Ions at the air-water interface : an end to a hundred-year-old mystery?
Autor(a) principal: | |
---|---|
Data de Publicação: | 2009 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRGS |
Texto Completo: | http://hdl.handle.net/10183/100098 |
Resumo: | Availability of highly reactive halogen ions at the surface of aerosols has tremendous implications for the atmospheric chemistry. Yet neither simulations, experiments, nor existing theories are able to provide a fully consistent description of the electrolyte-air interface. In this Letter a new theory is proposed which allows us to explicitly calculate the ionic density profiles, the surface tension, and the electrostatic potential difference across the solution-air interface. Predictions of the theory are compared to experiments and are found to be in excellent agreement. The theory also sheds new light on one of the oldest puzzles of physical chemistry—the Hofmeister effect. |
id |
UFRGS-2_a03e0787bf8b849dae44ddc61f93a626 |
---|---|
oai_identifier_str |
oai:www.lume.ufrgs.br:10183/100098 |
network_acronym_str |
UFRGS-2 |
network_name_str |
Repositório Institucional da UFRGS |
repository_id_str |
|
spelling |
Levin, YanSantos, Alexandre Pereira dosDiehl, Alexandre2014-08-12T02:10:31Z20090031-9007http://hdl.handle.net/10183/100098000731424Availability of highly reactive halogen ions at the surface of aerosols has tremendous implications for the atmospheric chemistry. Yet neither simulations, experiments, nor existing theories are able to provide a fully consistent description of the electrolyte-air interface. In this Letter a new theory is proposed which allows us to explicitly calculate the ionic density profiles, the surface tension, and the electrostatic potential difference across the solution-air interface. Predictions of the theory are compared to experiments and are found to be in excellent agreement. The theory also sheds new light on one of the oldest puzzles of physical chemistry—the Hofmeister effect.application/pdfengPhysical review letters. Melville. Vol. 103, no. 25 (Dec. 2009), 257802, 4 p.Física da matéria condensadaEstrutura líqüidaEletrostáticaEletrólitosInterface ar-águaTensão superficialIons at the air-water interface : an end to a hundred-year-old mystery?Estrangeiroinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFRGSinstname:Universidade Federal do Rio Grande do Sul (UFRGS)instacron:UFRGSORIGINAL000731424.pdf000731424.pdfTexto completo (inglês)application/pdf181869http://www.lume.ufrgs.br/bitstream/10183/100098/1/000731424.pdf0cbb0025659b1c1726f8cb5b68b38fffMD51TEXT000731424.pdf.txt000731424.pdf.txtExtracted Texttext/plain21842http://www.lume.ufrgs.br/bitstream/10183/100098/2/000731424.pdf.txt025016635f6eef26671e638e18b37199MD5210183/1000982023-06-14 03:30:19.035334oai:www.lume.ufrgs.br:10183/100098Repositório de PublicaçõesPUBhttps://lume.ufrgs.br/oai/requestopendoar:2023-06-14T06:30:19Repositório Institucional da UFRGS - Universidade Federal do Rio Grande do Sul (UFRGS)false |
dc.title.pt_BR.fl_str_mv |
Ions at the air-water interface : an end to a hundred-year-old mystery? |
title |
Ions at the air-water interface : an end to a hundred-year-old mystery? |
spellingShingle |
Ions at the air-water interface : an end to a hundred-year-old mystery? Levin, Yan Física da matéria condensada Estrutura líqüida Eletrostática Eletrólitos Interface ar-água Tensão superficial |
title_short |
Ions at the air-water interface : an end to a hundred-year-old mystery? |
title_full |
Ions at the air-water interface : an end to a hundred-year-old mystery? |
title_fullStr |
Ions at the air-water interface : an end to a hundred-year-old mystery? |
title_full_unstemmed |
Ions at the air-water interface : an end to a hundred-year-old mystery? |
title_sort |
Ions at the air-water interface : an end to a hundred-year-old mystery? |
author |
Levin, Yan |
author_facet |
Levin, Yan Santos, Alexandre Pereira dos Diehl, Alexandre |
author_role |
author |
author2 |
Santos, Alexandre Pereira dos Diehl, Alexandre |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Levin, Yan Santos, Alexandre Pereira dos Diehl, Alexandre |
dc.subject.por.fl_str_mv |
Física da matéria condensada Estrutura líqüida Eletrostática Eletrólitos Interface ar-água Tensão superficial |
topic |
Física da matéria condensada Estrutura líqüida Eletrostática Eletrólitos Interface ar-água Tensão superficial |
description |
Availability of highly reactive halogen ions at the surface of aerosols has tremendous implications for the atmospheric chemistry. Yet neither simulations, experiments, nor existing theories are able to provide a fully consistent description of the electrolyte-air interface. In this Letter a new theory is proposed which allows us to explicitly calculate the ionic density profiles, the surface tension, and the electrostatic potential difference across the solution-air interface. Predictions of the theory are compared to experiments and are found to be in excellent agreement. The theory also sheds new light on one of the oldest puzzles of physical chemistry—the Hofmeister effect. |
publishDate |
2009 |
dc.date.issued.fl_str_mv |
2009 |
dc.date.accessioned.fl_str_mv |
2014-08-12T02:10:31Z |
dc.type.driver.fl_str_mv |
Estrangeiro info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10183/100098 |
dc.identifier.issn.pt_BR.fl_str_mv |
0031-9007 |
dc.identifier.nrb.pt_BR.fl_str_mv |
000731424 |
identifier_str_mv |
0031-9007 000731424 |
url |
http://hdl.handle.net/10183/100098 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartof.pt_BR.fl_str_mv |
Physical review letters. Melville. Vol. 103, no. 25 (Dec. 2009), 257802, 4 p. |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFRGS instname:Universidade Federal do Rio Grande do Sul (UFRGS) instacron:UFRGS |
instname_str |
Universidade Federal do Rio Grande do Sul (UFRGS) |
instacron_str |
UFRGS |
institution |
UFRGS |
reponame_str |
Repositório Institucional da UFRGS |
collection |
Repositório Institucional da UFRGS |
bitstream.url.fl_str_mv |
http://www.lume.ufrgs.br/bitstream/10183/100098/1/000731424.pdf http://www.lume.ufrgs.br/bitstream/10183/100098/2/000731424.pdf.txt |
bitstream.checksum.fl_str_mv |
0cbb0025659b1c1726f8cb5b68b38fff 025016635f6eef26671e638e18b37199 |
bitstream.checksumAlgorithm.fl_str_mv |
MD5 MD5 |
repository.name.fl_str_mv |
Repositório Institucional da UFRGS - Universidade Federal do Rio Grande do Sul (UFRGS) |
repository.mail.fl_str_mv |
|
_version_ |
1798487252703117312 |