Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I)

Detalhes bibliográficos
Autor(a) principal: ZAMIAN, José Roberto
Data de Publicação: 2000
Outros Autores: MAURO, Antônio Eduardo, NUNES, Carolina Coimbra, ALMEIDA, Eduardo Tonon de
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFPA
Texto Completo: http://repositorio.ufpa.br/jspui/handle/2011/4423
Resumo: Foram preparados compostos carbonílicos heterobimetálicos do tipo [Fe(CO)4(HgX)2] ( X= Cl, Br, I), contendo ligação metal-metal, objetivando investigar suas estabilidades térmicas em função do halogênio coordenado aos átomos de mercúrio. A caracterização destes complexos foi feita usando-se de técnicas espectroscópicas de infravermelho e ressonância magnética nuclear, além de análise elementar. O produto final das termodecomposições foi identificado através de espectroscopia no infravermelho e difratograma de raios-X, método de pó.
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spelling 2013-11-08T14:50:33Z2013-11-08T14:50:33Z2000ZAMIAN, José Roberto, et al. Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I). Eclética Química, São Paulo, v. 25, p. 89-95, 2000. Disponível em: <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702000000100008&lng=pt&nrm=iso>. Acesso em: 30 out. 2013. <http://dx.doi.org/10.1590/S0100-46702000000100008>.0100-4670http://repositorio.ufpa.br/jspui/handle/2011/4423Foram preparados compostos carbonílicos heterobimetálicos do tipo [Fe(CO)4(HgX)2] ( X= Cl, Br, I), contendo ligação metal-metal, objetivando investigar suas estabilidades térmicas em função do halogênio coordenado aos átomos de mercúrio. A caracterização destes complexos foi feita usando-se de técnicas espectroscópicas de infravermelho e ressonância magnética nuclear, além de análise elementar. O produto final das termodecomposições foi identificado através de espectroscopia no infravermelho e difratograma de raios-X, método de pó.Heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X= Cl, Br, I), which have metal-metal bonds, have been prepared in order to study their thermal stabilities as a function of the halogen coordinated to mercury atoms. The characterization of the above complexes was carried out by elemental analysis, IR and NMR spectroscopies. Their thermal behaviour has been investigated and the final product was identified by IR spectroscopy and by X-ray powder diffractogram.engAnálise térmicaEspectroscopiaFerroMercúrioHalogênioCarbonil-metaisThermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I)info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleZAMIAN, José RobertoMAURO, Antônio EduardoNUNES, Carolina CoimbraALMEIDA, Eduardo Tonon deinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFPAinstname:Universidade Federal do Pará (UFPA)instacron:UFPAORIGINALArtigo_ThermalDecompositionStability.pdfArtigo_ThermalDecompositionStability.pdfapplication/pdf283833http://repositorio.ufpa.br/oai/bitstream/2011/4423/1/Artigo_ThermalDecompositionStability.pdf7afae33c523f7faef75e208902ddbf6eMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81774http://repositorio.ufpa.br/oai/bitstream/2011/4423/2/license.txtf0aa1a71c97d9c3e771021efac6d65e7MD52CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-822974http://repositorio.ufpa.br/oai/bitstream/2011/4423/3/license_rdf99c771d9f0b9c46790009b9874d49253MD53license_textlicense_texttext/html; charset=utf-80http://repositorio.ufpa.br/oai/bitstream/2011/4423/4/license_textd41d8cd98f00b204e9800998ecf8427eMD54license_urllicense_urltext/plain; charset=utf-852http://repositorio.ufpa.br/oai/bitstream/2011/4423/5/license_url3d480ae6c91e310daba2020f8787d6f9MD55TEXTArtigo_ThermalDecompositionStability.pdf.txtArtigo_ThermalDecompositionStability.pdf.txtExtracted texttext/plain12092http://repositorio.ufpa.br/oai/bitstream/2011/4423/6/Artigo_ThermalDecompositionStability.pdf.txt8c46dfdc1ab0820f466a68f58dbc6d03MD562011/44232018-01-10 12:35:36.963oai:repositorio.ufpa.br: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Repositório InstitucionalPUBhttp://repositorio.ufpa.br/oai/requestriufpabc@ufpa.bropendoar:21232018-01-10T15:35:36Repositório Institucional da UFPA - Universidade Federal do Pará (UFPA)false
dc.title.pt_BR.fl_str_mv Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I)
title Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I)
spellingShingle Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I)
ZAMIAN, José Roberto
Análise térmica
Espectroscopia
Ferro
Mercúrio
Halogênio
Carbonil-metais
title_short Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I)
title_full Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I)
title_fullStr Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I)
title_full_unstemmed Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I)
title_sort Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I)
author ZAMIAN, José Roberto
author_facet ZAMIAN, José Roberto
MAURO, Antônio Eduardo
NUNES, Carolina Coimbra
ALMEIDA, Eduardo Tonon de
author_role author
author2 MAURO, Antônio Eduardo
NUNES, Carolina Coimbra
ALMEIDA, Eduardo Tonon de
author2_role author
author
author
dc.contributor.author.fl_str_mv ZAMIAN, José Roberto
MAURO, Antônio Eduardo
NUNES, Carolina Coimbra
ALMEIDA, Eduardo Tonon de
dc.subject.por.fl_str_mv Análise térmica
Espectroscopia
Ferro
Mercúrio
Halogênio
Carbonil-metais
topic Análise térmica
Espectroscopia
Ferro
Mercúrio
Halogênio
Carbonil-metais
description Foram preparados compostos carbonílicos heterobimetálicos do tipo [Fe(CO)4(HgX)2] ( X= Cl, Br, I), contendo ligação metal-metal, objetivando investigar suas estabilidades térmicas em função do halogênio coordenado aos átomos de mercúrio. A caracterização destes complexos foi feita usando-se de técnicas espectroscópicas de infravermelho e ressonância magnética nuclear, além de análise elementar. O produto final das termodecomposições foi identificado através de espectroscopia no infravermelho e difratograma de raios-X, método de pó.
publishDate 2000
dc.date.issued.fl_str_mv 2000
dc.date.accessioned.fl_str_mv 2013-11-08T14:50:33Z
dc.date.available.fl_str_mv 2013-11-08T14:50:33Z
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dc.identifier.citation.fl_str_mv ZAMIAN, José Roberto, et al. Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I). Eclética Química, São Paulo, v. 25, p. 89-95, 2000. Disponível em: <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702000000100008&lng=pt&nrm=iso>. Acesso em: 30 out. 2013. <http://dx.doi.org/10.1590/S0100-46702000000100008>.
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identifier_str_mv ZAMIAN, José Roberto, et al. Thermal decomposition and stability in a series of heterobimetallic carbonyl compounds of the type [Fe(CO)4(HgX)2] (X=Cl, Br, I). Eclética Química, São Paulo, v. 25, p. 89-95, 2000. Disponível em: <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702000000100008&lng=pt&nrm=iso>. Acesso em: 30 out. 2013. <http://dx.doi.org/10.1590/S0100-46702000000100008>.
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