Comparison between the action of Nano-Oxides and conventional EP additives in boundary lubrication

Detalhes bibliográficos
Autor(a) principal: Alves, S.M
Data de Publicação: 2020
Outros Autores: Mello, Valdicleide Silva, Trajano, Marinalva Ferreira, Guedes, Ana Emilia Diniz Silva
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRN
Texto Completo: https://repositorio.ufrn.br/jspui/handle/123456789/30153
Resumo: Additives are essential in lubricant development, improving their performance by the formation of a protective film, thus reducing friction and wear. Some such additives are extreme pressure additives. However, due to environmental issues, their use has been questioned because their composition includes sulfur, chlorine, and phosphorus. Nanoparticles have been demonstrated to be a suitable substitute for those additives. This paper aims to make a comparison of the tribological performance of conventional EP additives and oxides nanoparticles (copper and zinc) under boundary lubrication conditions. The additives (nanoparticles, ZDDP, and sulfur) were added to mineral and synthetic oils. The lubricant tribological properties were analyzed in the tribometer HFRR (high frequency reciprocating rig), and during the test, the friction coefficient and percentual of film formation were measured. The wear was analyzed by scanning electron microscopy. The results showed that the conventional EP additives have a good performance owing to their anti-wear and small friction coefficient in both lubricant bases. The oxides nanoparticles, when used as additives, can reduce the friction more effectively than conventional additives, and displayed similar behavior to the extreme pressure additives. Thus, the oxide nanoparticles are more environmentally suitable, and they can replace EP additives adapting the lubricant to current environmental requirements
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spelling Alves, S.MMello, Valdicleide SilvaTrajano, Marinalva FerreiraGuedes, Ana Emilia Diniz Silva2020-09-21T23:36:54Z2020-09-21T23:36:54Z2020-05-12MELLO, Valdicleide Silva; TRAJANO, Marinalva Ferreira; GUEDES, Ana Emilia Diniz Silva; ALVES, Salete Martins. Comparison between the action of Nano-Oxides and conventional EP additives in boundary lubrication. Lubricants, [s.l.], v. 8, n. 5, p. 54, 12 maio 2020. Disponível em: https://www.mdpi.com/2075-4442/8/5/54. Acesso em: 24 ago. 2020. http://dx.doi.org/10.3390/lubricants8050054.2075-4442https://repositorio.ufrn.br/jspui/handle/123456789/3015310.3390/lubricants8050054MDPIAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessBoundary lubrication;EP additivesOxides nanoparticlesComparison between the action of Nano-Oxides and conventional EP additives in boundary lubricationinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleAdditives are essential in lubricant development, improving their performance by the formation of a protective film, thus reducing friction and wear. Some such additives are extreme pressure additives. However, due to environmental issues, their use has been questioned because their composition includes sulfur, chlorine, and phosphorus. Nanoparticles have been demonstrated to be a suitable substitute for those additives. This paper aims to make a comparison of the tribological performance of conventional EP additives and oxides nanoparticles (copper and zinc) under boundary lubrication conditions. The additives (nanoparticles, ZDDP, and sulfur) were added to mineral and synthetic oils. The lubricant tribological properties were analyzed in the tribometer HFRR (high frequency reciprocating rig), and during the test, the friction coefficient and percentual of film formation were measured. The wear was analyzed by scanning electron microscopy. The results showed that the conventional EP additives have a good performance owing to their anti-wear and small friction coefficient in both lubricant bases. The oxides nanoparticles, when used as additives, can reduce the friction more effectively than conventional additives, and displayed similar behavior to the extreme pressure additives. Thus, the oxide nanoparticles are more environmentally suitable, and they can replace EP additives adapting the lubricant to current environmental requirementsengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALComparisonBetweenAction_ALVES_2020 (4).pdfComparisonBetweenAction_ALVES_2020 (4).pdfapplication/pdf4060281https://repositorio.ufrn.br/bitstream/123456789/30153/1/ComparisonBetweenAction_ALVES_2020%20%284%29.pdf55ba6400d43116c2884200aaad24bcc2MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/30153/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/30153/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53TEXTComparisonBetweenAction_ALVES_2020 (4).pdf.txtComparisonBetweenAction_ALVES_2020 (4).pdf.txtExtracted texttext/plain44712https://repositorio.ufrn.br/bitstream/123456789/30153/4/ComparisonBetweenAction_ALVES_2020%20%284%29.pdf.txtfa8f736fb39ae830c23c63ce216d4e2cMD54THUMBNAILComparisonBetweenAction_ALVES_2020 (4).pdf.jpgComparisonBetweenAction_ALVES_2020 (4).pdf.jpgGenerated Thumbnailimage/jpeg1597https://repositorio.ufrn.br/bitstream/123456789/30153/5/ComparisonBetweenAction_ALVES_2020%20%284%29.pdf.jpg321608a4c91f9e8d46e46f827abdf839MD55123456789/301532020-09-27 04:55:38.99oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2020-09-27T07:55:38Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false
dc.title.pt_BR.fl_str_mv Comparison between the action of Nano-Oxides and conventional EP additives in boundary lubrication
title Comparison between the action of Nano-Oxides and conventional EP additives in boundary lubrication
spellingShingle Comparison between the action of Nano-Oxides and conventional EP additives in boundary lubrication
Alves, S.M
Boundary lubrication;
EP additives
Oxides nanoparticles
title_short Comparison between the action of Nano-Oxides and conventional EP additives in boundary lubrication
title_full Comparison between the action of Nano-Oxides and conventional EP additives in boundary lubrication
title_fullStr Comparison between the action of Nano-Oxides and conventional EP additives in boundary lubrication
title_full_unstemmed Comparison between the action of Nano-Oxides and conventional EP additives in boundary lubrication
title_sort Comparison between the action of Nano-Oxides and conventional EP additives in boundary lubrication
author Alves, S.M
author_facet Alves, S.M
Mello, Valdicleide Silva
Trajano, Marinalva Ferreira
Guedes, Ana Emilia Diniz Silva
author_role author
author2 Mello, Valdicleide Silva
Trajano, Marinalva Ferreira
Guedes, Ana Emilia Diniz Silva
author2_role author
author
author
dc.contributor.author.fl_str_mv Alves, S.M
Mello, Valdicleide Silva
Trajano, Marinalva Ferreira
Guedes, Ana Emilia Diniz Silva
dc.subject.por.fl_str_mv Boundary lubrication;
EP additives
Oxides nanoparticles
topic Boundary lubrication;
EP additives
Oxides nanoparticles
description Additives are essential in lubricant development, improving their performance by the formation of a protective film, thus reducing friction and wear. Some such additives are extreme pressure additives. However, due to environmental issues, their use has been questioned because their composition includes sulfur, chlorine, and phosphorus. Nanoparticles have been demonstrated to be a suitable substitute for those additives. This paper aims to make a comparison of the tribological performance of conventional EP additives and oxides nanoparticles (copper and zinc) under boundary lubrication conditions. The additives (nanoparticles, ZDDP, and sulfur) were added to mineral and synthetic oils. The lubricant tribological properties were analyzed in the tribometer HFRR (high frequency reciprocating rig), and during the test, the friction coefficient and percentual of film formation were measured. The wear was analyzed by scanning electron microscopy. The results showed that the conventional EP additives have a good performance owing to their anti-wear and small friction coefficient in both lubricant bases. The oxides nanoparticles, when used as additives, can reduce the friction more effectively than conventional additives, and displayed similar behavior to the extreme pressure additives. Thus, the oxide nanoparticles are more environmentally suitable, and they can replace EP additives adapting the lubricant to current environmental requirements
publishDate 2020
dc.date.accessioned.fl_str_mv 2020-09-21T23:36:54Z
dc.date.available.fl_str_mv 2020-09-21T23:36:54Z
dc.date.issued.fl_str_mv 2020-05-12
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
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dc.identifier.citation.fl_str_mv MELLO, Valdicleide Silva; TRAJANO, Marinalva Ferreira; GUEDES, Ana Emilia Diniz Silva; ALVES, Salete Martins. Comparison between the action of Nano-Oxides and conventional EP additives in boundary lubrication. Lubricants, [s.l.], v. 8, n. 5, p. 54, 12 maio 2020. Disponível em: https://www.mdpi.com/2075-4442/8/5/54. Acesso em: 24 ago. 2020. http://dx.doi.org/10.3390/lubricants8050054.
dc.identifier.uri.fl_str_mv https://repositorio.ufrn.br/jspui/handle/123456789/30153
dc.identifier.issn.none.fl_str_mv 2075-4442
dc.identifier.doi.none.fl_str_mv 10.3390/lubricants8050054
identifier_str_mv MELLO, Valdicleide Silva; TRAJANO, Marinalva Ferreira; GUEDES, Ana Emilia Diniz Silva; ALVES, Salete Martins. Comparison between the action of Nano-Oxides and conventional EP additives in boundary lubrication. Lubricants, [s.l.], v. 8, n. 5, p. 54, 12 maio 2020. Disponível em: https://www.mdpi.com/2075-4442/8/5/54. Acesso em: 24 ago. 2020. http://dx.doi.org/10.3390/lubricants8050054.
2075-4442
10.3390/lubricants8050054
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