Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4.
Autor(a) principal: | |
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Data de Publicação: | 2011 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFOP |
Texto Completo: | http://www.repositorio.ufop.br/handle/123456789/4972 https://doi.org/10.1016/j.cattod.2010.10.053 |
Resumo: | Methane decomposition is an endothermic process. Therefore a high temperature increases the methane conversion and improves the carbon accumulation. Nevertheless at high temperature conditions a faster deactivation of catalyst is generally observed. To keep the stability of the catalyst, lower reaction temperatures can be used as well as methane dilution but the catalytic activity is lowered. The aim of the present work consists in the study of the catalytic properties of Ni–Pt supported over MgAl2O4 for the selective conversion of methane into hydrogen and carbon nanotubes. The addition of a small amount of Pt to a nickel–MgAl2O4 catalyst promotes the formation of carbon nanotubes with a significant selectivity to MWCNT. The interest of using a bimetallic (Pt–Ni) catalyst is to favour the reduction of the Ni precursor (and the formation of small nickel particles). For the catalyst that we prepared methane is mainly transformed into structured MWCNTs if the reduction is complete while graphitization is observed over partially reduced catalysts. A fine characterization of the catalyst surface after each step of the preparation and use is currently under investigation in order to progress in the relationships between the surface composition and the CNTs formation. |
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Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4.Carbon nanotubesFree-hydrogenMethane conversionMethane decomposition is an endothermic process. Therefore a high temperature increases the methane conversion and improves the carbon accumulation. Nevertheless at high temperature conditions a faster deactivation of catalyst is generally observed. To keep the stability of the catalyst, lower reaction temperatures can be used as well as methane dilution but the catalytic activity is lowered. The aim of the present work consists in the study of the catalytic properties of Ni–Pt supported over MgAl2O4 for the selective conversion of methane into hydrogen and carbon nanotubes. The addition of a small amount of Pt to a nickel–MgAl2O4 catalyst promotes the formation of carbon nanotubes with a significant selectivity to MWCNT. The interest of using a bimetallic (Pt–Ni) catalyst is to favour the reduction of the Ni precursor (and the formation of small nickel particles). For the catalyst that we prepared methane is mainly transformed into structured MWCNTs if the reduction is complete while graphitization is observed over partially reduced catalysts. A fine characterization of the catalyst surface after each step of the preparation and use is currently under investigation in order to progress in the relationships between the surface composition and the CNTs formation.2015-04-09T10:58:16Z2015-04-09T10:58:16Z2011info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfNUEMBERG, G. D. B. el al. Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4. Catalysis Today, v. 176, p. 465-469, 2011. Disponível em: <http://www.sciencedirect.com/science/article/pii/S0920586110006875>. Acesso em: 02 fev. 2015.0920-5861http://www.repositorio.ufop.br/handle/123456789/4972https://doi.org/10.1016/j.cattod.2010.10.053O periódico Catalysis Today concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3580760390908.info:eu-repo/semantics/openAccessNuernberg, Giselle De BoitFajardo, Humberto VieiraFoletto, Edson LuizProbst, Sonia Maria HickelCarreño, Neftalí Lenin VillarrealProbst, Luiz Fernando DiasBarrault, Joelengreponame:Repositório Institucional da UFOPinstname:Universidade Federal de Ouro Preto (UFOP)instacron:UFOP2019-07-09T12:48:53Zoai:repositorio.ufop.br:123456789/4972Repositório InstitucionalPUBhttp://www.repositorio.ufop.br/oai/requestrepositorio@ufop.edu.bropendoar:32332019-07-09T12:48:53Repositório Institucional da UFOP - Universidade Federal de Ouro Preto (UFOP)false |
dc.title.none.fl_str_mv |
Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4. |
title |
Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4. |
spellingShingle |
Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4. Nuernberg, Giselle De Boit Carbon nanotubes Free-hydrogen Methane conversion |
title_short |
Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4. |
title_full |
Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4. |
title_fullStr |
Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4. |
title_full_unstemmed |
Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4. |
title_sort |
Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4. |
author |
Nuernberg, Giselle De Boit |
author_facet |
Nuernberg, Giselle De Boit Fajardo, Humberto Vieira Foletto, Edson Luiz Probst, Sonia Maria Hickel Carreño, Neftalí Lenin Villarreal Probst, Luiz Fernando Dias Barrault, Joel |
author_role |
author |
author2 |
Fajardo, Humberto Vieira Foletto, Edson Luiz Probst, Sonia Maria Hickel Carreño, Neftalí Lenin Villarreal Probst, Luiz Fernando Dias Barrault, Joel |
author2_role |
author author author author author author |
dc.contributor.author.fl_str_mv |
Nuernberg, Giselle De Boit Fajardo, Humberto Vieira Foletto, Edson Luiz Probst, Sonia Maria Hickel Carreño, Neftalí Lenin Villarreal Probst, Luiz Fernando Dias Barrault, Joel |
dc.subject.por.fl_str_mv |
Carbon nanotubes Free-hydrogen Methane conversion |
topic |
Carbon nanotubes Free-hydrogen Methane conversion |
description |
Methane decomposition is an endothermic process. Therefore a high temperature increases the methane conversion and improves the carbon accumulation. Nevertheless at high temperature conditions a faster deactivation of catalyst is generally observed. To keep the stability of the catalyst, lower reaction temperatures can be used as well as methane dilution but the catalytic activity is lowered. The aim of the present work consists in the study of the catalytic properties of Ni–Pt supported over MgAl2O4 for the selective conversion of methane into hydrogen and carbon nanotubes. The addition of a small amount of Pt to a nickel–MgAl2O4 catalyst promotes the formation of carbon nanotubes with a significant selectivity to MWCNT. The interest of using a bimetallic (Pt–Ni) catalyst is to favour the reduction of the Ni precursor (and the formation of small nickel particles). For the catalyst that we prepared methane is mainly transformed into structured MWCNTs if the reduction is complete while graphitization is observed over partially reduced catalysts. A fine characterization of the catalyst surface after each step of the preparation and use is currently under investigation in order to progress in the relationships between the surface composition and the CNTs formation. |
publishDate |
2011 |
dc.date.none.fl_str_mv |
2011 2015-04-09T10:58:16Z 2015-04-09T10:58:16Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
NUEMBERG, G. D. B. el al. Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4. Catalysis Today, v. 176, p. 465-469, 2011. Disponível em: <http://www.sciencedirect.com/science/article/pii/S0920586110006875>. Acesso em: 02 fev. 2015. 0920-5861 http://www.repositorio.ufop.br/handle/123456789/4972 https://doi.org/10.1016/j.cattod.2010.10.053 |
identifier_str_mv |
NUEMBERG, G. D. B. el al. Methane conversion to hydrogen and nanotubes on Pt/Ni catalysts supported over spinel MgAl2O4. Catalysis Today, v. 176, p. 465-469, 2011. Disponível em: <http://www.sciencedirect.com/science/article/pii/S0920586110006875>. Acesso em: 02 fev. 2015. 0920-5861 |
url |
http://www.repositorio.ufop.br/handle/123456789/4972 https://doi.org/10.1016/j.cattod.2010.10.053 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFOP instname:Universidade Federal de Ouro Preto (UFOP) instacron:UFOP |
instname_str |
Universidade Federal de Ouro Preto (UFOP) |
instacron_str |
UFOP |
institution |
UFOP |
reponame_str |
Repositório Institucional da UFOP |
collection |
Repositório Institucional da UFOP |
repository.name.fl_str_mv |
Repositório Institucional da UFOP - Universidade Federal de Ouro Preto (UFOP) |
repository.mail.fl_str_mv |
repositorio@ufop.edu.br |
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1813002795665588224 |