Obtaining Mn-Co alloys in AISI 430 steel from lithium-ion battery recycling: application in SOFC interconnectors

Detalhes bibliográficos
Autor(a) principal: Sicele Luciana Abreu Gonçalves
Data de Publicação: 2020
Outros Autores: Eric Marsalha Garcia, Hosane Aparecida Tarôco, Tulio Matencio
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFMG
Texto Completo: https://doi.org/10.3390/chemengineering4010010
http://hdl.handle.net/1843/57521
https://orcid.org/0000-0002-5371-6040
https://orcid.org/0000-0002-3731-7568
https://orcid.org/0000-0002-8744-9200
https://orcid.org/0000-0002-5660-8125
Resumo: CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
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spelling 2023-08-07T14:04:32Z2023-08-07T14:04:32Z202041https://doi.org/10.3390/chemengineering40100102305-7084http://hdl.handle.net/1843/57521https://orcid.org/0000-0002-5371-6040https://orcid.org/0000-0002-3731-7568https://orcid.org/0000-0002-8744-9200https://orcid.org/0000-0002-5660-8125CNPq - Conselho Nacional de Desenvolvimento Científico e TecnológicoFAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas GeraisCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível SuperiorThe recycling of exhausted lithium-ion batteries from mobile phones originate five solutions with different Co and Mn proportions that were used as electrolytic solutions to obtain Mn-Co spinel coatings on the surface of AISI430 stainless steel. The coatings are intended to contain chromium volatility in the working conditions of Solid Oxide Fuel Cells (SOFC) metallic interconnectors. Potentiostatic electrodeposition was the technique used to obtain Mn-Co coatings from low concentration electrolytes at pH = 3.0 and potential applied −1.3 V. Charge efficiency data were used for sample optimization. Three optimized samples were subjected to oxidation heat treatment at 800 °C for 300 h and then characterized by XRD, SEM and EDS. The results showed that the addition of manganese ions instead of cobalt ions in the electrolytic bath produces more stable and well-distributed deposits as the ratio of the two ions becomes equal in the electrolytic bath. Thin, homogeneous and stable spinel coatings (Mn, Co)3O4 2.8 μm and 3.9 μm thick were able to block chromium volatility when exposed to SOFC operating temperature.engUniversidade Federal de Minas GeraisUFMGBrasilENG - DEPARTAMENTO DE ENGENHARIA QUÍMICAICX - DEPARTAMENTO DE QUÍMICAChemEngineeringEletroquímicaBaterias de lítioAço inoxidávelLigas de manganêsLigas de cobaltoCromoBaterias - ReaproveitamentoCélulas à combustívelRaios X - DifraçãoEletrodeposiçãoVoltametriaMicroscopia eletrônica de varreduraSolução eletrolíticaInterconnectorsSOFCChromium volatilityObtaining Mn-Co alloys in AISI 430 steel from lithium-ion battery recycling: application in SOFC interconnectorsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://www.mdpi.com/2305-7084/4/1/10Sicele Luciana Abreu GonçalvesEric Marsalha GarciaHosane Aparecida TarôcoTulio Matencioapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/57521/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALObtaining mn-co alloys in aisi 430 steel from lithium-ion battery recycling application in sofc interconnectors.pdfObtaining mn-co alloys in aisi 430 steel from lithium-ion battery recycling application in sofc interconnectors.pdfapplication/pdf1061592https://repositorio.ufmg.br/bitstream/1843/57521/2/Obtaining%20mn-co%20alloys%20in%20aisi%20430%20steel%20from%20lithium-ion%20battery%20recycling%20application%20in%20sofc%20interconnectors.pdff58546b2184abc858cc9ffec2aa29813MD521843/575212023-08-07 14:08:44.681oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2023-08-07T17:08:44Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false
dc.title.pt_BR.fl_str_mv Obtaining Mn-Co alloys in AISI 430 steel from lithium-ion battery recycling: application in SOFC interconnectors
title Obtaining Mn-Co alloys in AISI 430 steel from lithium-ion battery recycling: application in SOFC interconnectors
spellingShingle Obtaining Mn-Co alloys in AISI 430 steel from lithium-ion battery recycling: application in SOFC interconnectors
Sicele Luciana Abreu Gonçalves
Interconnectors
SOFC
Chromium volatility
Eletroquímica
Baterias de lítio
Aço inoxidável
Ligas de manganês
Ligas de cobalto
Cromo
Baterias - Reaproveitamento
Células à combustível
Raios X - Difração
Eletrodeposição
Voltametria
Microscopia eletrônica de varredura
Solução eletrolítica
title_short Obtaining Mn-Co alloys in AISI 430 steel from lithium-ion battery recycling: application in SOFC interconnectors
title_full Obtaining Mn-Co alloys in AISI 430 steel from lithium-ion battery recycling: application in SOFC interconnectors
title_fullStr Obtaining Mn-Co alloys in AISI 430 steel from lithium-ion battery recycling: application in SOFC interconnectors
title_full_unstemmed Obtaining Mn-Co alloys in AISI 430 steel from lithium-ion battery recycling: application in SOFC interconnectors
title_sort Obtaining Mn-Co alloys in AISI 430 steel from lithium-ion battery recycling: application in SOFC interconnectors
author Sicele Luciana Abreu Gonçalves
author_facet Sicele Luciana Abreu Gonçalves
Eric Marsalha Garcia
Hosane Aparecida Tarôco
Tulio Matencio
author_role author
author2 Eric Marsalha Garcia
Hosane Aparecida Tarôco
Tulio Matencio
author2_role author
author
author
dc.contributor.author.fl_str_mv Sicele Luciana Abreu Gonçalves
Eric Marsalha Garcia
Hosane Aparecida Tarôco
Tulio Matencio
dc.subject.por.fl_str_mv Interconnectors
SOFC
Chromium volatility
topic Interconnectors
SOFC
Chromium volatility
Eletroquímica
Baterias de lítio
Aço inoxidável
Ligas de manganês
Ligas de cobalto
Cromo
Baterias - Reaproveitamento
Células à combustível
Raios X - Difração
Eletrodeposição
Voltametria
Microscopia eletrônica de varredura
Solução eletrolítica
dc.subject.other.pt_BR.fl_str_mv Eletroquímica
Baterias de lítio
Aço inoxidável
Ligas de manganês
Ligas de cobalto
Cromo
Baterias - Reaproveitamento
Células à combustível
Raios X - Difração
Eletrodeposição
Voltametria
Microscopia eletrônica de varredura
Solução eletrolítica
description CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
publishDate 2020
dc.date.issued.fl_str_mv 2020
dc.date.accessioned.fl_str_mv 2023-08-07T14:04:32Z
dc.date.available.fl_str_mv 2023-08-07T14:04:32Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1843/57521
dc.identifier.doi.pt_BR.fl_str_mv https://doi.org/10.3390/chemengineering4010010
dc.identifier.issn.pt_BR.fl_str_mv 2305-7084
dc.identifier.orcid.pt_BR.fl_str_mv https://orcid.org/0000-0002-5371-6040
https://orcid.org/0000-0002-3731-7568
https://orcid.org/0000-0002-8744-9200
https://orcid.org/0000-0002-5660-8125
url https://doi.org/10.3390/chemengineering4010010
http://hdl.handle.net/1843/57521
https://orcid.org/0000-0002-5371-6040
https://orcid.org/0000-0002-3731-7568
https://orcid.org/0000-0002-8744-9200
https://orcid.org/0000-0002-5660-8125
identifier_str_mv 2305-7084
dc.language.iso.fl_str_mv eng
language eng
dc.relation.ispartof.none.fl_str_mv ChemEngineering
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.publisher.initials.fl_str_mv UFMG
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv ENG - DEPARTAMENTO DE ENGENHARIA QUÍMICA
ICX - DEPARTAMENTO DE QUÍMICA
publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFMG
instname:Universidade Federal de Minas Gerais (UFMG)
instacron:UFMG
instname_str Universidade Federal de Minas Gerais (UFMG)
instacron_str UFMG
institution UFMG
reponame_str Repositório Institucional da UFMG
collection Repositório Institucional da UFMG
bitstream.url.fl_str_mv https://repositorio.ufmg.br/bitstream/1843/57521/1/License.txt
https://repositorio.ufmg.br/bitstream/1843/57521/2/Obtaining%20mn-co%20alloys%20in%20aisi%20430%20steel%20from%20lithium-ion%20battery%20recycling%20application%20in%20sofc%20interconnectors.pdf
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repository.name.fl_str_mv Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)
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