Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles

Detalhes bibliográficos
Autor(a) principal: Rodrigues, Murillo Henrique de Matos
Data de Publicação: 2019
Outros Autores: Sousa, Priscila Afonso Rodrigues de, Borges, Kellen Cristina M., Coelho, Luciana de Melo, Gonçalves, Rosana de Fatima, Teodoro, Marcio Daldin, Motta, Fabiana Vilella da, Nascimento, Rubens Maribondo do, Godinho Júnior, Mario
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRN
Texto Completo: https://repositorio.ufrn.br/handle/123456789/45386
http://dx.doi.org/10.1016/j.jallcom.2019.151711
Resumo: Forms of degradation of the environmental pollutant sulphamethoxazole have been studied over the years, and one form of degradation in heterogeneous photocatalysis. In this work a study was carried out to elaborate a photocatalyst capable of degrading the pollutant sulfamethoxazole, starting to elaborate heterojunctions between TiO2 and CeO2 doped with gadolinium, showing that the combination of both materials is able to contribute to the degradation of the pollutant, promoting 97% degradation. This favorable performance can be attributed by the formation of a characterized heterojunction with presence of mesopores that aid in the adsorption processes on the surface of the photocatalyst, and a high formation of active sites resulting from the formation of the electron pair, promoted by the excitation of the electrons of the band of valence for conduction band by means of photons.
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spelling Rodrigues, Murillo Henrique de MatosSousa, Priscila Afonso Rodrigues deBorges, Kellen Cristina M.Coelho, Luciana de MeloGonçalves, Rosana de FatimaTeodoro, Marcio DaldinMotta, Fabiana Vilella daNascimento, Rubens Maribondo doGodinho Júnior, Mario2021-12-15T20:10:08Z2021-12-15T20:10:08Z2019-11RODRIGUES, Murillo Henrique de Matos; SOUSA, Priscila Afonso Rodrigues de; BORGES, Kellen Cristina M.; COELHO, Luciana de Melo; GONÇALVES, Rosana de Fátima; TEODORO, Márcio Daldin; MOTTA, Fabiana Vilella da; NASCIMENTO, Rubens Maribondo do; GODINHO JÚNIOR, Mario. Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles. Journal of Alloys and Compounds, [S.l.], v. 808, p. 151711-151711, nov. 2019. Elsevier BV. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0925838819329445?via%3Dihub . Acesso em: 06 set. 2021. DOI: http://dx.doi.org/10.1016/j.jallcom.2019.151711https://repositorio.ufrn.br/handle/123456789/45386http://dx.doi.org/10.1016/j.jallcom.2019.151711Forms of degradation of the environmental pollutant sulphamethoxazole have been studied over the years, and one form of degradation in heterogeneous photocatalysis. In this work a study was carried out to elaborate a photocatalyst capable of degrading the pollutant sulfamethoxazole, starting to elaborate heterojunctions between TiO2 and CeO2 doped with gadolinium, showing that the combination of both materials is able to contribute to the degradation of the pollutant, promoting 97% degradation. This favorable performance can be attributed by the formation of a characterized heterojunction with presence of mesopores that aid in the adsorption processes on the surface of the photocatalyst, and a high formation of active sites resulting from the formation of the electron pair, promoted by the excitation of the electrons of the band of valence for conduction band by means of photons.Forms of degradation of the environmental pollutant sulphamethoxazole have been studied over the years, and one form of degradation in heterogeneous photocatalysis. In this work a study was carried out to elaborate a photocatalyst capable of degrading the pollutant sulfamethoxazole, starting to elaborate heterojunctions between TiO2 and CeO2 doped with gadolinium, showing that the combination of both materials is able to contribute to the degradation of the pollutant, promoting 97% degradation. This favorable performance can be attributed by the formation of a characterized heterojunction with presence of mesopores that aid in the adsorption processes on the surface of the photocatalyst, and a high formation of active sites resulting from the formation of the electron pair, promoted by the excitation of the electrons of the band of valence for conduction band by means of photons.ElsevierAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessSulfamethoxazolePollutantHeterogeneous photocatalysisHeterojunctionTiO2Ce0,8Gd0,2O2-δEnhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particlesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALEnhancedDegradationAntibiotic_MOTTA_2019.pdfEnhancedDegradationAntibiotic_MOTTA_2019.pdfapplication/pdf3153789https://repositorio.ufrn.br/bitstream/123456789/45386/1/EnhancedDegradationAntibiotic_MOTTA_2019.pdfdf6575cca02eb92af58d79a50f46ddc2MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/45386/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/45386/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53123456789/453862021-12-15 17:20:45.168oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-12-15T20:20:45Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false
dc.title.pt_BR.fl_str_mv Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles
title Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles
spellingShingle Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles
Rodrigues, Murillo Henrique de Matos
Sulfamethoxazole
Pollutant
Heterogeneous photocatalysis
Heterojunction
TiO2
Ce0,8Gd0,2O2-δ
title_short Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles
title_full Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles
title_fullStr Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles
title_full_unstemmed Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles
title_sort Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles
author Rodrigues, Murillo Henrique de Matos
author_facet Rodrigues, Murillo Henrique de Matos
Sousa, Priscila Afonso Rodrigues de
Borges, Kellen Cristina M.
Coelho, Luciana de Melo
Gonçalves, Rosana de Fatima
Teodoro, Marcio Daldin
Motta, Fabiana Vilella da
Nascimento, Rubens Maribondo do
Godinho Júnior, Mario
author_role author
author2 Sousa, Priscila Afonso Rodrigues de
Borges, Kellen Cristina M.
Coelho, Luciana de Melo
Gonçalves, Rosana de Fatima
Teodoro, Marcio Daldin
Motta, Fabiana Vilella da
Nascimento, Rubens Maribondo do
Godinho Júnior, Mario
author2_role author
author
author
author
author
author
author
author
dc.contributor.author.fl_str_mv Rodrigues, Murillo Henrique de Matos
Sousa, Priscila Afonso Rodrigues de
Borges, Kellen Cristina M.
Coelho, Luciana de Melo
Gonçalves, Rosana de Fatima
Teodoro, Marcio Daldin
Motta, Fabiana Vilella da
Nascimento, Rubens Maribondo do
Godinho Júnior, Mario
dc.subject.por.fl_str_mv Sulfamethoxazole
Pollutant
Heterogeneous photocatalysis
Heterojunction
TiO2
Ce0,8Gd0,2O2-δ
topic Sulfamethoxazole
Pollutant
Heterogeneous photocatalysis
Heterojunction
TiO2
Ce0,8Gd0,2O2-δ
description Forms of degradation of the environmental pollutant sulphamethoxazole have been studied over the years, and one form of degradation in heterogeneous photocatalysis. In this work a study was carried out to elaborate a photocatalyst capable of degrading the pollutant sulfamethoxazole, starting to elaborate heterojunctions between TiO2 and CeO2 doped with gadolinium, showing that the combination of both materials is able to contribute to the degradation of the pollutant, promoting 97% degradation. This favorable performance can be attributed by the formation of a characterized heterojunction with presence of mesopores that aid in the adsorption processes on the surface of the photocatalyst, and a high formation of active sites resulting from the formation of the electron pair, promoted by the excitation of the electrons of the band of valence for conduction band by means of photons.
publishDate 2019
dc.date.issued.fl_str_mv 2019-11
dc.date.accessioned.fl_str_mv 2021-12-15T20:10:08Z
dc.date.available.fl_str_mv 2021-12-15T20:10:08Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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status_str publishedVersion
dc.identifier.citation.fl_str_mv RODRIGUES, Murillo Henrique de Matos; SOUSA, Priscila Afonso Rodrigues de; BORGES, Kellen Cristina M.; COELHO, Luciana de Melo; GONÇALVES, Rosana de Fátima; TEODORO, Márcio Daldin; MOTTA, Fabiana Vilella da; NASCIMENTO, Rubens Maribondo do; GODINHO JÚNIOR, Mario. Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles. Journal of Alloys and Compounds, [S.l.], v. 808, p. 151711-151711, nov. 2019. Elsevier BV. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0925838819329445?via%3Dihub . Acesso em: 06 set. 2021. DOI: http://dx.doi.org/10.1016/j.jallcom.2019.151711
dc.identifier.uri.fl_str_mv https://repositorio.ufrn.br/handle/123456789/45386
dc.identifier.doi.none.fl_str_mv http://dx.doi.org/10.1016/j.jallcom.2019.151711
identifier_str_mv RODRIGUES, Murillo Henrique de Matos; SOUSA, Priscila Afonso Rodrigues de; BORGES, Kellen Cristina M.; COELHO, Luciana de Melo; GONÇALVES, Rosana de Fátima; TEODORO, Márcio Daldin; MOTTA, Fabiana Vilella da; NASCIMENTO, Rubens Maribondo do; GODINHO JÚNIOR, Mario. Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles. Journal of Alloys and Compounds, [S.l.], v. 808, p. 151711-151711, nov. 2019. Elsevier BV. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0925838819329445?via%3Dihub . Acesso em: 06 set. 2021. DOI: http://dx.doi.org/10.1016/j.jallcom.2019.151711
url https://repositorio.ufrn.br/handle/123456789/45386
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rights_invalid_str_mv Attribution 3.0 Brazil
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dc.publisher.none.fl_str_mv Elsevier
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