Influence of temperature on the electrochemical coloration process and properties of the AISI 304 and 430 colored stainless steel
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Repositório Institucional da UFMG |
Texto Completo: | https://doi.org/10.1016/j.jmrt.2021.11.117 http://hdl.handle.net/1843/57086 https://orcid.org/0000-0002-4776-4222 https://orcid.org/0000-0002-6357-9553 https://orcid.org/0000-0003-0800-1713 |
Resumo: | The influence of temperature on the speed of an electrochemical coloration process of AISI 304 and AISI 430 stainless steel was investigated in temperature ranging from 25 °C to 40 °C. The surface properties of the interference colored nanofilms obtained in both types of stainless steel substrates, were also evaluated. A higher coloring speed was observed for AISI 304. The coloring time to obtain a gold color decreased with increasing temperature for both steels. This effect was stronger on the AISI 430 substrate, with a decrease of 36.6% in the coloration time for the samples colored at 40 °C and 25 °C. The Arrhenius model was applied to estimate the equations of colored films growth rate. The films porous fractions evaluated by SEM were in the range of 27–29%, without relevant variation with the coloring temperature. The nanohardness of the conjugated film-substrate obtained in a nanoindenter coupled to an AFM shows lower values than the uncolored substrates, and this reduction is more significant for the films grown on the AISI 430 ferritic specimens. The wettability of the surface to water and oil increased after coloring. The amplification effect of the hydrophilic effect can be associated with the increased AFM nanorugosity values. |
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2023-07-27T18:56:28Z2023-07-27T18:56:28Z202116102109https://doi.org/10.1016/j.jmrt.2021.11.1172238-7854http://hdl.handle.net/1843/57086https://orcid.org/0000-0002-4776-4222https://orcid.org/0000-0002-6357-9553https://orcid.org/0000-0003-0800-1713The influence of temperature on the speed of an electrochemical coloration process of AISI 304 and AISI 430 stainless steel was investigated in temperature ranging from 25 °C to 40 °C. The surface properties of the interference colored nanofilms obtained in both types of stainless steel substrates, were also evaluated. A higher coloring speed was observed for AISI 304. The coloring time to obtain a gold color decreased with increasing temperature for both steels. This effect was stronger on the AISI 430 substrate, with a decrease of 36.6% in the coloration time for the samples colored at 40 °C and 25 °C. The Arrhenius model was applied to estimate the equations of colored films growth rate. The films porous fractions evaluated by SEM were in the range of 27–29%, without relevant variation with the coloring temperature. The nanohardness of the conjugated film-substrate obtained in a nanoindenter coupled to an AFM shows lower values than the uncolored substrates, and this reduction is more significant for the films grown on the AISI 430 ferritic specimens. The wettability of the surface to water and oil increased after coloring. The amplification effect of the hydrophilic effect can be associated with the increased AFM nanorugosity values.porUniversidade Federal de Minas GeraisUFMGBrasilENG - DEPARTAMENTO DE ENGENHARIA METALÚRGICAJournal of Materials Research and TechnologyAço inoxidavelTemperaturaDetectores eletroquimicosColored stainless steelNanoindentationWettabilityInterference filmNanohardnessInfluence of temperature on the electrochemical coloration process and properties of the AISI 304 and 430 colored stainless steelinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://www.sciencedirect.com/science/article/pii/S2238785421013971Jaqueline Lacerda da SilvaAndreia Rocha Canella CarneiroGeovane Martins CastroEduardo Henrique Martins NunesVanessa de Freitas Cunha LinsRosa Maria Rabelo Junqueirainfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/57086/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALInfluence of temperature on the electrochemical coloration process and properties of the AISI 304 and 430 colored stainless steel.pdfInfluence of temperature on the electrochemical coloration process and properties of the AISI 304 and 430 colored stainless steel.pdfapplication/pdf837998https://repositorio.ufmg.br/bitstream/1843/57086/2/Influence%20of%20temperature%20on%20the%20electrochemical%20coloration%20process%20and%20properties%20of%20the%20AISI%20304%20and%20430%20colored%20stainless%20steel.pdfc6d2008bc3e46044e5a776fb69757220MD521843/570862023-07-27 15:56:29.023oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2023-07-27T18:56:29Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false |
dc.title.pt_BR.fl_str_mv |
Influence of temperature on the electrochemical coloration process and properties of the AISI 304 and 430 colored stainless steel |
title |
Influence of temperature on the electrochemical coloration process and properties of the AISI 304 and 430 colored stainless steel |
spellingShingle |
Influence of temperature on the electrochemical coloration process and properties of the AISI 304 and 430 colored stainless steel Jaqueline Lacerda da Silva Colored stainless steel Nanoindentation Wettability Interference film Nanohardness Aço inoxidavel Temperatura Detectores eletroquimicos |
title_short |
Influence of temperature on the electrochemical coloration process and properties of the AISI 304 and 430 colored stainless steel |
title_full |
Influence of temperature on the electrochemical coloration process and properties of the AISI 304 and 430 colored stainless steel |
title_fullStr |
Influence of temperature on the electrochemical coloration process and properties of the AISI 304 and 430 colored stainless steel |
title_full_unstemmed |
Influence of temperature on the electrochemical coloration process and properties of the AISI 304 and 430 colored stainless steel |
title_sort |
Influence of temperature on the electrochemical coloration process and properties of the AISI 304 and 430 colored stainless steel |
author |
Jaqueline Lacerda da Silva |
author_facet |
Jaqueline Lacerda da Silva Andreia Rocha Canella Carneiro Geovane Martins Castro Eduardo Henrique Martins Nunes Vanessa de Freitas Cunha Lins Rosa Maria Rabelo Junqueira |
author_role |
author |
author2 |
Andreia Rocha Canella Carneiro Geovane Martins Castro Eduardo Henrique Martins Nunes Vanessa de Freitas Cunha Lins Rosa Maria Rabelo Junqueira |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Jaqueline Lacerda da Silva Andreia Rocha Canella Carneiro Geovane Martins Castro Eduardo Henrique Martins Nunes Vanessa de Freitas Cunha Lins Rosa Maria Rabelo Junqueira |
dc.subject.por.fl_str_mv |
Colored stainless steel Nanoindentation Wettability Interference film Nanohardness |
topic |
Colored stainless steel Nanoindentation Wettability Interference film Nanohardness Aço inoxidavel Temperatura Detectores eletroquimicos |
dc.subject.other.pt_BR.fl_str_mv |
Aço inoxidavel Temperatura Detectores eletroquimicos |
description |
The influence of temperature on the speed of an electrochemical coloration process of AISI 304 and AISI 430 stainless steel was investigated in temperature ranging from 25 °C to 40 °C. The surface properties of the interference colored nanofilms obtained in both types of stainless steel substrates, were also evaluated. A higher coloring speed was observed for AISI 304. The coloring time to obtain a gold color decreased with increasing temperature for both steels. This effect was stronger on the AISI 430 substrate, with a decrease of 36.6% in the coloration time for the samples colored at 40 °C and 25 °C. The Arrhenius model was applied to estimate the equations of colored films growth rate. The films porous fractions evaluated by SEM were in the range of 27–29%, without relevant variation with the coloring temperature. The nanohardness of the conjugated film-substrate obtained in a nanoindenter coupled to an AFM shows lower values than the uncolored substrates, and this reduction is more significant for the films grown on the AISI 430 ferritic specimens. The wettability of the surface to water and oil increased after coloring. The amplification effect of the hydrophilic effect can be associated with the increased AFM nanorugosity values. |
publishDate |
2021 |
dc.date.issued.fl_str_mv |
2021 |
dc.date.accessioned.fl_str_mv |
2023-07-27T18:56:28Z |
dc.date.available.fl_str_mv |
2023-07-27T18:56:28Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1843/57086 |
dc.identifier.doi.pt_BR.fl_str_mv |
https://doi.org/10.1016/j.jmrt.2021.11.117 |
dc.identifier.issn.pt_BR.fl_str_mv |
2238-7854 |
dc.identifier.orcid.pt_BR.fl_str_mv |
https://orcid.org/0000-0002-4776-4222 https://orcid.org/0000-0002-6357-9553 https://orcid.org/0000-0003-0800-1713 |
url |
https://doi.org/10.1016/j.jmrt.2021.11.117 http://hdl.handle.net/1843/57086 https://orcid.org/0000-0002-4776-4222 https://orcid.org/0000-0002-6357-9553 https://orcid.org/0000-0003-0800-1713 |
identifier_str_mv |
2238-7854 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.ispartof.pt_BR.fl_str_mv |
Journal of Materials Research and Technology |
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info:eu-repo/semantics/openAccess |
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openAccess |
dc.publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
dc.publisher.initials.fl_str_mv |
UFMG |
dc.publisher.country.fl_str_mv |
Brasil |
dc.publisher.department.fl_str_mv |
ENG - DEPARTAMENTO DE ENGENHARIA METALÚRGICA |
publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
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reponame:Repositório Institucional da UFMG instname:Universidade Federal de Minas Gerais (UFMG) instacron:UFMG |
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UFMG |
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