Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles.
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFOP |
Texto Completo: | http://www.repositorio.ufop.br/handle/123456789/9611 https://doi.org/10.1016/j.catcom.2017.06.004 |
Resumo: | A microwave-assisted hydrothermal method was employed to synthesis Nb2O5 (niobium pentoxide) nanoparticles and the effects of synthesis conditions on the physical-chemical properties were evaluated. The catalytic activity of the prepared samples in the liquid phase oxidation of aniline with aqueous hydrogen peroxide as oxidizing agent was also studied. The nanoparticles showed hexagonal structure and rounded shape covered by nanoneedles. The results evidenced high catalytic activity with total conversion of aniline at ambient condition. Aniline conversion and product selectivities depended on the experimental parameters, particularly the oxidizing agent concentration, the nature of the solvent, type of the catalyst and reaction time. |
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Repositório Institucional da UFOP |
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Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles.Niobium pentoxideHydrogen peroxideAniline OxidationA microwave-assisted hydrothermal method was employed to synthesis Nb2O5 (niobium pentoxide) nanoparticles and the effects of synthesis conditions on the physical-chemical properties were evaluated. The catalytic activity of the prepared samples in the liquid phase oxidation of aniline with aqueous hydrogen peroxide as oxidizing agent was also studied. The nanoparticles showed hexagonal structure and rounded shape covered by nanoneedles. The results evidenced high catalytic activity with total conversion of aniline at ambient condition. Aniline conversion and product selectivities depended on the experimental parameters, particularly the oxidizing agent concentration, the nature of the solvent, type of the catalyst and reaction time.2018-03-13T15:25:31Z2018-03-13T15:25:31Z2017info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfVENTURA, W. M. et al. Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles. Catalysis Communications, v. 99, p. 135-140, ago. 2017. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1566736717302352>. Acesso em: 15 set. 2017.1566-7367http://www.repositorio.ufop.br/handle/123456789/9611https://doi.org/10.1016/j.catcom.2017.06.004O periódico Catalysis Communications concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 4210801160834.info:eu-repo/semantics/openAccessVentura, Wellington MartinsBatalha, Daniel CarreiraFajardo, Humberto VieiraTaylor, Jason GuyMarins, Natália HadlerNoremberg, Bruno S.Tański, TomaszCarreño, Neftalí Lenin Villarrealengreponame:Repositório Institucional da UFOPinstname:Universidade Federal de Ouro Preto (UFOP)instacron:UFOP2020-03-16T12:51:05Zoai:repositorio.ufop.br:123456789/9611Repositório InstitucionalPUBhttp://www.repositorio.ufop.br/oai/requestrepositorio@ufop.edu.bropendoar:32332020-03-16T12:51:05Repositório Institucional da UFOP - Universidade Federal de Ouro Preto (UFOP)false |
dc.title.none.fl_str_mv |
Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles. |
title |
Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles. |
spellingShingle |
Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles. Ventura, Wellington Martins Niobium pentoxide Hydrogen peroxide Aniline Oxidation |
title_short |
Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles. |
title_full |
Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles. |
title_fullStr |
Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles. |
title_full_unstemmed |
Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles. |
title_sort |
Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles. |
author |
Ventura, Wellington Martins |
author_facet |
Ventura, Wellington Martins Batalha, Daniel Carreira Fajardo, Humberto Vieira Taylor, Jason Guy Marins, Natália Hadler Noremberg, Bruno S. Tański, Tomasz Carreño, Neftalí Lenin Villarreal |
author_role |
author |
author2 |
Batalha, Daniel Carreira Fajardo, Humberto Vieira Taylor, Jason Guy Marins, Natália Hadler Noremberg, Bruno S. Tański, Tomasz Carreño, Neftalí Lenin Villarreal |
author2_role |
author author author author author author author |
dc.contributor.author.fl_str_mv |
Ventura, Wellington Martins Batalha, Daniel Carreira Fajardo, Humberto Vieira Taylor, Jason Guy Marins, Natália Hadler Noremberg, Bruno S. Tański, Tomasz Carreño, Neftalí Lenin Villarreal |
dc.subject.por.fl_str_mv |
Niobium pentoxide Hydrogen peroxide Aniline Oxidation |
topic |
Niobium pentoxide Hydrogen peroxide Aniline Oxidation |
description |
A microwave-assisted hydrothermal method was employed to synthesis Nb2O5 (niobium pentoxide) nanoparticles and the effects of synthesis conditions on the physical-chemical properties were evaluated. The catalytic activity of the prepared samples in the liquid phase oxidation of aniline with aqueous hydrogen peroxide as oxidizing agent was also studied. The nanoparticles showed hexagonal structure and rounded shape covered by nanoneedles. The results evidenced high catalytic activity with total conversion of aniline at ambient condition. Aniline conversion and product selectivities depended on the experimental parameters, particularly the oxidizing agent concentration, the nature of the solvent, type of the catalyst and reaction time. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017 2018-03-13T15:25:31Z 2018-03-13T15:25:31Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
VENTURA, W. M. et al. Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles. Catalysis Communications, v. 99, p. 135-140, ago. 2017. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1566736717302352>. Acesso em: 15 set. 2017. 1566-7367 http://www.repositorio.ufop.br/handle/123456789/9611 https://doi.org/10.1016/j.catcom.2017.06.004 |
identifier_str_mv |
VENTURA, W. M. et al. Low temperature liquid phase catalytic oxidation of aniline promoted by niobium pentoxide micro and nanoparticles. Catalysis Communications, v. 99, p. 135-140, ago. 2017. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1566736717302352>. Acesso em: 15 set. 2017. 1566-7367 |
url |
http://www.repositorio.ufop.br/handle/123456789/9611 https://doi.org/10.1016/j.catcom.2017.06.004 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFOP instname:Universidade Federal de Ouro Preto (UFOP) instacron:UFOP |
instname_str |
Universidade Federal de Ouro Preto (UFOP) |
instacron_str |
UFOP |
institution |
UFOP |
reponame_str |
Repositório Institucional da UFOP |
collection |
Repositório Institucional da UFOP |
repository.name.fl_str_mv |
Repositório Institucional da UFOP - Universidade Federal de Ouro Preto (UFOP) |
repository.mail.fl_str_mv |
repositorio@ufop.edu.br |
_version_ |
1813002811774861312 |