Unconventional silica source employment in zeolite synthesis: Raw powder glass in MFI synthesis case study

Detalhes bibliográficos
Autor(a) principal: Vinaches, Paloma
Data de Publicação: 2015
Outros Autores: Rebitski, Ediana Paula, Alves, José Antônio Barros Leal Reis, Melo, Dulce M. A., Pergher, Sibele Berenice Castellã
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRN
Texto Completo: https://repositorio.ufrn.br/jspui/handle/123456789/29634
Resumo: In this work, the use of raw powder glass as a silica source was studied for silica MFI zeolite synthesis. The zeolite was successfully obtained by employing this silica source treated with a hydrochloric acid solution and as provided. Synthesis was performed using hydrofluoric acid as the mineralizing agent and tetrapropylammonium hydroxide as the organic structure-directing agent. Scanning electron microscopy micrographs revealed elongated crystals of larger size when the raw powder glass employed contained a lower silica percentage. X-ray diffraction patterns of the resulting products indicated that Fe-silicalite-1 was obtained and the Si/Fe ratio was calculated by interpolating the unit cell volume of the obtained zeolites in a linear regression created by employing literature data. The presence of iron was also confirmed by the presence of ν(Si–O–Fe)sym.str in the infrared spectra. Thermogravimetric analyses indicated good stability. This study concluded with a reproducible and optimized method for obtaining this versatile zeolite from raw powder glass with different compositions
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spelling Vinaches, PalomaRebitski, Ediana PaulaAlves, José Antônio Barros Leal ReisMelo, Dulce M. A.Pergher, Sibele Berenice Castellã2020-07-15T02:10:15Z2020-07-15T02:10:15Z2015-11-15VINACHES, P.; REBITSKI, E. P.; ALVES, J. A. B. L. R.; MELO, D. M. A.; PERGHER, Sibele Berenice Castellã. Unconventional silica source employment in zeolite synthesis: raw powder glass in mfi synthesis case study. Materials Letters, [s.l.], v. 159, p. 233-236, 15 nov. 2015. ISSN 0167-577X. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0167577X15301695?via%3Dihub. Acesso em: 14 jul. 2020. https://doi.org/10.1016/j.matlet.2015.06.120.0167-577Xhttps://repositorio.ufrn.br/jspui/handle/123456789/2963410.1016/j.matlet.2015.06.120ElsevierAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessMFI zeoliteRaw powder glassHydrofluoric acidUnconventional silica source employment in zeolite synthesis: Raw powder glass in MFI synthesis case studyinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleIn this work, the use of raw powder glass as a silica source was studied for silica MFI zeolite synthesis. The zeolite was successfully obtained by employing this silica source treated with a hydrochloric acid solution and as provided. Synthesis was performed using hydrofluoric acid as the mineralizing agent and tetrapropylammonium hydroxide as the organic structure-directing agent. Scanning electron microscopy micrographs revealed elongated crystals of larger size when the raw powder glass employed contained a lower silica percentage. X-ray diffraction patterns of the resulting products indicated that Fe-silicalite-1 was obtained and the Si/Fe ratio was calculated by interpolating the unit cell volume of the obtained zeolites in a linear regression created by employing literature data. The presence of iron was also confirmed by the presence of ν(Si–O–Fe)sym.str in the infrared spectra. Thermogravimetric analyses indicated good stability. This study concluded with a reproducible and optimized method for obtaining this versatile zeolite from raw powder glass with different compositionsengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALUnconventionalSilicaSourceEmployment_Pergher_2015.pdfUnconventionalSilicaSourceEmployment_Pergher_2015.pdfapplication/pdf848148https://repositorio.ufrn.br/bitstream/123456789/29634/1/UnconventionalSilicaSourceEmployment_Pergher_2015.pdf862763e710f0ad26ab66854adce2cc79MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/29634/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/29634/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53TEXTUnconventionalSilicaSourceEmployment_Pergher_2015.pdf.txtUnconventionalSilicaSourceEmployment_Pergher_2015.pdf.txtExtracted texttext/plain14665https://repositorio.ufrn.br/bitstream/123456789/29634/4/UnconventionalSilicaSourceEmployment_Pergher_2015.pdf.txt149e06cdc4acd6544096c66698993b0dMD54THUMBNAILUnconventionalSilicaSourceEmployment_Pergher_2015.pdf.jpgUnconventionalSilicaSourceEmployment_Pergher_2015.pdf.jpgGenerated Thumbnailimage/jpeg1722https://repositorio.ufrn.br/bitstream/123456789/29634/5/UnconventionalSilicaSourceEmployment_Pergher_2015.pdf.jpg671c0711dc8566dd04a57305349d81f1MD55123456789/296342021-02-15 15:48:39.238oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-02-15T18:48:39Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false
dc.title.pt_BR.fl_str_mv Unconventional silica source employment in zeolite synthesis: Raw powder glass in MFI synthesis case study
title Unconventional silica source employment in zeolite synthesis: Raw powder glass in MFI synthesis case study
spellingShingle Unconventional silica source employment in zeolite synthesis: Raw powder glass in MFI synthesis case study
Vinaches, Paloma
MFI zeolite
Raw powder glass
Hydrofluoric acid
title_short Unconventional silica source employment in zeolite synthesis: Raw powder glass in MFI synthesis case study
title_full Unconventional silica source employment in zeolite synthesis: Raw powder glass in MFI synthesis case study
title_fullStr Unconventional silica source employment in zeolite synthesis: Raw powder glass in MFI synthesis case study
title_full_unstemmed Unconventional silica source employment in zeolite synthesis: Raw powder glass in MFI synthesis case study
title_sort Unconventional silica source employment in zeolite synthesis: Raw powder glass in MFI synthesis case study
author Vinaches, Paloma
author_facet Vinaches, Paloma
Rebitski, Ediana Paula
Alves, José Antônio Barros Leal Reis
Melo, Dulce M. A.
Pergher, Sibele Berenice Castellã
author_role author
author2 Rebitski, Ediana Paula
Alves, José Antônio Barros Leal Reis
Melo, Dulce M. A.
Pergher, Sibele Berenice Castellã
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Vinaches, Paloma
Rebitski, Ediana Paula
Alves, José Antônio Barros Leal Reis
Melo, Dulce M. A.
Pergher, Sibele Berenice Castellã
dc.subject.por.fl_str_mv MFI zeolite
Raw powder glass
Hydrofluoric acid
topic MFI zeolite
Raw powder glass
Hydrofluoric acid
description In this work, the use of raw powder glass as a silica source was studied for silica MFI zeolite synthesis. The zeolite was successfully obtained by employing this silica source treated with a hydrochloric acid solution and as provided. Synthesis was performed using hydrofluoric acid as the mineralizing agent and tetrapropylammonium hydroxide as the organic structure-directing agent. Scanning electron microscopy micrographs revealed elongated crystals of larger size when the raw powder glass employed contained a lower silica percentage. X-ray diffraction patterns of the resulting products indicated that Fe-silicalite-1 was obtained and the Si/Fe ratio was calculated by interpolating the unit cell volume of the obtained zeolites in a linear regression created by employing literature data. The presence of iron was also confirmed by the presence of ν(Si–O–Fe)sym.str in the infrared spectra. Thermogravimetric analyses indicated good stability. This study concluded with a reproducible and optimized method for obtaining this versatile zeolite from raw powder glass with different compositions
publishDate 2015
dc.date.issued.fl_str_mv 2015-11-15
dc.date.accessioned.fl_str_mv 2020-07-15T02:10:15Z
dc.date.available.fl_str_mv 2020-07-15T02:10:15Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.citation.fl_str_mv VINACHES, P.; REBITSKI, E. P.; ALVES, J. A. B. L. R.; MELO, D. M. A.; PERGHER, Sibele Berenice Castellã. Unconventional silica source employment in zeolite synthesis: raw powder glass in mfi synthesis case study. Materials Letters, [s.l.], v. 159, p. 233-236, 15 nov. 2015. ISSN 0167-577X. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0167577X15301695?via%3Dihub. Acesso em: 14 jul. 2020. https://doi.org/10.1016/j.matlet.2015.06.120.
dc.identifier.uri.fl_str_mv https://repositorio.ufrn.br/jspui/handle/123456789/29634
dc.identifier.issn.none.fl_str_mv 0167-577X
dc.identifier.doi.none.fl_str_mv 10.1016/j.matlet.2015.06.120
identifier_str_mv VINACHES, P.; REBITSKI, E. P.; ALVES, J. A. B. L. R.; MELO, D. M. A.; PERGHER, Sibele Berenice Castellã. Unconventional silica source employment in zeolite synthesis: raw powder glass in mfi synthesis case study. Materials Letters, [s.l.], v. 159, p. 233-236, 15 nov. 2015. ISSN 0167-577X. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0167577X15301695?via%3Dihub. Acesso em: 14 jul. 2020. https://doi.org/10.1016/j.matlet.2015.06.120.
0167-577X
10.1016/j.matlet.2015.06.120
url https://repositorio.ufrn.br/jspui/handle/123456789/29634
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv Attribution 3.0 Brazil
http://creativecommons.org/licenses/by/3.0/br/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution 3.0 Brazil
http://creativecommons.org/licenses/by/3.0/br/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
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