Use of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curing

Detalhes bibliográficos
Autor(a) principal: Cristiane do Bom Conselho Sales Alvarenga
Data de Publicação: 2022
Outros Autores: Rosemary do Bom Conselho Sales, Rodrigo Barreto Caldas, Paulo Roberto Cetlin, Maria Teresa Paulino Aguilar
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFMG
Texto Completo: https://doi.org/10.1590/s1678-86212022000100584
http://hdl.handle.net/1843/60683
http://orcid.org/0000-0002-5309-2020
http://orcid.org/0000-0002-9475-0835
http://orcid.org/0000-0002-0851-7632
http://orcid.org/0000-0002-8051-062X
http://orcid.org/0000-0002-0121-0881
Resumo: Metakaolinis the principal raw material utilized in the synthesis of geopolymers, although its ratio of silica and alumina contents is not ideal. Normally, the SiO2 content is adjusted with the use of silicates present in the activating solution. An eco-efficient alternative would be the use of glass waste as an additional source of silica.This work evaluates the efficiency of the alkaline activation of metakaolin, using potassium hydroxide and silicate, with and without the substitution of 12.5% of metakaolin by microparticles of glass. The efficiency of the alkaline activation was evaluated by X ray diffractometry, spectroscopy in the infrared region with the Fourier transform, nuclear magnetic resonance spectroscopy of 27Al and 29Si, specific mass and compressive strength. The results indicate the occurrence of geopolymerization with and without the use of glass waste. It was observed that the substitution of 12.5% favors the mechanical performance of the compounds at 28 days, with increases by 37% and 47% in the mechanical strength of the material with thermal curing and ambient temperature curing, respectively.
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spelling 2023-11-08T22:24:04Z2023-11-08T22:24:04Z2022221147160https://doi.org/10.1590/s1678-862120220001005841678-8621http://hdl.handle.net/1843/60683http://orcid.org/0000-0002-5309-2020http://orcid.org/0000-0002-9475-0835http://orcid.org/0000-0002-0851-7632http://orcid.org/0000-0002-8051-062Xhttp://orcid.org/0000-0002-0121-0881Metakaolinis the principal raw material utilized in the synthesis of geopolymers, although its ratio of silica and alumina contents is not ideal. Normally, the SiO2 content is adjusted with the use of silicates present in the activating solution. An eco-efficient alternative would be the use of glass waste as an additional source of silica.This work evaluates the efficiency of the alkaline activation of metakaolin, using potassium hydroxide and silicate, with and without the substitution of 12.5% of metakaolin by microparticles of glass. The efficiency of the alkaline activation was evaluated by X ray diffractometry, spectroscopy in the infrared region with the Fourier transform, nuclear magnetic resonance spectroscopy of 27Al and 29Si, specific mass and compressive strength. The results indicate the occurrence of geopolymerization with and without the use of glass waste. It was observed that the substitution of 12.5% favors the mechanical performance of the compounds at 28 days, with increases by 37% and 47% in the mechanical strength of the material with thermal curing and ambient temperature curing, respectively.O metacaulim é a principal matéria-prima utilizada na síntese de geopolímeros, embora a relação entre os teores de sílica e alumina não seja a ideal. Normalmente, o teor de SiO 2 é ajustado com o uso de silicatos presentes na solução ativadora. Uma opção ecoeficiente seria o uso de resíduos de vidro como fonte adicional de sílica. Este trabalho avalia a eficiência da ativação alcalina do metacaulim, utilizando hidróxido e silicato de potássio, com e sem substituição de 12,5% de metacaulim por micropartículas de vidro. A eficiência da ativação alcalina foi avaliada por difratometria de raios x, espectroscopia na região infravermelha com transformada de Fourier, espectroscopia de ressonância magnética nuclear do 27 Al e 29 Si, massa específica e resistência à compressão. Os resultados indicam a ocorrência de geopolimerização com e sem uso de resíduo de vidro. Observou-se que a substituição de 12,5% favorece o desempenho mecânico dos compósitos aos 28 dias, com aumentos de 37% e 47% da resistência mecânica do material com cura em estufa e na temperatura ambiente, respectivamente.engUniversidade Federal de Minas GeraisUFMGBrasilENG - DEPARTAMENTO DE ENGENHARIA ESTRUTURASENG - DEPARTAMENTO DE ENGENHARIA MATERIAIS E DA CONSTRUÇÃO CIVILENG - DEPARTAMENTO DE ENGENHARIA MECÂNICAAmbiente ConstruídoMetacaulimRefugo de vidroPotássioGeopolímerosMetakaolinGlass wastePotassium hydroxideAlkaline activationGeopolymerizationUse of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curingUtilização de resíduo de vidro na produção de geopolímero de base metacaulim submetido a cura ambiente e em estufainfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://www.scielo.br/j/ac/a/qhSXXMjVH88CQJGFzzzvwnt/?lang=en#Cristiane do Bom Conselho Sales AlvarengaRosemary do Bom Conselho SalesRodrigo Barreto CaldasPaulo Roberto CetlinMaria Teresa Paulino Aguilarapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/60683/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALUse of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curing.pdfUse of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curing.pdfapplication/pdf1553451https://repositorio.ufmg.br/bitstream/1843/60683/2/Use%20of%20glass%20waste%20in%20the%20production%20of%20metakaolin-based%20geopolymer%20submitted%20to%20room%20temperature%20and%20thermal%20curing.pdfd894396603b517ae9cde9814734549efMD521843/606832023-11-08 19:24:04.877oai:repositorio.ufmg.br:1843/60683Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2023-11-08T22:24:04Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false
dc.title.pt_BR.fl_str_mv Use of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curing
dc.title.alternative.pt_BR.fl_str_mv Utilização de resíduo de vidro na produção de geopolímero de base metacaulim submetido a cura ambiente e em estufa
title Use of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curing
spellingShingle Use of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curing
Cristiane do Bom Conselho Sales Alvarenga
Metakaolin
Glass waste
Potassium hydroxide
Alkaline activation
Geopolymerization
Metacaulim
Refugo de vidro
Potássio
Geopolímeros
title_short Use of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curing
title_full Use of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curing
title_fullStr Use of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curing
title_full_unstemmed Use of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curing
title_sort Use of glass waste in the production of metakaolin-based geopolymer submitted to room temperature and thermal curing
author Cristiane do Bom Conselho Sales Alvarenga
author_facet Cristiane do Bom Conselho Sales Alvarenga
Rosemary do Bom Conselho Sales
Rodrigo Barreto Caldas
Paulo Roberto Cetlin
Maria Teresa Paulino Aguilar
author_role author
author2 Rosemary do Bom Conselho Sales
Rodrigo Barreto Caldas
Paulo Roberto Cetlin
Maria Teresa Paulino Aguilar
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Cristiane do Bom Conselho Sales Alvarenga
Rosemary do Bom Conselho Sales
Rodrigo Barreto Caldas
Paulo Roberto Cetlin
Maria Teresa Paulino Aguilar
dc.subject.por.fl_str_mv Metakaolin
Glass waste
Potassium hydroxide
Alkaline activation
Geopolymerization
topic Metakaolin
Glass waste
Potassium hydroxide
Alkaline activation
Geopolymerization
Metacaulim
Refugo de vidro
Potássio
Geopolímeros
dc.subject.other.pt_BR.fl_str_mv Metacaulim
Refugo de vidro
Potássio
Geopolímeros
description Metakaolinis the principal raw material utilized in the synthesis of geopolymers, although its ratio of silica and alumina contents is not ideal. Normally, the SiO2 content is adjusted with the use of silicates present in the activating solution. An eco-efficient alternative would be the use of glass waste as an additional source of silica.This work evaluates the efficiency of the alkaline activation of metakaolin, using potassium hydroxide and silicate, with and without the substitution of 12.5% of metakaolin by microparticles of glass. The efficiency of the alkaline activation was evaluated by X ray diffractometry, spectroscopy in the infrared region with the Fourier transform, nuclear magnetic resonance spectroscopy of 27Al and 29Si, specific mass and compressive strength. The results indicate the occurrence of geopolymerization with and without the use of glass waste. It was observed that the substitution of 12.5% favors the mechanical performance of the compounds at 28 days, with increases by 37% and 47% in the mechanical strength of the material with thermal curing and ambient temperature curing, respectively.
publishDate 2022
dc.date.issued.fl_str_mv 2022
dc.date.accessioned.fl_str_mv 2023-11-08T22:24:04Z
dc.date.available.fl_str_mv 2023-11-08T22:24:04Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1843/60683
dc.identifier.doi.pt_BR.fl_str_mv https://doi.org/10.1590/s1678-86212022000100584
dc.identifier.issn.pt_BR.fl_str_mv 1678-8621
dc.identifier.orcid.pt_BR.fl_str_mv http://orcid.org/0000-0002-5309-2020
http://orcid.org/0000-0002-9475-0835
http://orcid.org/0000-0002-0851-7632
http://orcid.org/0000-0002-8051-062X
http://orcid.org/0000-0002-0121-0881
url https://doi.org/10.1590/s1678-86212022000100584
http://hdl.handle.net/1843/60683
http://orcid.org/0000-0002-5309-2020
http://orcid.org/0000-0002-9475-0835
http://orcid.org/0000-0002-0851-7632
http://orcid.org/0000-0002-8051-062X
http://orcid.org/0000-0002-0121-0881
identifier_str_mv 1678-8621
dc.language.iso.fl_str_mv eng
language eng
dc.relation.ispartof.pt_BR.fl_str_mv Ambiente Construído
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
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dc.publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.publisher.initials.fl_str_mv UFMG
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv ENG - DEPARTAMENTO DE ENGENHARIA ESTRUTURAS
ENG - DEPARTAMENTO DE ENGENHARIA MATERIAIS E DA CONSTRUÇÃO CIVIL
ENG - DEPARTAMENTO DE ENGENHARIA MECÂNICA
publisher.none.fl_str_mv Universidade Federal de Minas Gerais
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