Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/45386 http://dx.doi.org/10.1016/j.jallcom.2019.151711 |
Resumo: | Forms of degradation of the environmental pollutant sulphamethoxazole have been studied over the years, and one form of degradation in heterogeneous photocatalysis. In this work a study was carried out to elaborate a photocatalyst capable of degrading the pollutant sulfamethoxazole, starting to elaborate heterojunctions between TiO2 and CeO2 doped with gadolinium, showing that the combination of both materials is able to contribute to the degradation of the pollutant, promoting 97% degradation. This favorable performance can be attributed by the formation of a characterized heterojunction with presence of mesopores that aid in the adsorption processes on the surface of the photocatalyst, and a high formation of active sites resulting from the formation of the electron pair, promoted by the excitation of the electrons of the band of valence for conduction band by means of photons. |
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Rodrigues, Murillo Henrique de MatosSousa, Priscila Afonso Rodrigues deBorges, Kellen Cristina M.Coelho, Luciana de MeloGonçalves, Rosana de FatimaTeodoro, Marcio DaldinMotta, Fabiana Vilella daNascimento, Rubens Maribondo doGodinho Júnior, Mario2021-12-15T20:10:08Z2021-12-15T20:10:08Z2019-11RODRIGUES, Murillo Henrique de Matos; SOUSA, Priscila Afonso Rodrigues de; BORGES, Kellen Cristina M.; COELHO, Luciana de Melo; GONÇALVES, Rosana de Fátima; TEODORO, Márcio Daldin; MOTTA, Fabiana Vilella da; NASCIMENTO, Rubens Maribondo do; GODINHO JÚNIOR, Mario. Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles. Journal of Alloys and Compounds, [S.l.], v. 808, p. 151711-151711, nov. 2019. Elsevier BV. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0925838819329445?via%3Dihub . Acesso em: 06 set. 2021. DOI: http://dx.doi.org/10.1016/j.jallcom.2019.151711https://repositorio.ufrn.br/handle/123456789/45386http://dx.doi.org/10.1016/j.jallcom.2019.151711Forms of degradation of the environmental pollutant sulphamethoxazole have been studied over the years, and one form of degradation in heterogeneous photocatalysis. In this work a study was carried out to elaborate a photocatalyst capable of degrading the pollutant sulfamethoxazole, starting to elaborate heterojunctions between TiO2 and CeO2 doped with gadolinium, showing that the combination of both materials is able to contribute to the degradation of the pollutant, promoting 97% degradation. This favorable performance can be attributed by the formation of a characterized heterojunction with presence of mesopores that aid in the adsorption processes on the surface of the photocatalyst, and a high formation of active sites resulting from the formation of the electron pair, promoted by the excitation of the electrons of the band of valence for conduction band by means of photons.Forms of degradation of the environmental pollutant sulphamethoxazole have been studied over the years, and one form of degradation in heterogeneous photocatalysis. In this work a study was carried out to elaborate a photocatalyst capable of degrading the pollutant sulfamethoxazole, starting to elaborate heterojunctions between TiO2 and CeO2 doped with gadolinium, showing that the combination of both materials is able to contribute to the degradation of the pollutant, promoting 97% degradation. This favorable performance can be attributed by the formation of a characterized heterojunction with presence of mesopores that aid in the adsorption processes on the surface of the photocatalyst, and a high formation of active sites resulting from the formation of the electron pair, promoted by the excitation of the electrons of the band of valence for conduction band by means of photons.ElsevierAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessSulfamethoxazolePollutantHeterogeneous photocatalysisHeterojunctionTiO2Ce0,8Gd0,2O2-δEnhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particlesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALEnhancedDegradationAntibiotic_MOTTA_2019.pdfEnhancedDegradationAntibiotic_MOTTA_2019.pdfapplication/pdf3153789https://repositorio.ufrn.br/bitstream/123456789/45386/1/EnhancedDegradationAntibiotic_MOTTA_2019.pdfdf6575cca02eb92af58d79a50f46ddc2MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/45386/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/45386/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53123456789/453862021-12-15 17:20:45.168oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-12-15T20:20:45Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles |
title |
Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles |
spellingShingle |
Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles Rodrigues, Murillo Henrique de Matos Sulfamethoxazole Pollutant Heterogeneous photocatalysis Heterojunction TiO2 Ce0,8Gd0,2O2-δ |
title_short |
Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles |
title_full |
Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles |
title_fullStr |
Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles |
title_full_unstemmed |
Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles |
title_sort |
Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles |
author |
Rodrigues, Murillo Henrique de Matos |
author_facet |
Rodrigues, Murillo Henrique de Matos Sousa, Priscila Afonso Rodrigues de Borges, Kellen Cristina M. Coelho, Luciana de Melo Gonçalves, Rosana de Fatima Teodoro, Marcio Daldin Motta, Fabiana Vilella da Nascimento, Rubens Maribondo do Godinho Júnior, Mario |
author_role |
author |
author2 |
Sousa, Priscila Afonso Rodrigues de Borges, Kellen Cristina M. Coelho, Luciana de Melo Gonçalves, Rosana de Fatima Teodoro, Marcio Daldin Motta, Fabiana Vilella da Nascimento, Rubens Maribondo do Godinho Júnior, Mario |
author2_role |
author author author author author author author author |
dc.contributor.author.fl_str_mv |
Rodrigues, Murillo Henrique de Matos Sousa, Priscila Afonso Rodrigues de Borges, Kellen Cristina M. Coelho, Luciana de Melo Gonçalves, Rosana de Fatima Teodoro, Marcio Daldin Motta, Fabiana Vilella da Nascimento, Rubens Maribondo do Godinho Júnior, Mario |
dc.subject.por.fl_str_mv |
Sulfamethoxazole Pollutant Heterogeneous photocatalysis Heterojunction TiO2 Ce0,8Gd0,2O2-δ |
topic |
Sulfamethoxazole Pollutant Heterogeneous photocatalysis Heterojunction TiO2 Ce0,8Gd0,2O2-δ |
description |
Forms of degradation of the environmental pollutant sulphamethoxazole have been studied over the years, and one form of degradation in heterogeneous photocatalysis. In this work a study was carried out to elaborate a photocatalyst capable of degrading the pollutant sulfamethoxazole, starting to elaborate heterojunctions between TiO2 and CeO2 doped with gadolinium, showing that the combination of both materials is able to contribute to the degradation of the pollutant, promoting 97% degradation. This favorable performance can be attributed by the formation of a characterized heterojunction with presence of mesopores that aid in the adsorption processes on the surface of the photocatalyst, and a high formation of active sites resulting from the formation of the electron pair, promoted by the excitation of the electrons of the band of valence for conduction band by means of photons. |
publishDate |
2019 |
dc.date.issued.fl_str_mv |
2019-11 |
dc.date.accessioned.fl_str_mv |
2021-12-15T20:10:08Z |
dc.date.available.fl_str_mv |
2021-12-15T20:10:08Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
RODRIGUES, Murillo Henrique de Matos; SOUSA, Priscila Afonso Rodrigues de; BORGES, Kellen Cristina M.; COELHO, Luciana de Melo; GONÇALVES, Rosana de Fátima; TEODORO, Márcio Daldin; MOTTA, Fabiana Vilella da; NASCIMENTO, Rubens Maribondo do; GODINHO JÚNIOR, Mario. Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles. Journal of Alloys and Compounds, [S.l.], v. 808, p. 151711-151711, nov. 2019. Elsevier BV. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0925838819329445?via%3Dihub . Acesso em: 06 set. 2021. DOI: http://dx.doi.org/10.1016/j.jallcom.2019.151711 |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/45386 |
dc.identifier.doi.none.fl_str_mv |
http://dx.doi.org/10.1016/j.jallcom.2019.151711 |
identifier_str_mv |
RODRIGUES, Murillo Henrique de Matos; SOUSA, Priscila Afonso Rodrigues de; BORGES, Kellen Cristina M.; COELHO, Luciana de Melo; GONÇALVES, Rosana de Fátima; TEODORO, Márcio Daldin; MOTTA, Fabiana Vilella da; NASCIMENTO, Rubens Maribondo do; GODINHO JÚNIOR, Mario. Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles. Journal of Alloys and Compounds, [S.l.], v. 808, p. 151711-151711, nov. 2019. Elsevier BV. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0925838819329445?via%3Dihub . Acesso em: 06 set. 2021. DOI: http://dx.doi.org/10.1016/j.jallcom.2019.151711 |
url |
https://repositorio.ufrn.br/handle/123456789/45386 http://dx.doi.org/10.1016/j.jallcom.2019.151711 |
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eng |
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openAccess |
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Elsevier |
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Elsevier |
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