Persistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials.
Autor(a) principal: | |
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Data de Publicação: | 2009 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFOP |
Texto Completo: | http://www.repositorio.ufop.br/handle/123456789/1218 |
Resumo: | Polycrystalline Eu2+ and Dy3+ doped barium aluminate materials, BaAl2O4:Eu2+,Dy3+, were prepared with solid state reactions at temperatures between 700 and 1500 _C. The influence of the thermal treatments on the stability, homogeneity and structure as well as to the UV-excited and persistent luminescence of the materials was investigated by X-ray powder diffraction, SEM imaging and infrared spectroscopies as well as by steady state luminescence spectroscopy and persistent luminescence decay curves, respectively. The IR spectra of the materials prepared at 250, 700, and 1500 _C follow the formation of BaAl2O4 composition whereas the X-ray powder diffraction of compounds revealed how the hexagonal structure was obtained. The morphology of the materials at high temperatures indicated important aggregation due to sintering. The luminescence decay of the quite narrow Eu2+ band at ca. 500 nm shows the presence of persistent luminescence after UV irradiation. The dopant (Eu2+) and co-dopant (Dy3+) concentrations affect the crystallinity and luminescence properties of the materials. |
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Stefani, RobervalRodrigues, Lucas Carvalho VelosoCarvalho, Carlos Alberto Alves deFelinto, Maria Claudia França da CunhaBrito, Hermi Felinto deLastusaari, MikaHölsä, Jorma2012-08-01T12:18:30Z2012-08-01T12:18:30Z2009STEFANI, R. et al. Persistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials. Optical Materials, v. 31, n.12, p.1815-1818, out. 2009. Disponível em: <http://www.ipen.br/biblioteca/2009/14530.pdf>. Acesso em: 01 ago. 2012.09253467http://www.repositorio.ufop.br/handle/123456789/1218Polycrystalline Eu2+ and Dy3+ doped barium aluminate materials, BaAl2O4:Eu2+,Dy3+, were prepared with solid state reactions at temperatures between 700 and 1500 _C. The influence of the thermal treatments on the stability, homogeneity and structure as well as to the UV-excited and persistent luminescence of the materials was investigated by X-ray powder diffraction, SEM imaging and infrared spectroscopies as well as by steady state luminescence spectroscopy and persistent luminescence decay curves, respectively. The IR spectra of the materials prepared at 250, 700, and 1500 _C follow the formation of BaAl2O4 composition whereas the X-ray powder diffraction of compounds revealed how the hexagonal structure was obtained. The morphology of the materials at high temperatures indicated important aggregation due to sintering. The luminescence decay of the quite narrow Eu2+ band at ca. 500 nm shows the presence of persistent luminescence after UV irradiation. The dopant (Eu2+) and co-dopant (Dy3+) concentrations affect the crystallinity and luminescence properties of the materials.Optical MaterialsBarium aluminateDysprosiumEuropiumPersistent luminescencePersistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials.info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleO periódico Optical Materials concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença 3333160408518.info:eu-repo/semantics/openAccessengreponame:Repositório Institucional da UFOPinstname:Universidade Federal de Ouro Preto (UFOP)instacron:UFOPLICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://www.repositorio.ufop.br/bitstream/123456789/1218/5/license.txt8a4605be74aa9ea9d79846c1fba20a33MD55ORIGINALARTIGO_PersistentLuminescenceDoped.pdfARTIGO_PersistentLuminescenceDoped.pdfapplication/pdf368208http://www.repositorio.ufop.br/bitstream/123456789/1218/1/ARTIGO_PersistentLuminescenceDoped.pdff23eaf245c7b8e87da84ca11718ddb72MD51123456789/12182019-02-28 10:16:57.183oai:localhost: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Repositório InstitucionalPUBhttp://www.repositorio.ufop.br/oai/requestrepositorio@ufop.edu.bropendoar:32332019-02-28T15:16:57Repositório Institucional da UFOP - Universidade Federal de Ouro Preto (UFOP)false |
dc.title.pt_BR.fl_str_mv |
Persistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials. |
title |
Persistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials. |
spellingShingle |
Persistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials. Stefani, Roberval Barium aluminate Dysprosium Europium Persistent luminescence |
title_short |
Persistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials. |
title_full |
Persistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials. |
title_fullStr |
Persistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials. |
title_full_unstemmed |
Persistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials. |
title_sort |
Persistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials. |
author |
Stefani, Roberval |
author_facet |
Stefani, Roberval Rodrigues, Lucas Carvalho Veloso Carvalho, Carlos Alberto Alves de Felinto, Maria Claudia França da Cunha Brito, Hermi Felinto de Lastusaari, Mika Hölsä, Jorma |
author_role |
author |
author2 |
Rodrigues, Lucas Carvalho Veloso Carvalho, Carlos Alberto Alves de Felinto, Maria Claudia França da Cunha Brito, Hermi Felinto de Lastusaari, Mika Hölsä, Jorma |
author2_role |
author author author author author author |
dc.contributor.author.fl_str_mv |
Stefani, Roberval Rodrigues, Lucas Carvalho Veloso Carvalho, Carlos Alberto Alves de Felinto, Maria Claudia França da Cunha Brito, Hermi Felinto de Lastusaari, Mika Hölsä, Jorma |
dc.subject.por.fl_str_mv |
Barium aluminate Dysprosium Europium Persistent luminescence |
topic |
Barium aluminate Dysprosium Europium Persistent luminescence |
description |
Polycrystalline Eu2+ and Dy3+ doped barium aluminate materials, BaAl2O4:Eu2+,Dy3+, were prepared with solid state reactions at temperatures between 700 and 1500 _C. The influence of the thermal treatments on the stability, homogeneity and structure as well as to the UV-excited and persistent luminescence of the materials was investigated by X-ray powder diffraction, SEM imaging and infrared spectroscopies as well as by steady state luminescence spectroscopy and persistent luminescence decay curves, respectively. The IR spectra of the materials prepared at 250, 700, and 1500 _C follow the formation of BaAl2O4 composition whereas the X-ray powder diffraction of compounds revealed how the hexagonal structure was obtained. The morphology of the materials at high temperatures indicated important aggregation due to sintering. The luminescence decay of the quite narrow Eu2+ band at ca. 500 nm shows the presence of persistent luminescence after UV irradiation. The dopant (Eu2+) and co-dopant (Dy3+) concentrations affect the crystallinity and luminescence properties of the materials. |
publishDate |
2009 |
dc.date.issued.fl_str_mv |
2009 |
dc.date.accessioned.fl_str_mv |
2012-08-01T12:18:30Z |
dc.date.available.fl_str_mv |
2012-08-01T12:18:30Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
STEFANI, R. et al. Persistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials. Optical Materials, v. 31, n.12, p.1815-1818, out. 2009. Disponível em: <http://www.ipen.br/biblioteca/2009/14530.pdf>. Acesso em: 01 ago. 2012. |
dc.identifier.uri.fl_str_mv |
http://www.repositorio.ufop.br/handle/123456789/1218 |
dc.identifier.issn.none.fl_str_mv |
09253467 |
identifier_str_mv |
STEFANI, R. et al. Persistent luminescence of Eu2+ and Dy3+ doped barium aluminate (BaAl2O4:Eu2+,Dy3+) materials. Optical Materials, v. 31, n.12, p.1815-1818, out. 2009. Disponível em: <http://www.ipen.br/biblioteca/2009/14530.pdf>. Acesso em: 01 ago. 2012. 09253467 |
url |
http://www.repositorio.ufop.br/handle/123456789/1218 |
dc.language.iso.fl_str_mv |
eng |
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eng |
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info:eu-repo/semantics/openAccess |
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openAccess |
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Optical Materials |
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Optical Materials |
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