Crystal structure of (4R,5S)-4-methyl-3-methylsulfinyl-5-phenyl-1,3-oxazolidin-2-one

Detalhes bibliográficos
Autor(a) principal: Silveira, Gustavo Pozza
Data de Publicação: 2014
Outros Autores: Silva, Vinícius Flores da, Oliver, Allen G.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRGS
Texto Completo: http://hdl.handle.net/10183/109529
Resumo: The absolute structure of the chiral asymmetric indole precursor title compound, C11H13NO3S, was confirmed by refinement of the Flack and Hooft parameters and is that expected based on the starting materials for the synthesis. The phenyl group subtends a dihedral angle of 56.40 (5) with the mean plane of the oxazolidinone ring, which adopts an envelope conformation, with the C atom bearing the methyl group as the flap. In the crystal, no significant directional interactions beyond van der Waals contacts are observed.
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spelling Silveira, Gustavo PozzaSilva, Vinícius Flores daOliver, Allen G.2015-01-31T02:19:49Z20141600-5368http://hdl.handle.net/10183/109529000949073The absolute structure of the chiral asymmetric indole precursor title compound, C11H13NO3S, was confirmed by refinement of the Flack and Hooft parameters and is that expected based on the starting materials for the synthesis. The phenyl group subtends a dihedral angle of 56.40 (5) with the mean plane of the oxazolidinone ring, which adopts an envelope conformation, with the C atom bearing the methyl group as the flap. In the crystal, no significant directional interactions beyond van der Waals contacts are observed.application/pdfengActa Crystallographica Section E: Crystallographic Communications. Chester, UK. Vol. E70, pt. 12 (Dec. 2014), p. o1257-o1258OxazolidinonasEstrutura cristalinaCrystal structureOxazolidinoneAsymmetric indoleCrystal structure of (4R,5S)-4-methyl-3-methylsulfinyl-5-phenyl-1,3-oxazolidin-2-oneEstrangeiroinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFRGSinstname:Universidade Federal do Rio Grande do Sul (UFRGS)instacron:UFRGSORIGINAL000949073.pdf000949073.pdfTexto completo (inglês)application/pdf197228http://www.lume.ufrgs.br/bitstream/10183/109529/1/000949073.pdf92bd085c0f7e246a5103597a77a02df8MD51TEXT000949073.pdf.txt000949073.pdf.txtExtracted Texttext/plain15858http://www.lume.ufrgs.br/bitstream/10183/109529/2/000949073.pdf.txtf37e901eeb446790af55cf4ced030c15MD52THUMBNAIL000949073.pdf.jpg000949073.pdf.jpgGenerated Thumbnailimage/jpeg1935http://www.lume.ufrgs.br/bitstream/10183/109529/3/000949073.pdf.jpg683bfbcda54382dc8240d3843a83b48aMD5310183/1095292018-10-23 09:00:32.962oai:www.lume.ufrgs.br:10183/109529Repositório de PublicaçõesPUBhttps://lume.ufrgs.br/oai/requestopendoar:2018-10-23T12:00:32Repositório Institucional da UFRGS - Universidade Federal do Rio Grande do Sul (UFRGS)false
dc.title.pt_BR.fl_str_mv Crystal structure of (4R,5S)-4-methyl-3-methylsulfinyl-5-phenyl-1,3-oxazolidin-2-one
title Crystal structure of (4R,5S)-4-methyl-3-methylsulfinyl-5-phenyl-1,3-oxazolidin-2-one
spellingShingle Crystal structure of (4R,5S)-4-methyl-3-methylsulfinyl-5-phenyl-1,3-oxazolidin-2-one
Silveira, Gustavo Pozza
Oxazolidinonas
Estrutura cristalina
Crystal structure
Oxazolidinone
Asymmetric indole
title_short Crystal structure of (4R,5S)-4-methyl-3-methylsulfinyl-5-phenyl-1,3-oxazolidin-2-one
title_full Crystal structure of (4R,5S)-4-methyl-3-methylsulfinyl-5-phenyl-1,3-oxazolidin-2-one
title_fullStr Crystal structure of (4R,5S)-4-methyl-3-methylsulfinyl-5-phenyl-1,3-oxazolidin-2-one
title_full_unstemmed Crystal structure of (4R,5S)-4-methyl-3-methylsulfinyl-5-phenyl-1,3-oxazolidin-2-one
title_sort Crystal structure of (4R,5S)-4-methyl-3-methylsulfinyl-5-phenyl-1,3-oxazolidin-2-one
author Silveira, Gustavo Pozza
author_facet Silveira, Gustavo Pozza
Silva, Vinícius Flores da
Oliver, Allen G.
author_role author
author2 Silva, Vinícius Flores da
Oliver, Allen G.
author2_role author
author
dc.contributor.author.fl_str_mv Silveira, Gustavo Pozza
Silva, Vinícius Flores da
Oliver, Allen G.
dc.subject.por.fl_str_mv Oxazolidinonas
Estrutura cristalina
topic Oxazolidinonas
Estrutura cristalina
Crystal structure
Oxazolidinone
Asymmetric indole
dc.subject.eng.fl_str_mv Crystal structure
Oxazolidinone
Asymmetric indole
description The absolute structure of the chiral asymmetric indole precursor title compound, C11H13NO3S, was confirmed by refinement of the Flack and Hooft parameters and is that expected based on the starting materials for the synthesis. The phenyl group subtends a dihedral angle of 56.40 (5) with the mean plane of the oxazolidinone ring, which adopts an envelope conformation, with the C atom bearing the methyl group as the flap. In the crystal, no significant directional interactions beyond van der Waals contacts are observed.
publishDate 2014
dc.date.issued.fl_str_mv 2014
dc.date.accessioned.fl_str_mv 2015-01-31T02:19:49Z
dc.type.driver.fl_str_mv Estrangeiro
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dc.identifier.uri.fl_str_mv http://hdl.handle.net/10183/109529
dc.identifier.issn.pt_BR.fl_str_mv 1600-5368
dc.identifier.nrb.pt_BR.fl_str_mv 000949073
identifier_str_mv 1600-5368
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url http://hdl.handle.net/10183/109529
dc.language.iso.fl_str_mv eng
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dc.relation.ispartof.pt_BR.fl_str_mv Acta Crystallographica Section E: Crystallographic Communications. Chester, UK. Vol. E70, pt. 12 (Dec. 2014), p. o1257-o1258
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