Estudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de caju

Detalhes bibliográficos
Autor(a) principal: Jerônimo, Carlos Enrique de Medeiros
Data de Publicação: 2010
Tipo de documento: Tese
Idioma: por
Título da fonte: Repositório Institucional da UFRN
Texto Completo: https://repositorio.ufrn.br/jspui/handle/123456789/15901
Resumo: An evaluation project was conducted on the technique of treatment for effluent oil which is the deriving process to improve cashews. During the evaluation the following techniques were developed: advanced processes of humid oxidation, oxidative processes, processes of biological treatment and processes of adsorption. The assays had been carried through in kinetic models, with an evaluation of the quality of the process by means of determining the chemical demand of oxygen (defined as a technique of control by means of comparative study between the available techniques). The results demonstrated that the natural biodegradation of the effluent ones is limited, as result using the present natural flora in the effluent one revealed impracticable for an application in the industrial systems, independent of the evaluation environment (with or without the oxygen presence). The job of specific microorganisms for the oily composite degradation developed the viability technique of this route, the acceptable levels of inclusion in effluent system of treatment of the improvement of the cashew being highly good with reasonable levels of removal of CDO. However, the use combined with other techniques of daily pay-treatment for these effluent ones revealed to still be more efficient for the context of the treatment of effluent and discarding in receiving bodies in acceptable standards for resolution CONAMA 357/2005. While the significant generation of solid residues the process of adsorption with agroindustrial residues (in special the chitosan) is a technical viable alternative, however, when applied only for the treatment of the effluent ones for discarding in bodies of water, the economic viability is harmed and minimized ambient profits. Though, it was proven that if used for ends of I reuse, the viability is equalized and justifies the investments. There was a study of the photochemistry process which have are applicable to the treatment of the effluent ones, having resulted more satisfactory than those gotten for the UV-Peroxide techniques. There was different result on the one waited for the use of catalyses used in the process of Photo. The catalyses contained the mixing oxide base of Cerium and Manganese, incorporated of Potassium promoters this had presented the best results in the decomposition of the involved pollutants. Having itself an agreed form the gotten photochemistry daily paytreatment resulted, then after disinfection with chlorine the characteristics next the portability to the water were guarantee. The job of the humid oxidation presented significant results in the removal of pollutants; however, its high cost alone is made possible for job in projects of reuses, areas of low scarcity and of raised costs with the capitation/acquisition of the water, in special, for use for industrial and potable use. The route with better economic conditions and techniques for the job in the treatment of the effluent ones of the improvement of the cashew possesses the sequence to follow: conventional process of separation water-oil, photochemistry process and finally, the complementary biological treatment
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spelling Jerônimo, Carlos Enrique de Medeiroshttp://lattes.cnpq.br/9996525070555805http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4783510Y4Melo, Hênio Normando de Souzahttp://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4783216E1Mendes, Carlos Gomes Navehttp://lattes.cnpq.br/0093698796119367Oliveira, Fernando Jorge Santos dehttp://lattes.cnpq.br/7040531448584052Santos, Everaldo Silvino doshttp://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4799564Y2Araújo, André Luis Caladohttp://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4799320A6Sousa, João Fernandes de2014-12-17T15:01:50Z2010-12-222014-12-17T15:01:50Z2010-05-24JERÔNIMO, Carlos Enrique de Medeiros. Estudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de caju. 2010. 148 f. Tese (Doutorado em Pesquisa e Desenvolvimento de Tecnologias Regionais) - Universidade Federal do Rio Grande do Norte, Natal, 2010.https://repositorio.ufrn.br/jspui/handle/123456789/15901An evaluation project was conducted on the technique of treatment for effluent oil which is the deriving process to improve cashews. During the evaluation the following techniques were developed: advanced processes of humid oxidation, oxidative processes, processes of biological treatment and processes of adsorption. The assays had been carried through in kinetic models, with an evaluation of the quality of the process by means of determining the chemical demand of oxygen (defined as a technique of control by means of comparative study between the available techniques). The results demonstrated that the natural biodegradation of the effluent ones is limited, as result using the present natural flora in the effluent one revealed impracticable for an application in the industrial systems, independent of the evaluation environment (with or without the oxygen presence). The job of specific microorganisms for the oily composite degradation developed the viability technique of this route, the acceptable levels of inclusion in effluent system of treatment of the improvement of the cashew being highly good with reasonable levels of removal of CDO. However, the use combined with other techniques of daily pay-treatment for these effluent ones revealed to still be more efficient for the context of the treatment of effluent and discarding in receiving bodies in acceptable standards for resolution CONAMA 357/2005. While the significant generation of solid residues the process of adsorption with agroindustrial residues (in special the chitosan) is a technical viable alternative, however, when applied only for the treatment of the effluent ones for discarding in bodies of water, the economic viability is harmed and minimized ambient profits. Though, it was proven that if used for ends of I reuse, the viability is equalized and justifies the investments. There was a study of the photochemistry process which have are applicable to the treatment of the effluent ones, having resulted more satisfactory than those gotten for the UV-Peroxide techniques. There was different result on the one waited for the use of catalyses used in the process of Photo. The catalyses contained the mixing oxide base of Cerium and Manganese, incorporated of Potassium promoters this had presented the best results in the decomposition of the involved pollutants. Having itself an agreed form the gotten photochemistry daily paytreatment resulted, then after disinfection with chlorine the characteristics next the portability to the water were guarantee. The job of the humid oxidation presented significant results in the removal of pollutants; however, its high cost alone is made possible for job in projects of reuses, areas of low scarcity and of raised costs with the capitation/acquisition of the water, in special, for use for industrial and potable use. The route with better economic conditions and techniques for the job in the treatment of the effluent ones of the improvement of the cashew possesses the sequence to follow: conventional process of separation water-oil, photochemistry process and finally, the complementary biological treatmentNeste trabalho foram avaliadas técnicas de tratamento para os efluentes oleosos oriundos do processo de beneficiamento da castanha de caju. As técnicas avaliadas foram: processos de oxidação úmida, processos oxidativos avançados, processos de tratamento biológico e processos de adsorção. Os ensaios foram realizados com propostas de modelos cinéticos, com monitoramento da qualidade dos processos por meio da determinação da demanda química de oxigênio (definida como técnica de controle por meio de estudo comparativo entre as técnicas disponíveis). Os resultados demonstram que a biodegradação natural dos efluentes é limitada, e os resultados utilizando da flora natural presente no efluente mostrou-se inviável para aplicação em sistemas industriais, independente do ambiente de avaliação (com ou sem a presença de oxigênio). O emprego de microorganismos específicos para a degradação de compostos oleosos incrementou a viabilidade técnica dessa rota,em níveis adequados para aplicação em sistemas de tratamento de efluentes do beneficiamento da castanha, tendo-se uma boa expressividade, com remoção da DQO. Porém, o uso combinado com outras técnicas de pré-tratamento para esses efluentes mostrou-se ainda mais eficiente para o contexto do tratamento de efluentes e descarte em corpos receptores dentro dos padrões preconizados pela resolução CONAMA 357/2005. Apesar da geração significativa de resíduos sólidos, o emprego do processo de adsorção com resíduos agroindustriais (em especial a quitosana) é uma alternativa tecnicamente viável, porém, quando aplicada apenas para o tratamento dos efluentes para o descarte em corpos d água, a viabilidade econômica é prejudicada e os ganhos ambientais minimizados. Porém, foi comprovado que se utilizado para fins de reuso, a viabilidade é equiparada e justifica os investimentos. Os processos fotoquímicos são aplicáveis ao tratamento dos efluentes estudados, tendo-se como resultados mais satisfatórios aqueles obtidos para as técnicas de UV-Peróxido. Sendo o resultado diferente do esperado pela utilização de catalisadores usados no processo de Foto-Fenton. Os catalisadores a base de óxido misto de Cério e Manganês, incorporado de promotores de Potássio, apresentaram os melhores resultados na decomposição dos poluentes envolvidos. Os resultados obtidos de forma combinada ao pré-tratamento fotoquímico, após desinfecção com cloro, garantem características próximas a potabilidade da água. O emprego da oxidação úmida apresenta resultados muito significativos na remoção de poluentes, entretanto, o seu alto custo só é viabilizado para emprego em projetos de reuso, em áreas de baixa escassez e de elevados custos com a captação/aquisição da água, em especial, para utilização para uso industrial e potável. A rota com melhores condições econômicas e técnicas para o emprego no tratamento dos efluentes do beneficiamento da castanha de caju, possui a seqüência a seguir: processo convencional de separação água-óleo, processo fotoquímico e por fim, o tratamento biológico complementarapplication/pdfporUniversidade Federal do Rio Grande do NortePrograma de Pós-Graduação em Engenharia QuímicaUFRNBRPesquisa e Desenvolvimento de Tecnologias RegionaisEfluentes oleososProcessos oxidativos avançadosFotoquímicaCinéticaReatoresEffluent oilyAdvanced treatmentOxidation processes and photochemistryCNPQ::ENGENHARIAS::ENGENHARIA DE PRODUCAOEstudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de cajuinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALCarlosEMJ_TESE.pdfapplication/pdf1404904https://repositorio.ufrn.br/bitstream/123456789/15901/1/CarlosEMJ_TESE.pdf3029c558b265d6dfdac69a6fac1ef20cMD51TEXTCarlosEMJ_TESE.pdf.txtCarlosEMJ_TESE.pdf.txtExtracted texttext/plain274243https://repositorio.ufrn.br/bitstream/123456789/15901/6/CarlosEMJ_TESE.pdf.txt5d272deb25d219b4e0ed6e0c56a68468MD56THUMBNAILCarlosEMJ_TESE.pdf.jpgCarlosEMJ_TESE.pdf.jpgIM Thumbnailimage/jpeg2641https://repositorio.ufrn.br/bitstream/123456789/15901/7/CarlosEMJ_TESE.pdf.jpg7fbd06841cd23d2dc3ba71418d5e5852MD57123456789/159012017-11-02 05:53:04.271oai:https://repositorio.ufrn.br:123456789/15901Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2017-11-02T08:53:04Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false
dc.title.por.fl_str_mv Estudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de caju
title Estudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de caju
spellingShingle Estudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de caju
Jerônimo, Carlos Enrique de Medeiros
Efluentes oleosos
Processos oxidativos avançados
Fotoquímica
Cinética
Reatores
Effluent oily
Advanced treatment
Oxidation processes and photochemistry
CNPQ::ENGENHARIAS::ENGENHARIA DE PRODUCAO
title_short Estudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de caju
title_full Estudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de caju
title_fullStr Estudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de caju
title_full_unstemmed Estudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de caju
title_sort Estudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de caju
author Jerônimo, Carlos Enrique de Medeiros
author_facet Jerônimo, Carlos Enrique de Medeiros
author_role author
dc.contributor.authorID.por.fl_str_mv
dc.contributor.authorLattes.por.fl_str_mv http://lattes.cnpq.br/9996525070555805
dc.contributor.advisorID.por.fl_str_mv
dc.contributor.advisorLattes.por.fl_str_mv http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4783510Y4
dc.contributor.referees1.pt_BR.fl_str_mv Melo, Hênio Normando de Souza
dc.contributor.referees1ID.por.fl_str_mv
dc.contributor.referees1Lattes.por.fl_str_mv http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4783216E1
dc.contributor.referees2.pt_BR.fl_str_mv Mendes, Carlos Gomes Nave
dc.contributor.referees2ID.por.fl_str_mv
dc.contributor.referees2Lattes.por.fl_str_mv http://lattes.cnpq.br/0093698796119367
dc.contributor.referees3.pt_BR.fl_str_mv Oliveira, Fernando Jorge Santos de
dc.contributor.referees3ID.por.fl_str_mv
dc.contributor.referees3Lattes.por.fl_str_mv http://lattes.cnpq.br/7040531448584052
dc.contributor.referees4.pt_BR.fl_str_mv Santos, Everaldo Silvino dos
dc.contributor.referees4ID.por.fl_str_mv
dc.contributor.referees4Lattes.por.fl_str_mv http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4799564Y2
dc.contributor.referees5.pt_BR.fl_str_mv Araújo, André Luis Calado
dc.contributor.referees5ID.por.fl_str_mv
dc.contributor.referees5Lattes.por.fl_str_mv http://buscatextual.cnpq.br/buscatextual/visualizacv.do?id=K4799320A6
dc.contributor.author.fl_str_mv Jerônimo, Carlos Enrique de Medeiros
dc.contributor.advisor1.fl_str_mv Sousa, João Fernandes de
contributor_str_mv Sousa, João Fernandes de
dc.subject.por.fl_str_mv Efluentes oleosos
Processos oxidativos avançados
Fotoquímica
Cinética
Reatores
topic Efluentes oleosos
Processos oxidativos avançados
Fotoquímica
Cinética
Reatores
Effluent oily
Advanced treatment
Oxidation processes and photochemistry
CNPQ::ENGENHARIAS::ENGENHARIA DE PRODUCAO
dc.subject.eng.fl_str_mv Effluent oily
Advanced treatment
Oxidation processes and photochemistry
dc.subject.cnpq.fl_str_mv CNPQ::ENGENHARIAS::ENGENHARIA DE PRODUCAO
description An evaluation project was conducted on the technique of treatment for effluent oil which is the deriving process to improve cashews. During the evaluation the following techniques were developed: advanced processes of humid oxidation, oxidative processes, processes of biological treatment and processes of adsorption. The assays had been carried through in kinetic models, with an evaluation of the quality of the process by means of determining the chemical demand of oxygen (defined as a technique of control by means of comparative study between the available techniques). The results demonstrated that the natural biodegradation of the effluent ones is limited, as result using the present natural flora in the effluent one revealed impracticable for an application in the industrial systems, independent of the evaluation environment (with or without the oxygen presence). The job of specific microorganisms for the oily composite degradation developed the viability technique of this route, the acceptable levels of inclusion in effluent system of treatment of the improvement of the cashew being highly good with reasonable levels of removal of CDO. However, the use combined with other techniques of daily pay-treatment for these effluent ones revealed to still be more efficient for the context of the treatment of effluent and discarding in receiving bodies in acceptable standards for resolution CONAMA 357/2005. While the significant generation of solid residues the process of adsorption with agroindustrial residues (in special the chitosan) is a technical viable alternative, however, when applied only for the treatment of the effluent ones for discarding in bodies of water, the economic viability is harmed and minimized ambient profits. Though, it was proven that if used for ends of I reuse, the viability is equalized and justifies the investments. There was a study of the photochemistry process which have are applicable to the treatment of the effluent ones, having resulted more satisfactory than those gotten for the UV-Peroxide techniques. There was different result on the one waited for the use of catalyses used in the process of Photo. The catalyses contained the mixing oxide base of Cerium and Manganese, incorporated of Potassium promoters this had presented the best results in the decomposition of the involved pollutants. Having itself an agreed form the gotten photochemistry daily paytreatment resulted, then after disinfection with chlorine the characteristics next the portability to the water were guarantee. The job of the humid oxidation presented significant results in the removal of pollutants; however, its high cost alone is made possible for job in projects of reuses, areas of low scarcity and of raised costs with the capitation/acquisition of the water, in special, for use for industrial and potable use. The route with better economic conditions and techniques for the job in the treatment of the effluent ones of the improvement of the cashew possesses the sequence to follow: conventional process of separation water-oil, photochemistry process and finally, the complementary biological treatment
publishDate 2010
dc.date.available.fl_str_mv 2010-12-22
2014-12-17T15:01:50Z
dc.date.issued.fl_str_mv 2010-05-24
dc.date.accessioned.fl_str_mv 2014-12-17T15:01:50Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
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dc.identifier.citation.fl_str_mv JERÔNIMO, Carlos Enrique de Medeiros. Estudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de caju. 2010. 148 f. Tese (Doutorado em Pesquisa e Desenvolvimento de Tecnologias Regionais) - Universidade Federal do Rio Grande do Norte, Natal, 2010.
dc.identifier.uri.fl_str_mv https://repositorio.ufrn.br/jspui/handle/123456789/15901
identifier_str_mv JERÔNIMO, Carlos Enrique de Medeiros. Estudo de técnicas para o tratamento alternativo de efluentes oleosos oriundos da industrialização da castanha de caju. 2010. 148 f. Tese (Doutorado em Pesquisa e Desenvolvimento de Tecnologias Regionais) - Universidade Federal do Rio Grande do Norte, Natal, 2010.
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