Nanocomposite hydrogels based on iota - carrageenan and maghemite : morphological, thermal and magnetic properties.
Autor(a) principal: | |
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Data de Publicação: | 2016 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFOP |
Texto Completo: | http://www.repositorio.ufop.br/handle/123456789/6681 https://doi.org/10.1016/j.eurpolymj.2016.01.043 |
Resumo: | The objective of this work was to prepare and characterize magnetic hydrogels based on iota-carrageenan, a polysaccharide obtained from biomass (Rodophyceae algae), containing maghemite (c-Fe2O3) nanoparticles. The morphological, thermal and magnetic properties of the hydrogels were evaluated, as well as the influence of the crosslinking agent (CaCl2) at different concentrations (0.3 mol L_1 and 0.5 mol L_1) on the hydrogels’ properties. The samples were characterized by scanning and transmission electron microscopy, vibrating sample magnetometry, thermogravimetry, Fourier-transform infrared spectroscopy and Mössbauer spectroscopy. The swelling degree of the hydrogels was also determined. The results showed that the synthesized magnetic material was mostly composed of c-Fe2O3 and presented ferrimagnetic behavior. The hydrogels had spherical morphology and particle size in the range of 710 lm. The TEM images proved the magnetic particles had nanometric size. The hydrogels had good thermal stability and swelling degree in water of around 55%. Both the magnetic nanoparticles and crosslinking agent (Ca2+) were well distributed on the surface of the hydrogels. The samples responded to the stimulus of a magnet. |
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Maciel, Diana JoséFerreira, Ivana Lourenço de MelloCosta, Geraldo Magela daSilva, Manoel Ribeiro da2016-07-29T16:52:28Z2016-07-29T16:52:28Z2016MACIEL, D. J. et al. Nanocomposite hydrogels based on iota - carrageenan and maghemite: morphological, thermal and magnetic properties. European Polymer Journal, v. 76, p. 147-155, 2016. Disponível em: <http://www.sciencedirect.com/science/article/pii/S0014305716300416>. Acesso em: 16 jun. 2016.0014-3057http://www.repositorio.ufop.br/handle/123456789/6681https://doi.org/10.1016/j.eurpolymj.2016.01.043The objective of this work was to prepare and characterize magnetic hydrogels based on iota-carrageenan, a polysaccharide obtained from biomass (Rodophyceae algae), containing maghemite (c-Fe2O3) nanoparticles. The morphological, thermal and magnetic properties of the hydrogels were evaluated, as well as the influence of the crosslinking agent (CaCl2) at different concentrations (0.3 mol L_1 and 0.5 mol L_1) on the hydrogels’ properties. The samples were characterized by scanning and transmission electron microscopy, vibrating sample magnetometry, thermogravimetry, Fourier-transform infrared spectroscopy and Mössbauer spectroscopy. The swelling degree of the hydrogels was also determined. The results showed that the synthesized magnetic material was mostly composed of c-Fe2O3 and presented ferrimagnetic behavior. The hydrogels had spherical morphology and particle size in the range of 710 lm. The TEM images proved the magnetic particles had nanometric size. The hydrogels had good thermal stability and swelling degree in water of around 55%. Both the magnetic nanoparticles and crosslinking agent (Ca2+) were well distributed on the surface of the hydrogels. The samples responded to the stimulus of a magnet.O periódico European Polymer Journal concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3898810687893.info:eu-repo/semantics/openAccessMagnetic hydrogelsThermal propertiesMaghemiteMorphological propertiesMagnetic propertiesNanocomposite hydrogels based on iota - carrageenan and maghemite : morphological, thermal and magnetic properties.info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleengreponame:Repositório Institucional da UFOPinstname:Universidade Federal de Ouro Preto (UFOP)instacron:UFOPLICENSElicense.txtlicense.txttext/plain; charset=utf-8924http://www.repositorio.ufop.br/bitstream/123456789/6681/2/license.txt62604f8d955274beb56c80ce1ee5dcaeMD52ORIGINALARTIGO_NanocompositeHidrogelsIota.pdfARTIGO_NanocompositeHidrogelsIota.pdfapplication/pdf1775946http://www.repositorio.ufop.br/bitstream/123456789/6681/1/ARTIGO_NanocompositeHidrogelsIota.pdf1239d828f3062226c77acc6fa052c9cbMD51123456789/66812019-09-23 10:03:13.765oai:localhost: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ório InstitucionalPUBhttp://www.repositorio.ufop.br/oai/requestrepositorio@ufop.edu.bropendoar:32332019-09-23T14:03:13Repositório Institucional da UFOP - Universidade Federal de Ouro Preto (UFOP)false |
dc.title.pt_BR.fl_str_mv |
Nanocomposite hydrogels based on iota - carrageenan and maghemite : morphological, thermal and magnetic properties. |
title |
Nanocomposite hydrogels based on iota - carrageenan and maghemite : morphological, thermal and magnetic properties. |
spellingShingle |
Nanocomposite hydrogels based on iota - carrageenan and maghemite : morphological, thermal and magnetic properties. Maciel, Diana José Magnetic hydrogels Thermal properties Maghemite Morphological properties Magnetic properties |
title_short |
Nanocomposite hydrogels based on iota - carrageenan and maghemite : morphological, thermal and magnetic properties. |
title_full |
Nanocomposite hydrogels based on iota - carrageenan and maghemite : morphological, thermal and magnetic properties. |
title_fullStr |
Nanocomposite hydrogels based on iota - carrageenan and maghemite : morphological, thermal and magnetic properties. |
title_full_unstemmed |
Nanocomposite hydrogels based on iota - carrageenan and maghemite : morphological, thermal and magnetic properties. |
title_sort |
Nanocomposite hydrogels based on iota - carrageenan and maghemite : morphological, thermal and magnetic properties. |
author |
Maciel, Diana José |
author_facet |
Maciel, Diana José Ferreira, Ivana Lourenço de Mello Costa, Geraldo Magela da Silva, Manoel Ribeiro da |
author_role |
author |
author2 |
Ferreira, Ivana Lourenço de Mello Costa, Geraldo Magela da Silva, Manoel Ribeiro da |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Maciel, Diana José Ferreira, Ivana Lourenço de Mello Costa, Geraldo Magela da Silva, Manoel Ribeiro da |
dc.subject.por.fl_str_mv |
Magnetic hydrogels Thermal properties Maghemite Morphological properties Magnetic properties |
topic |
Magnetic hydrogels Thermal properties Maghemite Morphological properties Magnetic properties |
description |
The objective of this work was to prepare and characterize magnetic hydrogels based on iota-carrageenan, a polysaccharide obtained from biomass (Rodophyceae algae), containing maghemite (c-Fe2O3) nanoparticles. The morphological, thermal and magnetic properties of the hydrogels were evaluated, as well as the influence of the crosslinking agent (CaCl2) at different concentrations (0.3 mol L_1 and 0.5 mol L_1) on the hydrogels’ properties. The samples were characterized by scanning and transmission electron microscopy, vibrating sample magnetometry, thermogravimetry, Fourier-transform infrared spectroscopy and Mössbauer spectroscopy. The swelling degree of the hydrogels was also determined. The results showed that the synthesized magnetic material was mostly composed of c-Fe2O3 and presented ferrimagnetic behavior. The hydrogels had spherical morphology and particle size in the range of 710 lm. The TEM images proved the magnetic particles had nanometric size. The hydrogels had good thermal stability and swelling degree in water of around 55%. Both the magnetic nanoparticles and crosslinking agent (Ca2+) were well distributed on the surface of the hydrogels. The samples responded to the stimulus of a magnet. |
publishDate |
2016 |
dc.date.accessioned.fl_str_mv |
2016-07-29T16:52:28Z |
dc.date.available.fl_str_mv |
2016-07-29T16:52:28Z |
dc.date.issued.fl_str_mv |
2016 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
MACIEL, D. J. et al. Nanocomposite hydrogels based on iota - carrageenan and maghemite: morphological, thermal and magnetic properties. European Polymer Journal, v. 76, p. 147-155, 2016. Disponível em: <http://www.sciencedirect.com/science/article/pii/S0014305716300416>. Acesso em: 16 jun. 2016. |
dc.identifier.uri.fl_str_mv |
http://www.repositorio.ufop.br/handle/123456789/6681 |
dc.identifier.issn.none.fl_str_mv |
0014-3057 |
dc.identifier.doi.none.fl_str_mv |
https://doi.org/10.1016/j.eurpolymj.2016.01.043 |
identifier_str_mv |
MACIEL, D. J. et al. Nanocomposite hydrogels based on iota - carrageenan and maghemite: morphological, thermal and magnetic properties. European Polymer Journal, v. 76, p. 147-155, 2016. Disponível em: <http://www.sciencedirect.com/science/article/pii/S0014305716300416>. Acesso em: 16 jun. 2016. 0014-3057 |
url |
http://www.repositorio.ufop.br/handle/123456789/6681 https://doi.org/10.1016/j.eurpolymj.2016.01.043 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
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reponame:Repositório Institucional da UFOP instname:Universidade Federal de Ouro Preto (UFOP) instacron:UFOP |
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Universidade Federal de Ouro Preto (UFOP) |
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UFOP |
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UFOP |
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Repositório Institucional da UFOP |
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Repositório Institucional da UFOP |
bitstream.url.fl_str_mv |
http://www.repositorio.ufop.br/bitstream/123456789/6681/2/license.txt http://www.repositorio.ufop.br/bitstream/123456789/6681/1/ARTIGO_NanocompositeHidrogelsIota.pdf |
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