Transferência de energia entre corantes catiônicos em sistemas homogêneos
Autor(a) principal: | |
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Data de Publicação: | 2003 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Repositório Institucional da UFMS |
Texto Completo: | https://repositorio.ufms.br/handle/123456789/751 http://dx.doi.org/10.1590/S0100-40422003000400020 |
Resumo: | In this work, the energy transfer by dipole-dipole interaction between cationic dyes in n-alcohols (methanol, ethanol, 1-propanol and 1-butanol) is studied by time resolved and steady state fluorescence measurements. The critical radii of energy transfer were determined by three independent methods; the spectral overlap, fluorescence decay profiles, and relative intensity measurements. In all solvents, R0 values of the dye pairs obtained from spectral overlap were between 40 to 90 Å. Steady state and time resolved fluorescence measurements resulted in values of R0 in the range of 50 - 80 Å, with good correlation of values. |
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2011-11-07T18:33:03Z2021-09-30T19:57:36Z2003OLIVEIRA, Hueder Paulo Moisés de et al . Transferência de energia entre corantes catiônicos em sistemas homogêneos. Quím. Nova, São Paulo, v. 26, n. 4, ago. 2003 . Disponível em <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422003000400020&lng=pt&nrm=iso>. acessos em 07 nov. 2011. http://dx.doi.org/10.1590/S0100-40422003000400020.https://repositorio.ufms.br/handle/123456789/751http://dx.doi.org/10.1590/S0100-40422003000400020In this work, the energy transfer by dipole-dipole interaction between cationic dyes in n-alcohols (methanol, ethanol, 1-propanol and 1-butanol) is studied by time resolved and steady state fluorescence measurements. The critical radii of energy transfer were determined by three independent methods; the spectral overlap, fluorescence decay profiles, and relative intensity measurements. In all solvents, R0 values of the dye pairs obtained from spectral overlap were between 40 to 90 Å. Steady state and time resolved fluorescence measurements resulted in values of R0 in the range of 50 - 80 Å, with good correlation of values.porQuímica NovaTransferência de EnergiaAgentes CorantesFluorescênciaEnergy TransferColoring AgentsFluorescenceTransferência de energia entre corantes catiônicos em sistemas homogêneosEnergy transfer between cationic dyes in homogeneous systemsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleOliveira, Hueder Paulo Moisés deMachulek Junior, AmilcarLegendre, Alexandre de OliveiraGehlen, Marcelo Henriqueinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMSinstname:Universidade Federal de Mato Grosso do Sul (UFMS)instacron:UFMSTHUMBNAILTranferencia de energia.pdf.jpgTranferencia de energia.pdf.jpgGenerated Thumbnailimage/jpeg1497https://repositorio.ufms.br/bitstream/123456789/751/4/Tranferencia%20de%20energia.pdf.jpg7f4cf734b0ed6230ce7d5e4a94a2e8acMD54ORIGINALTranferencia de energia.pdfTranferencia de energia.pdfapplication/pdf385669https://repositorio.ufms.br/bitstream/123456789/751/1/Tranferencia%20de%20energia.pdf88f9a4437990a90f873ac7433e2486bcMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://repositorio.ufms.br/bitstream/123456789/751/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52TEXTTranferencia de energia.pdf.txtTranferencia de energia.pdf.txtExtracted texttext/plain23555https://repositorio.ufms.br/bitstream/123456789/751/3/Tranferencia%20de%20energia.pdf.txt9faeb38b383b9abc1d986859964d0aafMD53123456789/7512021-09-30 15:57:36.309oai:repositorio.ufms.br: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Repositório InstitucionalPUBhttps://repositorio.ufms.br/oai/requestri.prograd@ufms.bropendoar:21242021-09-30T19:57:36Repositório Institucional da UFMS - Universidade Federal de Mato Grosso do Sul (UFMS)false |
dc.title.pt_BR.fl_str_mv |
Transferência de energia entre corantes catiônicos em sistemas homogêneos |
dc.title.alternative.pt_BR.fl_str_mv |
Energy transfer between cationic dyes in homogeneous systems |
title |
Transferência de energia entre corantes catiônicos em sistemas homogêneos |
spellingShingle |
Transferência de energia entre corantes catiônicos em sistemas homogêneos Oliveira, Hueder Paulo Moisés de Transferência de Energia Agentes Corantes Fluorescência Energy Transfer Coloring Agents Fluorescence |
title_short |
Transferência de energia entre corantes catiônicos em sistemas homogêneos |
title_full |
Transferência de energia entre corantes catiônicos em sistemas homogêneos |
title_fullStr |
Transferência de energia entre corantes catiônicos em sistemas homogêneos |
title_full_unstemmed |
Transferência de energia entre corantes catiônicos em sistemas homogêneos |
title_sort |
Transferência de energia entre corantes catiônicos em sistemas homogêneos |
author |
Oliveira, Hueder Paulo Moisés de |
author_facet |
Oliveira, Hueder Paulo Moisés de Machulek Junior, Amilcar Legendre, Alexandre de Oliveira Gehlen, Marcelo Henrique |
author_role |
author |
author2 |
Machulek Junior, Amilcar Legendre, Alexandre de Oliveira Gehlen, Marcelo Henrique |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Oliveira, Hueder Paulo Moisés de Machulek Junior, Amilcar Legendre, Alexandre de Oliveira Gehlen, Marcelo Henrique |
dc.subject.por.fl_str_mv |
Transferência de Energia Agentes Corantes Fluorescência Energy Transfer Coloring Agents Fluorescence |
topic |
Transferência de Energia Agentes Corantes Fluorescência Energy Transfer Coloring Agents Fluorescence |
description |
In this work, the energy transfer by dipole-dipole interaction between cationic dyes in n-alcohols (methanol, ethanol, 1-propanol and 1-butanol) is studied by time resolved and steady state fluorescence measurements. The critical radii of energy transfer were determined by three independent methods; the spectral overlap, fluorescence decay profiles, and relative intensity measurements. In all solvents, R0 values of the dye pairs obtained from spectral overlap were between 40 to 90 Å. Steady state and time resolved fluorescence measurements resulted in values of R0 in the range of 50 - 80 Å, with good correlation of values. |
publishDate |
2003 |
dc.date.issued.fl_str_mv |
2003 |
dc.date.accessioned.fl_str_mv |
2011-11-07T18:33:03Z |
dc.date.available.fl_str_mv |
2021-09-30T19:57:36Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
OLIVEIRA, Hueder Paulo Moisés de et al . Transferência de energia entre corantes catiônicos em sistemas homogêneos. Quím. Nova, São Paulo, v. 26, n. 4, ago. 2003 . Disponível em <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422003000400020&lng=pt&nrm=iso>. acessos em 07 nov. 2011. http://dx.doi.org/10.1590/S0100-40422003000400020. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufms.br/handle/123456789/751 |
dc.identifier.doi.none.fl_str_mv |
http://dx.doi.org/10.1590/S0100-40422003000400020 |
identifier_str_mv |
OLIVEIRA, Hueder Paulo Moisés de et al . Transferência de energia entre corantes catiônicos em sistemas homogêneos. Quím. Nova, São Paulo, v. 26, n. 4, ago. 2003 . Disponível em <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422003000400020&lng=pt&nrm=iso>. acessos em 07 nov. 2011. http://dx.doi.org/10.1590/S0100-40422003000400020. |
url |
https://repositorio.ufms.br/handle/123456789/751 http://dx.doi.org/10.1590/S0100-40422003000400020 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
Química Nova |
publisher.none.fl_str_mv |
Química Nova |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFMS instname:Universidade Federal de Mato Grosso do Sul (UFMS) instacron:UFMS |
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Universidade Federal de Mato Grosso do Sul (UFMS) |
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UFMS |
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UFMS |
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Repositório Institucional da UFMS |
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Repositório Institucional da UFMS |
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