Polymer-based Nanocomposites of P(VDF-TrFE)/Bi2O3 Applied to X-ray Shielding
Autor(a) principal: | |
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Data de Publicação: | 2016 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFMG |
Texto Completo: | http://hdl.handle.net/1843/57096 |
Resumo: | Radiology procedures such as fluoroscopy provide high doses to patients because they involve long periods of direct X-rays beam pointing to the same region. Composite materials containing compounds or elements with good attenuation properties such as barium sulfate and lead have been studied elsewhere. In this study, polymer based composites made of Poly(vinylidene fluoride-tryfluorethylene) [P(VDF TrFE)] copolymers and micro and nanosized crystalline Bismuth Oxide were prepared. The main objective of this work was to identify the morphological differences between micro and nanocomposites and their performance as X-ray shielding material. The bismuth oxide was previously surface-modified with Methyl-Methacrylate Acid (MMA) in order to improve the homogeneity distribution. The X-ray shielding characterization was performed for photons with energies ranging from 6.5 keV to 83.5 keV. The nanocomposite P(VDF-TrFE)/nano Bi2O3-MMA revealed to have better attenuation features than the microcomposite, in the entire range of energy studied. DRX, DSC, FTIR and SEM images data were used in order to understand the difference in the radiation shielding features. The investigation has demonstrated that the P(VDF TrFE)/nano Bi2O3-MMA nanocomposites are good candidates for application in radiology procedures as lightweight, conformable, flexible, and easy to process X-ray shielding materials. |
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2023-07-27T19:56:29Z2023-07-27T19:56:29Z2016-07-2543162323472278http://hdl.handle.net/1843/57096Radiology procedures such as fluoroscopy provide high doses to patients because they involve long periods of direct X-rays beam pointing to the same region. Composite materials containing compounds or elements with good attenuation properties such as barium sulfate and lead have been studied elsewhere. In this study, polymer based composites made of Poly(vinylidene fluoride-tryfluorethylene) [P(VDF TrFE)] copolymers and micro and nanosized crystalline Bismuth Oxide were prepared. The main objective of this work was to identify the morphological differences between micro and nanocomposites and their performance as X-ray shielding material. The bismuth oxide was previously surface-modified with Methyl-Methacrylate Acid (MMA) in order to improve the homogeneity distribution. The X-ray shielding characterization was performed for photons with energies ranging from 6.5 keV to 83.5 keV. The nanocomposite P(VDF-TrFE)/nano Bi2O3-MMA revealed to have better attenuation features than the microcomposite, in the entire range of energy studied. DRX, DSC, FTIR and SEM images data were used in order to understand the difference in the radiation shielding features. The investigation has demonstrated that the P(VDF TrFE)/nano Bi2O3-MMA nanocomposites are good candidates for application in radiology procedures as lightweight, conformable, flexible, and easy to process X-ray shielding materials.engUniversidade Federal de Minas GeraisUFMGBrasilMED - DEPARTAMENTO DE ANATOMIA E IMAGEMResearch & Reviews: Journal of Material SciencesRaios XNanocompostosPolimetil MetacrilatoP(VDF-TrFE)/Bi2O3Polymer-based NanocompositesX-rays shieldingProtective MaterialsPolymer-based Nanocomposites of P(VDF-TrFE)/Bi2O3 Applied to X-ray Shieldinginfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://www.rroij.com/open-access/polymerbased-nanocomposites-of-pvdftrfebi2o3-applied-to-xray-.php?aid=76851Críssia Carem Paiva FontainhaAnnibal Teotonio Baptista NetoLuiz Oliveira de Fariaapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/57096/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALPolymer-based nanocomposites of p vdf-trfe bi2o3 applied to x-ray shielding pdfa.pdfPolymer-based nanocomposites of p vdf-trfe bi2o3 applied to x-ray shielding pdfa.pdfapplication/pdf1428758https://repositorio.ufmg.br/bitstream/1843/57096/2/Polymer-based%20nanocomposites%20of%20p%20vdf-trfe%20%20bi2o3%20applied%20to%20x-ray%20shielding%20pdfa.pdf677620e14b6695d5e97d4a775d927f42MD521843/570962023-07-27 18:21:01.766oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2023-07-27T21:21:01Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false |
dc.title.pt_BR.fl_str_mv |
Polymer-based Nanocomposites of P(VDF-TrFE)/Bi2O3 Applied to X-ray Shielding |
title |
Polymer-based Nanocomposites of P(VDF-TrFE)/Bi2O3 Applied to X-ray Shielding |
spellingShingle |
Polymer-based Nanocomposites of P(VDF-TrFE)/Bi2O3 Applied to X-ray Shielding Críssia Carem Paiva Fontainha P(VDF-TrFE)/Bi2O3 Polymer-based Nanocomposites X-rays shielding Protective Materials Raios X Nanocompostos Polimetil Metacrilato |
title_short |
Polymer-based Nanocomposites of P(VDF-TrFE)/Bi2O3 Applied to X-ray Shielding |
title_full |
Polymer-based Nanocomposites of P(VDF-TrFE)/Bi2O3 Applied to X-ray Shielding |
title_fullStr |
Polymer-based Nanocomposites of P(VDF-TrFE)/Bi2O3 Applied to X-ray Shielding |
title_full_unstemmed |
Polymer-based Nanocomposites of P(VDF-TrFE)/Bi2O3 Applied to X-ray Shielding |
title_sort |
Polymer-based Nanocomposites of P(VDF-TrFE)/Bi2O3 Applied to X-ray Shielding |
author |
Críssia Carem Paiva Fontainha |
author_facet |
Críssia Carem Paiva Fontainha Annibal Teotonio Baptista Neto Luiz Oliveira de Faria |
author_role |
author |
author2 |
Annibal Teotonio Baptista Neto Luiz Oliveira de Faria |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Críssia Carem Paiva Fontainha Annibal Teotonio Baptista Neto Luiz Oliveira de Faria |
dc.subject.por.fl_str_mv |
P(VDF-TrFE)/Bi2O3 Polymer-based Nanocomposites X-rays shielding Protective Materials |
topic |
P(VDF-TrFE)/Bi2O3 Polymer-based Nanocomposites X-rays shielding Protective Materials Raios X Nanocompostos Polimetil Metacrilato |
dc.subject.other.pt_BR.fl_str_mv |
Raios X Nanocompostos Polimetil Metacrilato |
description |
Radiology procedures such as fluoroscopy provide high doses to patients because they involve long periods of direct X-rays beam pointing to the same region. Composite materials containing compounds or elements with good attenuation properties such as barium sulfate and lead have been studied elsewhere. In this study, polymer based composites made of Poly(vinylidene fluoride-tryfluorethylene) [P(VDF TrFE)] copolymers and micro and nanosized crystalline Bismuth Oxide were prepared. The main objective of this work was to identify the morphological differences between micro and nanocomposites and their performance as X-ray shielding material. The bismuth oxide was previously surface-modified with Methyl-Methacrylate Acid (MMA) in order to improve the homogeneity distribution. The X-ray shielding characterization was performed for photons with energies ranging from 6.5 keV to 83.5 keV. The nanocomposite P(VDF-TrFE)/nano Bi2O3-MMA revealed to have better attenuation features than the microcomposite, in the entire range of energy studied. DRX, DSC, FTIR and SEM images data were used in order to understand the difference in the radiation shielding features. The investigation has demonstrated that the P(VDF TrFE)/nano Bi2O3-MMA nanocomposites are good candidates for application in radiology procedures as lightweight, conformable, flexible, and easy to process X-ray shielding materials. |
publishDate |
2016 |
dc.date.issued.fl_str_mv |
2016-07-25 |
dc.date.accessioned.fl_str_mv |
2023-07-27T19:56:29Z |
dc.date.available.fl_str_mv |
2023-07-27T19:56:29Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/1843/57096 |
dc.identifier.issn.pt_BR.fl_str_mv |
23472278 |
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23472278 |
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http://hdl.handle.net/1843/57096 |
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eng |
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eng |
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Research & Reviews: Journal of Material Sciences |
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Universidade Federal de Minas Gerais |
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UFMG |
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Brasil |
dc.publisher.department.fl_str_mv |
MED - DEPARTAMENTO DE ANATOMIA E IMAGEM |
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Universidade Federal de Minas Gerais |
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