Determination of 93Zr in radioactive waste from nuclear power plants using Inductively Coupled Plasma Mass Spectrometry
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFMG |
Texto Completo: | https://doi.org/10.15392/bjrs.v6i1.317 http://hdl.handle.net/1843/46284 |
Resumo: | The zirconium isotope 93Zr is a long-lived pure β-particle-emitting radionuclide produced from 235U fission and from neutron activation of the stable isotope 92Zr and thus occurring as one of the radionuclides found in nuclear reactors. Due to its long half-life, 93Zr is one of the radionuclides of interest for the performance of assessment studies of waste storage or disposal. This paper describes the determination of 93Zr in evaporator concentrate (EC) sample from nuclear power plant (PWR). A zirconium selective separation using liquid-liquid extraction and TRU column were used before the ICPMS measurement to remove isobaric interferences.20-21 93Nb detection limit of 0.045 μg L-1 was obtained for 93Zr determination by ICPMS technique. |
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2022-10-17T21:54:09Z2022-10-17T21:54:09Z201861115https://doi.org/10.15392/bjrs.v6i1.3172319-0612http://hdl.handle.net/1843/46284The zirconium isotope 93Zr is a long-lived pure β-particle-emitting radionuclide produced from 235U fission and from neutron activation of the stable isotope 92Zr and thus occurring as one of the radionuclides found in nuclear reactors. Due to its long half-life, 93Zr is one of the radionuclides of interest for the performance of assessment studies of waste storage or disposal. This paper describes the determination of 93Zr in evaporator concentrate (EC) sample from nuclear power plant (PWR). A zirconium selective separation using liquid-liquid extraction and TRU column were used before the ICPMS measurement to remove isobaric interferences.20-21 93Nb detection limit of 0.045 μg L-1 was obtained for 93Zr determination by ICPMS technique.engUniversidade Federal de Minas GeraisUFMGBrasilENG - DEPARTAMENTO DE ENGENHARIA NUCLEARBrazilian Journal of Radiation SciencesQuímicaICPMSEvaporator concentrate wasteTRUZirconiumDetermination of 93Zr in radioactive waste from nuclear power plants using Inductively Coupled Plasma Mass Spectrometryinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://www.bjrs.org.br/revista/index.php/REVISTA/article/view/317Thiago César de OliveiraRoberto Pellacani Guedes MonteiroAluísio Souza Reis JúniorGeraldo Frederico KastnerArno Heeren de Oliveiraapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/46284/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALDetermination of 93Zr in radioactive waste from nuclear - PDFA.pdfDetermination of 93Zr in radioactive waste from nuclear - PDFA.pdfapplication/pdf837198https://repositorio.ufmg.br/bitstream/1843/46284/2/Determination%20of%2093Zr%20in%20radioactive%20waste%20from%20nuclear%20-%20PDFA.pdfdbb0946130d22a48ff3b3e17d5b7411bMD521843/462842022-10-17 18:54:09.625oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2022-10-17T21:54:09Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false |
dc.title.pt_BR.fl_str_mv |
Determination of 93Zr in radioactive waste from nuclear power plants using Inductively Coupled Plasma Mass Spectrometry |
title |
Determination of 93Zr in radioactive waste from nuclear power plants using Inductively Coupled Plasma Mass Spectrometry |
spellingShingle |
Determination of 93Zr in radioactive waste from nuclear power plants using Inductively Coupled Plasma Mass Spectrometry Thiago César de Oliveira ICPMS Evaporator concentrate waste TRU Zirconium Química |
title_short |
Determination of 93Zr in radioactive waste from nuclear power plants using Inductively Coupled Plasma Mass Spectrometry |
title_full |
Determination of 93Zr in radioactive waste from nuclear power plants using Inductively Coupled Plasma Mass Spectrometry |
title_fullStr |
Determination of 93Zr in radioactive waste from nuclear power plants using Inductively Coupled Plasma Mass Spectrometry |
title_full_unstemmed |
Determination of 93Zr in radioactive waste from nuclear power plants using Inductively Coupled Plasma Mass Spectrometry |
title_sort |
Determination of 93Zr in radioactive waste from nuclear power plants using Inductively Coupled Plasma Mass Spectrometry |
author |
Thiago César de Oliveira |
author_facet |
Thiago César de Oliveira Roberto Pellacani Guedes Monteiro Aluísio Souza Reis Júnior Geraldo Frederico Kastner Arno Heeren de Oliveira |
author_role |
author |
author2 |
Roberto Pellacani Guedes Monteiro Aluísio Souza Reis Júnior Geraldo Frederico Kastner Arno Heeren de Oliveira |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Thiago César de Oliveira Roberto Pellacani Guedes Monteiro Aluísio Souza Reis Júnior Geraldo Frederico Kastner Arno Heeren de Oliveira |
dc.subject.por.fl_str_mv |
ICPMS Evaporator concentrate waste TRU Zirconium |
topic |
ICPMS Evaporator concentrate waste TRU Zirconium Química |
dc.subject.other.pt_BR.fl_str_mv |
Química |
description |
The zirconium isotope 93Zr is a long-lived pure β-particle-emitting radionuclide produced from 235U fission and from neutron activation of the stable isotope 92Zr and thus occurring as one of the radionuclides found in nuclear reactors. Due to its long half-life, 93Zr is one of the radionuclides of interest for the performance of assessment studies of waste storage or disposal. This paper describes the determination of 93Zr in evaporator concentrate (EC) sample from nuclear power plant (PWR). A zirconium selective separation using liquid-liquid extraction and TRU column were used before the ICPMS measurement to remove isobaric interferences.20-21 93Nb detection limit of 0.045 μg L-1 was obtained for 93Zr determination by ICPMS technique. |
publishDate |
2018 |
dc.date.issued.fl_str_mv |
2018 |
dc.date.accessioned.fl_str_mv |
2022-10-17T21:54:09Z |
dc.date.available.fl_str_mv |
2022-10-17T21:54:09Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1843/46284 |
dc.identifier.doi.pt_BR.fl_str_mv |
https://doi.org/10.15392/bjrs.v6i1.317 |
dc.identifier.issn.pt_BR.fl_str_mv |
2319-0612 |
url |
https://doi.org/10.15392/bjrs.v6i1.317 http://hdl.handle.net/1843/46284 |
identifier_str_mv |
2319-0612 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartof.pt_BR.fl_str_mv |
Brazilian Journal of Radiation Sciences |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
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openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Minas Gerais |
dc.publisher.initials.fl_str_mv |
UFMG |
dc.publisher.country.fl_str_mv |
Brasil |
dc.publisher.department.fl_str_mv |
ENG - DEPARTAMENTO DE ENGENHARIA NUCLEAR |
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Universidade Federal de Minas Gerais |
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UFMG |
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