Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite
Autor(a) principal: | |
---|---|
Data de Publicação: | 2012 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRJ |
Texto Completo: | http://hdl.handle.net/11422/8546 |
Resumo: | Indisponível. |
id |
UFRJ_90bd0f004784fded9807974a33cbfe83 |
---|---|
oai_identifier_str |
oai:pantheon.ufrj.br:11422/8546 |
network_acronym_str |
UFRJ |
network_name_str |
Repositório Institucional da UFRJ |
repository_id_str |
|
spelling |
Tavman, Ismail HakkiTurgut, AlpaslanFonseca, Henrique Massard daOrlande, Helcio Rangel BarretoCotta, Renato MachadoMagalhães, Maycon Cesar Figueira2019-06-28T13:23:42Z2023-11-30T03:03:32Z2012-06-240195-928Xhttp://hdl.handle.net/11422/854610.1007/s10765-012-1231-zIndisponível.In this research, the thermal diffusivity of composites based on ethylene- vinyl acetate (EVA) copolymer filled with two kinds of reinforcement graphite materials was investigated. The reinforcement graphite fillers were untreated natural graphite (UG) and expanded graphite (EG). Composite samples up to 29.3 % graphite particle volumetric concentrations (50 % mass concentration) were prepared by the melt- mixing process in a Brabender Plasticorder. Upon mixing, the EG exfoliates in these films having nanosized thicknesses as evidenced by TEM micrographs. Thus, the thermal diffusivity and electrical conductivity of composites based on the ethylene-vinyl acetate matrix filled with nanostructuralized expanded graphite and standard, micro-sized graphite were investigated. From the experimental results it was deduced that the electrical conductivity was not only a function of filler concentration, but also strongly dependent on the graphite structure. The percolation concentration of the filler was found to be (15 to 17) vol% for micro-sized natural graphite, whereas the percolation concentration of the filler in nanocomposites filled with expanded graphite was much lower, about (5 to 6) vol%. The electrical conductivity of nanocomposites was also much higher than the electrical conductivity of composites filled with micro-sized filler at similar concentrations. Similarly, the values of the thermal diffusivity for the nanocomposites, EG-filled EVA, were significantly higher than the thermal diffusivity of the composites filled with micro-sized filler, UG-filled EVA, at similar concentrations. For 29.3 % graphite particle volumetric concentrations, the thermal diffusivity was 8.23 × 10−7 m2 · s−1 for EG-filled EVA and 6.14 × 10−7 m2 · s−1 for UG-filled EVA. The thermal diffusivity was measured by the flash method.Submitted by Jairo Amaro (jairo.amaro@sibi.ufrj.br) on 2019-06-28T13:23:42Z No. of bitstreams: 1 2012_COTTA_IJT_v33_p1-10-min.pdf: 268917 bytes, checksum: 99cd157df3011793fb3240e9444f53f9 (MD5)Made available in DSpace on 2019-06-28T13:23:42Z (GMT). No. of bitstreams: 1 2012_COTTA_IJT_v33_p1-10-min.pdf: 268917 bytes, checksum: 99cd157df3011793fb3240e9444f53f9 (MD5) Previous issue date: 2012-06-24engSpringer VerlagBrasilNúcleo Interdisciplinar de Dinâmica dos FluidosInternational Journal of ThermophysicsCNPQ::CIENCIAS EXATAS E DA TERRA::FISICA::AREAS CLASSICAS DE FENOMENOLOGIA E SUAS APLICACOES::DINAMICA DOS FLUIDOSConductive nanocompositesElectrical conductivityEVAExpanded graphiteUnexpanded graphiteFlash methodThermal diffusivityThermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphiteinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article341222972306365 diasinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFRJinstname:Universidade Federal do Rio de Janeiro (UFRJ)instacron:UFRJORIGINAL2012_COTTA_IJT_v33_p1-10-min.pdf2012_COTTA_IJT_v33_p1-10-min.pdfapplication/pdf268917http://pantheon.ufrj.br:80/bitstream/11422/8546/1/2012_COTTA_IJT_v33_p1-10-min.pdf99cd157df3011793fb3240e9444f53f9MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81853http://pantheon.ufrj.br:80/bitstream/11422/8546/2/license.txtdd32849f2bfb22da963c3aac6e26e255MD5211422/85462023-11-30 00:03:32.996oai:pantheon.ufrj.br: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Repositório de PublicaçõesPUBhttp://www.pantheon.ufrj.br/oai/requestopendoar:2023-11-30T03:03:32Repositório Institucional da UFRJ - Universidade Federal do Rio de Janeiro (UFRJ)false |
dc.title.en.fl_str_mv |
Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite |
title |
Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite |
spellingShingle |
Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite Tavman, Ismail Hakki CNPQ::CIENCIAS EXATAS E DA TERRA::FISICA::AREAS CLASSICAS DE FENOMENOLOGIA E SUAS APLICACOES::DINAMICA DOS FLUIDOS Conductive nanocomposites Electrical conductivity EVA Expanded graphite Unexpanded graphite Flash method Thermal diffusivity |
title_short |
Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite |
title_full |
Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite |
title_fullStr |
Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite |
title_full_unstemmed |
Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite |
title_sort |
Thermal-Diffusivity Measurements of Conductive Composites Based on EVA Copolymer Filled With Expanded and Unexpanded Graphite |
author |
Tavman, Ismail Hakki |
author_facet |
Tavman, Ismail Hakki Turgut, Alpaslan Fonseca, Henrique Massard da Orlande, Helcio Rangel Barreto Cotta, Renato Machado Magalhães, Maycon Cesar Figueira |
author_role |
author |
author2 |
Turgut, Alpaslan Fonseca, Henrique Massard da Orlande, Helcio Rangel Barreto Cotta, Renato Machado Magalhães, Maycon Cesar Figueira |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Tavman, Ismail Hakki Turgut, Alpaslan Fonseca, Henrique Massard da Orlande, Helcio Rangel Barreto Cotta, Renato Machado Magalhães, Maycon Cesar Figueira |
dc.subject.cnpq.fl_str_mv |
CNPQ::CIENCIAS EXATAS E DA TERRA::FISICA::AREAS CLASSICAS DE FENOMENOLOGIA E SUAS APLICACOES::DINAMICA DOS FLUIDOS |
topic |
CNPQ::CIENCIAS EXATAS E DA TERRA::FISICA::AREAS CLASSICAS DE FENOMENOLOGIA E SUAS APLICACOES::DINAMICA DOS FLUIDOS Conductive nanocomposites Electrical conductivity EVA Expanded graphite Unexpanded graphite Flash method Thermal diffusivity |
dc.subject.eng.fl_str_mv |
Conductive nanocomposites Electrical conductivity EVA Expanded graphite Unexpanded graphite Flash method Thermal diffusivity |
description |
Indisponível. |
publishDate |
2012 |
dc.date.issued.fl_str_mv |
2012-06-24 |
dc.date.accessioned.fl_str_mv |
2019-06-28T13:23:42Z |
dc.date.available.fl_str_mv |
2023-11-30T03:03:32Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/11422/8546 |
dc.identifier.issn.pt_BR.fl_str_mv |
0195-928X |
dc.identifier.doi.pt_BR.fl_str_mv |
10.1007/s10765-012-1231-z |
identifier_str_mv |
0195-928X 10.1007/s10765-012-1231-z |
url |
http://hdl.handle.net/11422/8546 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartof.en.fl_str_mv |
International Journal of Thermophysics |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
Springer Verlag |
dc.publisher.country.fl_str_mv |
Brasil |
dc.publisher.department.fl_str_mv |
Núcleo Interdisciplinar de Dinâmica dos Fluidos |
publisher.none.fl_str_mv |
Springer Verlag |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFRJ instname:Universidade Federal do Rio de Janeiro (UFRJ) instacron:UFRJ |
instname_str |
Universidade Federal do Rio de Janeiro (UFRJ) |
instacron_str |
UFRJ |
institution |
UFRJ |
reponame_str |
Repositório Institucional da UFRJ |
collection |
Repositório Institucional da UFRJ |
bitstream.url.fl_str_mv |
http://pantheon.ufrj.br:80/bitstream/11422/8546/1/2012_COTTA_IJT_v33_p1-10-min.pdf http://pantheon.ufrj.br:80/bitstream/11422/8546/2/license.txt |
bitstream.checksum.fl_str_mv |
99cd157df3011793fb3240e9444f53f9 dd32849f2bfb22da963c3aac6e26e255 |
bitstream.checksumAlgorithm.fl_str_mv |
MD5 MD5 |
repository.name.fl_str_mv |
Repositório Institucional da UFRJ - Universidade Federal do Rio de Janeiro (UFRJ) |
repository.mail.fl_str_mv |
|
_version_ |
1784097146681688064 |