Chemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser.

Detalhes bibliográficos
Autor(a) principal: Botaro, Vagner Roberto
Data de Publicação: 2001
Outros Autores: Santos, Cláudio Gouvêa dos, Arantes Júnior, Gilberto, Costa, Adilson Rodrigues da
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFOP
Texto Completo: http://www.repositorio.ufop.br/handle/123456789/870
Resumo: Most reports about modification of lignocellulosics are mainly based on chemical modifications such as specific reactions on hydroxyl groups of cellulose. In this work, we describe the irradiation of Whatman 5 filter paper, microcrystalline cellulose and organosolv lignin with Nd-YAG laser pulses at 1064 nm. The chemical and structural properties of the degraded products were investigated by using FTIR and UV spectroscopies, conductimetrical and SEC analyses. While irradiation affects molar mass and polydispersity of lignin, no detrimental effects caused by Nd-YAG laser treatments were observed for cellulose samples. These results demonstrate that Nd-YAG laser can be used as a practical and selective degradation tool, opening a new field for obtaining surface modified natural fibers.
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spelling Botaro, Vagner RobertoSantos, Cláudio Gouvêa dosArantes Júnior, GilbertoCosta, Adilson Rodrigues da2012-06-18T18:43:37Z2012-06-18T18:43:37Z2001BOTARO, V. R.; SANTOS, C. G. dos; ARANTES JÚNIOR, G. Chemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser. Applied Surface Science, v. 183, n.1-2, p.120–125, nov. 2001. Disponível em: <https://www.sciencedirect.com/science/article/pii/S0169433201005712>. Acesso em: 18 jun. 2012.01694332http://www.repositorio.ufop.br/handle/123456789/870Most reports about modification of lignocellulosics are mainly based on chemical modifications such as specific reactions on hydroxyl groups of cellulose. In this work, we describe the irradiation of Whatman 5 filter paper, microcrystalline cellulose and organosolv lignin with Nd-YAG laser pulses at 1064 nm. The chemical and structural properties of the degraded products were investigated by using FTIR and UV spectroscopies, conductimetrical and SEC analyses. While irradiation affects molar mass and polydispersity of lignin, no detrimental effects caused by Nd-YAG laser treatments were observed for cellulose samples. These results demonstrate that Nd-YAG laser can be used as a practical and selective degradation tool, opening a new field for obtaining surface modified natural fibers.Applied Surface ScienceLaserCompositeModificationSurfacesChemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser.info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleO Periódico Applied Surface Science concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3310910802468info:eu-repo/semantics/openAccessengreponame:Repositório Institucional da UFOPinstname:Universidade Federal de Ouro Preto (UFOP)instacron:UFOPLICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://www.repositorio.ufop.br/bitstream/123456789/870/5/license.txt8a4605be74aa9ea9d79846c1fba20a33MD55ORIGINALARTIGO_ChemicalModificationLignocellulosic.pdfARTIGO_ChemicalModificationLignocellulosic.pdfapplication/pdf110333http://www.repositorio.ufop.br/bitstream/123456789/870/1/ARTIGO_ChemicalModificationLignocellulosic.pdf4c041829ea68dca94de92b21d45547a4MD51123456789/8702019-02-22 14:08:04.717oai:localhost: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Repositório InstitucionalPUBhttp://www.repositorio.ufop.br/oai/requestrepositorio@ufop.edu.bropendoar:32332019-02-22T19:08:04Repositório Institucional da UFOP - Universidade Federal de Ouro Preto (UFOP)false
dc.title.pt_BR.fl_str_mv Chemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser.
title Chemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser.
spellingShingle Chemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser.
Botaro, Vagner Roberto
Laser
Composite
Modification
Surfaces
title_short Chemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser.
title_full Chemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser.
title_fullStr Chemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser.
title_full_unstemmed Chemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser.
title_sort Chemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser.
author Botaro, Vagner Roberto
author_facet Botaro, Vagner Roberto
Santos, Cláudio Gouvêa dos
Arantes Júnior, Gilberto
Costa, Adilson Rodrigues da
author_role author
author2 Santos, Cláudio Gouvêa dos
Arantes Júnior, Gilberto
Costa, Adilson Rodrigues da
author2_role author
author
author
dc.contributor.author.fl_str_mv Botaro, Vagner Roberto
Santos, Cláudio Gouvêa dos
Arantes Júnior, Gilberto
Costa, Adilson Rodrigues da
dc.subject.por.fl_str_mv Laser
Composite
Modification
Surfaces
topic Laser
Composite
Modification
Surfaces
description Most reports about modification of lignocellulosics are mainly based on chemical modifications such as specific reactions on hydroxyl groups of cellulose. In this work, we describe the irradiation of Whatman 5 filter paper, microcrystalline cellulose and organosolv lignin with Nd-YAG laser pulses at 1064 nm. The chemical and structural properties of the degraded products were investigated by using FTIR and UV spectroscopies, conductimetrical and SEC analyses. While irradiation affects molar mass and polydispersity of lignin, no detrimental effects caused by Nd-YAG laser treatments were observed for cellulose samples. These results demonstrate that Nd-YAG laser can be used as a practical and selective degradation tool, opening a new field for obtaining surface modified natural fibers.
publishDate 2001
dc.date.issued.fl_str_mv 2001
dc.date.accessioned.fl_str_mv 2012-06-18T18:43:37Z
dc.date.available.fl_str_mv 2012-06-18T18:43:37Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.citation.fl_str_mv BOTARO, V. R.; SANTOS, C. G. dos; ARANTES JÚNIOR, G. Chemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser. Applied Surface Science, v. 183, n.1-2, p.120–125, nov. 2001. Disponível em: <https://www.sciencedirect.com/science/article/pii/S0169433201005712>. Acesso em: 18 jun. 2012.
dc.identifier.uri.fl_str_mv http://www.repositorio.ufop.br/handle/123456789/870
dc.identifier.issn.none.fl_str_mv 01694332
identifier_str_mv BOTARO, V. R.; SANTOS, C. G. dos; ARANTES JÚNIOR, G. Chemical modification of lignocellulosic materials by irradiation with Nd-YAG pulsed laser. Applied Surface Science, v. 183, n.1-2, p.120–125, nov. 2001. Disponível em: <https://www.sciencedirect.com/science/article/pii/S0169433201005712>. Acesso em: 18 jun. 2012.
01694332
url http://www.repositorio.ufop.br/handle/123456789/870
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Applied Surface Science
publisher.none.fl_str_mv Applied Surface Science
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFOP
instname:Universidade Federal de Ouro Preto (UFOP)
instacron:UFOP
instname_str Universidade Federal de Ouro Preto (UFOP)
instacron_str UFOP
institution UFOP
reponame_str Repositório Institucional da UFOP
collection Repositório Institucional da UFOP
bitstream.url.fl_str_mv http://www.repositorio.ufop.br/bitstream/123456789/870/5/license.txt
http://www.repositorio.ufop.br/bitstream/123456789/870/1/ARTIGO_ChemicalModificationLignocellulosic.pdf
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