
institution UFMG
reponame_str Repositório Institucional da UFMG
collection Repositório Institucional da UFMG
bitstream.url.fl_str_mv https://repositorio.ufmg.br/bitstream/1843/48851/1/License.txt
https://repositorio.ufmg.br/bitstream/1843/48851/2/Optimization%20of%20methodology%20for%20determination%20of%20inorganic%20chromium%20species%20in%20sewage%20sludge%20samples%20by%20hplc-icp-ms%20ms.pdf
bitstream.checksum.fl_str_mv fa505098d172de0bc8864fc1287ffe22
53765c72f4714fd8dd4e609a67edf0ea
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
repository.name.fl_str_mv Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)
repository.mail.fl_str_mv
_version_ 1801676794715176960

Registros relacionados