Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite

Detalhes bibliográficos
Autor(a) principal: Tavman, Ismail Hakki
Data de Publicação: 2012
Outros Autores: Turgut, Alpaslan, Fonseca, Henrique Massard da, Orlande, Helcio Rangel Barreto, Cotta, Renato Machado, Magalhães, Maycon Cesar Figueira
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRJ
Texto Completo: http://hdl.handle.net/11422/8546
Resumo: Indisponível.
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spelling Tavman, Ismail HakkiTurgut, AlpaslanFonseca, Henrique Massard daOrlande, Helcio Rangel BarretoCotta, Renato MachadoMagalhães, Maycon Cesar Figueira2019-06-28T13:23:42Z2023-11-30T03:03:32Z2012-06-240195-928Xhttp://hdl.handle.net/11422/854610.1007/s10765-012-1231-zIndisponível.In this research, the thermal diffusivity of composites based on ethylene- vinyl acetate (EVA) copolymer filled with two kinds of reinforcement graphite materials was investigated. The reinforcement graphite fillers were untreated natural graphite (UG) and expanded graphite (EG). Composite samples up to 29.3 % graphite particle volumetric concentrations (50 % mass concentration) were prepared by the melt- mixing process in a Brabender Plasticorder. Upon mixing, the EG exfoliates in these films having nanosized thicknesses as evidenced by TEM micrographs. Thus, the thermal diffusivity and electrical conductivity of composites based on the ethylene-vinyl acetate matrix filled with nanostructuralized expanded graphite and standard, micro-sized graphite were investigated. From the experimental results it was deduced that the electrical conductivity was not only a function of filler concentration, but also strongly dependent on the graphite structure. The percolation concentration of the filler was found to be (15 to 17) vol% for micro-sized natural graphite, whereas the percolation concentration of the filler in nanocomposites filled with expanded graphite was much lower, about (5 to 6) vol%. The electrical conductivity of nanocomposites was also much higher than the electrical conductivity of composites filled with micro-sized filler at similar concentrations. Similarly, the values of the thermal diffusivity for the nanocomposites, EG-filled EVA, were significantly higher than the thermal diffusivity of the composites filled with micro-sized filler, UG-filled EVA, at similar concentrations. For 29.3 % graphite particle volumetric concentrations, the thermal diffusivity was 8.23 × 10−7 m2 · s−1 for EG-filled EVA and 6.14 × 10−7 m2 · s−1 for UG-filled EVA. The thermal diffusivity was measured by the flash method.Submitted by Jairo Amaro (jairo.amaro@sibi.ufrj.br) on 2019-06-28T13:23:42Z No. of bitstreams: 1 2012_COTTA_IJT_v33_p1-10-min.pdf: 268917 bytes, checksum: 99cd157df3011793fb3240e9444f53f9 (MD5)Made available in DSpace on 2019-06-28T13:23:42Z (GMT). No. of bitstreams: 1 2012_COTTA_IJT_v33_p1-10-min.pdf: 268917 bytes, checksum: 99cd157df3011793fb3240e9444f53f9 (MD5) Previous issue date: 2012-06-24engSpringer VerlagBrasilNúcleo Interdisciplinar de Dinâmica dos FluidosInternational Journal of ThermophysicsCNPQ::CIENCIAS EXATAS E DA TERRA::FISICA::AREAS CLASSICAS DE FENOMENOLOGIA E SUAS APLICACOES::DINAMICA DOS FLUIDOSConductive nanocompositesElectrical conductivityEVAExpanded graphiteUnexpanded graphiteFlash methodThermal diffusivityThermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphiteinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article341222972306365 diasinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFRJinstname:Universidade Federal do Rio de Janeiro (UFRJ)instacron:UFRJORIGINAL2012_COTTA_IJT_v33_p1-10-min.pdf2012_COTTA_IJT_v33_p1-10-min.pdfapplication/pdf268917http://pantheon.ufrj.br:80/bitstream/11422/8546/1/2012_COTTA_IJT_v33_p1-10-min.pdf99cd157df3011793fb3240e9444f53f9MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81853http://pantheon.ufrj.br:80/bitstream/11422/8546/2/license.txtdd32849f2bfb22da963c3aac6e26e255MD5211422/85462023-11-30 00:03:32.996oai:pantheon.ufrj.br:11422/8546TElDRU7Dh0EgTsODTy1FWENMVVNJVkEgREUgRElTVFJJQlVJw4fDg08KCkFvIGFzc2luYXIgZSBlbnRyZWdhciBlc3RhIGxpY2Vuw6dhLCB2b2PDqihzKSBvKHMpIGF1dG9yKGVzKSBvdSBwcm9wcmlldMOhcmlvKHMpIGRvcyBkaXJlaXRvcyBhdXRvcmFpcyBjb25jZWRlKG0pIGFvIFJlcG9zaXTDs3JpbyBQYW50aGVvbiBkYSBVbml2ZXJzaWRhZGUgRmVkZXJhbCBkbyBSaW8gZGUgSmFuZWlybyAoVUZSSikgbyBkaXJlaXRvIG7Do28gLSBleGNsdXNpdm8gZGUgcmVwcm9kdXppciwgY29udmVydGVyIChjb21vIGRlZmluaWRvIGFiYWl4byksIGUvb3UgZGlzdHJpYnVpciBvIGRvY3VtZW50byBlbnRyZWd1ZSAoaW5jbHVpbmRvIG8gcmVzdW1vKSBlbSB0b2RvIG8gbXVuZG8sIGVtIGZvcm1hdG8gZWxldHLDtG5pY28gZSBlbSBxdWFscXVlciBtZWlvLCBpbmNsdWluZG8sIG1hcyBuw6NvIGxpbWl0YWRvIGEgw6F1ZGlvIGUvb3UgdsOtZGVvLgoKVm9jw6ogY29uY29yZGEgcXVlIGEgVUZSSiBwb2RlLCBzZW0gYWx0ZXJhciBvIGNvbnRlw7pkbywgdHJhZHV6aXIgYSBhcHJlc2VudGHDp8OjbyBkZSBxdWFscXVlciBtZWlvIG91IGZvcm1hdG8gY29tIGEgZmluYWxpZGFkZSBkZSBwcmVzZXJ2YcOnw6NvLgoKVm9jw6ogdGFtYsOpbSBjb25jb3JkYSBxdWUgYSBVRlJKIHBvZGUgbWFudGVyIG1haXMgZGUgdW1hIGPDs3BpYSBkZXNzYSBzdWJtaXNzw6NvIHBhcmEgZmlucyBkZSBzZWd1cmFuw6dhLCBiYWNrLXVwIGUgcHJlc2VydmHDp8OjbyBkaWdpdGFsLgoKRGVjbGFyYSBxdWUgbyBkb2N1bWVudG8gZW50cmVndWUgw6kgc2V1IHRyYWJhbGhvIG9yaWdpbmFsLCBlIHF1ZSB2b2PDqiB0ZW0gbyBkaXJlaXRvIGRlIGNvbmNlZGVyIG9zIGRpcmVpdG9zIGNvbnRpZG9zIG5lc3RhIGxpY2Vuw6dhLiBWb2PDqiB0YW1iw6ltIGRlY2xhcmEgcXVlIGEgc3VhIGFwcmVzZW50YcOnw6NvLCBjb20gbyBtZWxob3IgZGUgc2V1cyBjb25oZWNpbWVudG9zLCBuw6NvIGluZnJpbmdpIGRpcmVpdG9zIGF1dG9yYWlzIGRlIHRlcmNlaXJvcy4KClNlIG8gZG9jdW1lbnRvIGVudHJlZ3VlIGNvbnTDqW0gbWF0ZXJpYWwgZG8gcXVhbCB2b2PDqiBuw6NvIHRlbSBkaXJlaXRvcyBkZSBhdXRvciwgZGVjbGFyYSBxdWUgb2J0ZXZlIGEgcGVybWlzc8OjbyBpcnJlc3RyaXRhIGRvIGRldGVudG9yIGRvcyBkaXJlaXRvcyBhdXRvcmFpcyBlIGNvbmNlZGUgYSBVRlJKIG9zIGRpcmVpdG9zIHJlcXVlcmlkb3MgcG9yIGVzdGEgbGljZW7Dp2EsIGUgcXVlIGVzc2UgbWF0ZXJpYWwgZGUgcHJvcHJpZWRhZGUgZGUgdGVyY2Vpcm9zIGVzdMOhIGNsYXJhbWVudGUgaWRlbnRpZmljYWRvIGUgcmVjb25oZWNpZG8gbm8gdGV4dG8gb3UgY29udGXDumRvIGRhIHN1Ym1pc3PDo28uCgpTZSBvIGRvY3VtZW50byBlbnRyZWd1ZSDDqSBiYXNlYWRvIGVtIHRyYWJhbGhvIHF1ZSBmb2ksIG91IHRlbSBzaWRvIHBhdHJvY2luYWRvIG91IGFwb2lhZG8gcG9yIHVtYSBhZ8OqbmNpYSBvdSBvdXRybyhzKSBvcmdhbmlzbW8ocykgcXVlIG7Do28gYSBVRlJKLCB2b2PDqiBkZWNsYXJhIHF1ZSBjdW1wcml1IHF1YWxxdWVyIGRpcmVpdG8gZGUgUkVWSVPDg08gb3UgZGUgb3V0cmFzIG9icmlnYcOnw7VlcyByZXF1ZXJpZGFzIHBvciBjb250cmF0byBvdSBhY29yZG8uCgpBIFVGUkogaXLDoSBpZGVudGlmaWNhciBjbGFyYW1lbnRlIG8ocykgc2V1KHMpIG5vbWUocykgY29tbyBhdXRvcihlcykgb3UgcHJvcHJpZXTDoXJpbyhzKSBkYSBzdWJtaXNzw6NvLCBlIG7Do28gZmFyw6EgcXVhbHF1ZXIgYWx0ZXJhw6fDo28sIHBhcmEgYWzDqW0gZGFzIHBlcm1pdGlkYXMgcG9yIGVzdGEgbGljZW7Dp2EsIG5vIGF0byBkZSBzdWJtaXNzw6NvLgo=Repositório de PublicaçõesPUBhttp://www.pantheon.ufrj.br/oai/requestopendoar:2023-11-30T03:03:32Repositório Institucional da UFRJ - Universidade Federal do Rio de Janeiro (UFRJ)false
dc.title.en.fl_str_mv Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite
title Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite
spellingShingle Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite
Tavman, Ismail Hakki
CNPQ::CIENCIAS EXATAS E DA TERRA::FISICA::AREAS CLASSICAS DE FENOMENOLOGIA E SUAS APLICACOES::DINAMICA DOS FLUIDOS
Conductive nanocomposites
Electrical conductivity
EVA
Expanded graphite
Unexpanded graphite
Flash method
Thermal diffusivity
title_short Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite
title_full Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite
title_fullStr Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite
title_full_unstemmed Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite
title_sort Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite
author Tavman, Ismail Hakki
author_facet Tavman, Ismail Hakki
Turgut, Alpaslan
Fonseca, Henrique Massard da
Orlande, Helcio Rangel Barreto
Cotta, Renato Machado
Magalhães, Maycon Cesar Figueira
author_role author
author2 Turgut, Alpaslan
Fonseca, Henrique Massard da
Orlande, Helcio Rangel Barreto
Cotta, Renato Machado
Magalhães, Maycon Cesar Figueira
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Tavman, Ismail Hakki
Turgut, Alpaslan
Fonseca, Henrique Massard da
Orlande, Helcio Rangel Barreto
Cotta, Renato Machado
Magalhães, Maycon Cesar Figueira
dc.subject.cnpq.fl_str_mv CNPQ::CIENCIAS EXATAS E DA TERRA::FISICA::AREAS CLASSICAS DE FENOMENOLOGIA E SUAS APLICACOES::DINAMICA DOS FLUIDOS
topic CNPQ::CIENCIAS EXATAS E DA TERRA::FISICA::AREAS CLASSICAS DE FENOMENOLOGIA E SUAS APLICACOES::DINAMICA DOS FLUIDOS
Conductive nanocomposites
Electrical conductivity
EVA
Expanded graphite
Unexpanded graphite
Flash method
Thermal diffusivity
dc.subject.eng.fl_str_mv Conductive nanocomposites
Electrical conductivity
EVA
Expanded graphite
Unexpanded graphite
Flash method
Thermal diffusivity
description Indisponível.
publishDate 2012
dc.date.issued.fl_str_mv 2012-06-24
dc.date.accessioned.fl_str_mv 2019-06-28T13:23:42Z
dc.date.available.fl_str_mv 2023-11-30T03:03:32Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/11422/8546
dc.identifier.issn.pt_BR.fl_str_mv 0195-928X
dc.identifier.doi.pt_BR.fl_str_mv 10.1007/s10765-012-1231-z
identifier_str_mv 0195-928X
10.1007/s10765-012-1231-z
url http://hdl.handle.net/11422/8546
dc.language.iso.fl_str_mv eng
language eng
dc.relation.ispartof.en.fl_str_mv International Journal of Thermophysics
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Springer Verlag
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv Núcleo Interdisciplinar de Dinâmica dos Fluidos
publisher.none.fl_str_mv Springer Verlag
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFRJ
instname:Universidade Federal do Rio de Janeiro (UFRJ)
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