Corrosion resistance of hybrid films applied on tin plate : precursor solution acidified with nitric acid (pH=3)

Detalhes bibliográficos
Autor(a) principal: Kunst, Sandra Raquel
Data de Publicação: 2014
Outros Autores: Ludwig, Gustavo Alberto, Ortega Vega, Maria Rita, Oliveira, Cláudia Trindade, Malfatti, Célia de Fraga
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRGS
Texto Completo: http://hdl.handle.net/10183/259381
Resumo: Siloxane - poly (methylmethacrylate)-based materials are systems formed by a silicon network, to which chains of poly (methylmethacrylate) are linked by covalent bonds or by physical interactions. Their stability and adherence allow their application on substrates like tin plate in order to increase the corrosion resistance. The aim of this work is to coat tin plate with a hybrid film obtained from a sol consisting of alkoxide precursors: 3 - (trimethoxysilylpropyl) methacrylate (TMSM) and poly (methyl methacrylate) PMMA. Effect of tetraethoxysilane (TEOS) addition was evaluated. Morphology was evaluated by SEM and contact angle. Electrochemical behavior was evaluated by open circuit potential (OCP), potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Results showed that siloxane-PMMA film obtained with a higher addition of TEOS had higher thickness. However, intense densification caused by TEOS addition promoted crack formation, thereby compromising the corrosion resistance.
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spelling Kunst, Sandra RaquelLudwig, Gustavo AlbertoOrtega Vega, Maria RitaOliveira, Cláudia TrindadeMalfatti, Célia de Fraga2023-06-24T03:37:03Z20140012-7353http://hdl.handle.net/10183/259381000952309Siloxane - poly (methylmethacrylate)-based materials are systems formed by a silicon network, to which chains of poly (methylmethacrylate) are linked by covalent bonds or by physical interactions. Their stability and adherence allow their application on substrates like tin plate in order to increase the corrosion resistance. The aim of this work is to coat tin plate with a hybrid film obtained from a sol consisting of alkoxide precursors: 3 - (trimethoxysilylpropyl) methacrylate (TMSM) and poly (methyl methacrylate) PMMA. Effect of tetraethoxysilane (TEOS) addition was evaluated. Morphology was evaluated by SEM and contact angle. Electrochemical behavior was evaluated by open circuit potential (OCP), potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Results showed that siloxane-PMMA film obtained with a higher addition of TEOS had higher thickness. However, intense densification caused by TEOS addition promoted crack formation, thereby compromising the corrosion resistance.Los materiales híbridos a base de siloxano y PMMA se constituyen por una red de silicona, a la que están enlazadas cadenas de polimetilmetacrilato. Su estabilidad y adherencia permiten su aplicación en láminas de estaño para aumentar la resistencia a la corrosión. En este trabajo se recubrió una lámina de estaño con una película híbrida a partir de un sol que consta de los precursores alcóxidos: 3-trimetoxisililpropilmetacrilato (TMSM) y polimetilmetacrilado (PMMA). Se evaluó la influencia de la adición de tetraetoxisilano (TEOS). Se evaluó la morfología de los filmes por SEM y ángulo de contacto. Se evaluó el comportamiento electroquímico con medidas de potencial a circuito abierto, polarización potenciodinámica e impedancia electroquímica. Los resultados muestran que la película con mayor adición de TEOS tuvo mayor espesor; sin embargo, el TEOS intensificó la densificación. Así, se formaron grietas que comprometieron la resistencia a la corrosión.application/pdfengDyna : revista de la Facultad de Minas. Vol. 81, no. 188 (dic. 2014), p. 11-19Filmes híbridosFolha de flandresÁcido nítricoResistência à corrosãoHybrid filmsNitric acidTin platepH=3TEOSCorrosionPelículas híbridasLáminas de estañoTEOS corrosiónCorrosion resistance of hybrid films applied on tin plate : precursor solution acidified with nitric acid (pH=3)Resistencia a la corrosión de películas híbridas sobre láminas de estaño : solución precursora acidificada con ácido nítrico (pH=3)Estrangeiroinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFRGSinstname:Universidade Federal do Rio Grande do Sul (UFRGS)instacron:UFRGSTEXT000952309.pdf.txt000952309.pdf.txtExtracted Texttext/plain36191http://www.lume.ufrgs.br/bitstream/10183/259381/2/000952309.pdf.txtf860385dacd3ecaf87b1e2ce63db836fMD52ORIGINAL000952309.pdfTexto completo (inglês)application/pdf1790090http://www.lume.ufrgs.br/bitstream/10183/259381/1/000952309.pdfce5ba8098e13cdc9b79d29ae78fe746cMD5110183/2593812024-01-10 04:36:11.18258oai:www.lume.ufrgs.br:10183/259381Repositório de PublicaçõesPUBhttps://lume.ufrgs.br/oai/requestopendoar:2024-01-10T06:36:11Repositório Institucional da UFRGS - Universidade Federal do Rio Grande do Sul (UFRGS)false
dc.title.pt_BR.fl_str_mv Corrosion resistance of hybrid films applied on tin plate : precursor solution acidified with nitric acid (pH=3)
dc.title.alternative.es.fl_str_mv Resistencia a la corrosión de películas híbridas sobre láminas de estaño : solución precursora acidificada con ácido nítrico (pH=3)
title Corrosion resistance of hybrid films applied on tin plate : precursor solution acidified with nitric acid (pH=3)
spellingShingle Corrosion resistance of hybrid films applied on tin plate : precursor solution acidified with nitric acid (pH=3)
Kunst, Sandra Raquel
Filmes híbridos
Folha de flandres
Ácido nítrico
Resistência à corrosão
Hybrid films
Nitric acid
Tin plate
pH=3
TEOS
Corrosion
Películas híbridas
Láminas de estaño
TEOS corrosión
title_short Corrosion resistance of hybrid films applied on tin plate : precursor solution acidified with nitric acid (pH=3)
title_full Corrosion resistance of hybrid films applied on tin plate : precursor solution acidified with nitric acid (pH=3)
title_fullStr Corrosion resistance of hybrid films applied on tin plate : precursor solution acidified with nitric acid (pH=3)
title_full_unstemmed Corrosion resistance of hybrid films applied on tin plate : precursor solution acidified with nitric acid (pH=3)
title_sort Corrosion resistance of hybrid films applied on tin plate : precursor solution acidified with nitric acid (pH=3)
author Kunst, Sandra Raquel
author_facet Kunst, Sandra Raquel
Ludwig, Gustavo Alberto
Ortega Vega, Maria Rita
Oliveira, Cláudia Trindade
Malfatti, Célia de Fraga
author_role author
author2 Ludwig, Gustavo Alberto
Ortega Vega, Maria Rita
Oliveira, Cláudia Trindade
Malfatti, Célia de Fraga
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Kunst, Sandra Raquel
Ludwig, Gustavo Alberto
Ortega Vega, Maria Rita
Oliveira, Cláudia Trindade
Malfatti, Célia de Fraga
dc.subject.por.fl_str_mv Filmes híbridos
Folha de flandres
Ácido nítrico
Resistência à corrosão
topic Filmes híbridos
Folha de flandres
Ácido nítrico
Resistência à corrosão
Hybrid films
Nitric acid
Tin plate
pH=3
TEOS
Corrosion
Películas híbridas
Láminas de estaño
TEOS corrosión
dc.subject.eng.fl_str_mv Hybrid films
Nitric acid
Tin plate
pH=3
TEOS
Corrosion
dc.subject.spa.fl_str_mv Películas híbridas
Láminas de estaño
TEOS corrosión
description Siloxane - poly (methylmethacrylate)-based materials are systems formed by a silicon network, to which chains of poly (methylmethacrylate) are linked by covalent bonds or by physical interactions. Their stability and adherence allow their application on substrates like tin plate in order to increase the corrosion resistance. The aim of this work is to coat tin plate with a hybrid film obtained from a sol consisting of alkoxide precursors: 3 - (trimethoxysilylpropyl) methacrylate (TMSM) and poly (methyl methacrylate) PMMA. Effect of tetraethoxysilane (TEOS) addition was evaluated. Morphology was evaluated by SEM and contact angle. Electrochemical behavior was evaluated by open circuit potential (OCP), potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Results showed that siloxane-PMMA film obtained with a higher addition of TEOS had higher thickness. However, intense densification caused by TEOS addition promoted crack formation, thereby compromising the corrosion resistance.
publishDate 2014
dc.date.issued.fl_str_mv 2014
dc.date.accessioned.fl_str_mv 2023-06-24T03:37:03Z
dc.type.driver.fl_str_mv Estrangeiro
info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10183/259381
dc.identifier.issn.pt_BR.fl_str_mv 0012-7353
dc.identifier.nrb.pt_BR.fl_str_mv 000952309
identifier_str_mv 0012-7353
000952309
url http://hdl.handle.net/10183/259381
dc.language.iso.fl_str_mv eng
language eng
dc.relation.ispartof.pt_BR.fl_str_mv Dyna : revista de la Facultad de Minas. Vol. 81, no. 188 (dic. 2014), p. 11-19
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFRGS
instname:Universidade Federal do Rio Grande do Sul (UFRGS)
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instname_str Universidade Federal do Rio Grande do Sul (UFRGS)
instacron_str UFRGS
institution UFRGS
reponame_str Repositório Institucional da UFRGS
collection Repositório Institucional da UFRGS
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