Nanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgy
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
DOI: | 10.1016/j.jallcom.2013.06.162 |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/33164 |
Resumo: | Nano-quasicrystalline Al–Fe–Cr based alloys produced by rapid solidification processes exhibit high strength at elevated temperatures. Nevertheless, the quasicrystalline particles in these systems become unstable at high temperature limiting the industrial applications. In early works, it was observed that the use of Nb or Ta increases the stability of the Al–Fe–Cr quasicrystalline phase delaying the microstructural transformation to higher temperatures. Thus, these nano-quasicrystalline Al-based alloys have become promising new high strength material to be used at elevated temperatures in the automotive and aero-nautical industries. In previous works, nano-quasicrystalline Al–Fe–Cr–Nb based alloys were obtained by rapid solidification using the melt-spinning technique. In order to obtain bulk alloys for industrial applications other fabrication routes such as powder production by gas atomization followed by compaction and extrusion are required. In the present work, the production of Al–Fe–Cr–Nb based alloys by powder atomization at laboratory scale was investigated. The powders obtained were sieved in different ranges of sizes and the microstructures were characterised by means of X-ray diffraction, scanning and transmission electron microscopy, and energy dispersive of X-ray analysis. Mechanical properties have been measured by compression tests at room temperature and at 250 C. It was observed that a very high temperature is required to produce these alloys by gas atomization; the icosahedral quasicrystalline phase can be retained after the atomization in powder sizes typically under 75 lm, and also after the extrusion at 375 C. The extruded bars were able to retain a very high strength at elevated temperature, around 60% of the yield stress at room temperature, in contrast with the 10–30% typically obtained for many commercial Al alloys |
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Peres, Maurício MirdhauiAudebert, Fernando E.Galano, Marina L.Rios, C. TriveñoKasama, H.Kiminami, Claudio ShyintiBotta, Walter JoseBolfarini, Claudemiro2021-08-16T14:28:19Z2021-08-16T14:28:19Z2013-11-15AUDEBERT, F.; GALANO, M.; RIOS, C. Triveño; KASAMA, H.; PERES, M.; KIMINAMI, C.; BOTTA, W.J.; BOLFARINI, C.. Nanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgy. Journal Of Alloys And Compounds, [S.L.], v. 577, p. 650-657, nov. 2013. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0925838813015600?via%3Dihub. Acesso em: 02 mar. 2021. http://dx.doi.org/10.1016/j.jallcom.2013.06.162.0925-8388https://repositorio.ufrn.br/handle/123456789/3316410.1016/j.jallcom.2013.06.162ElsevierAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessAluminium alloysQuasicrystalsRapid solidificationPowder metallurgyNanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgyinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleNano-quasicrystalline Al–Fe–Cr based alloys produced by rapid solidification processes exhibit high strength at elevated temperatures. Nevertheless, the quasicrystalline particles in these systems become unstable at high temperature limiting the industrial applications. In early works, it was observed that the use of Nb or Ta increases the stability of the Al–Fe–Cr quasicrystalline phase delaying the microstructural transformation to higher temperatures. Thus, these nano-quasicrystalline Al-based alloys have become promising new high strength material to be used at elevated temperatures in the automotive and aero-nautical industries. In previous works, nano-quasicrystalline Al–Fe–Cr–Nb based alloys were obtained by rapid solidification using the melt-spinning technique. In order to obtain bulk alloys for industrial applications other fabrication routes such as powder production by gas atomization followed by compaction and extrusion are required. In the present work, the production of Al–Fe–Cr–Nb based alloys by powder atomization at laboratory scale was investigated. The powders obtained were sieved in different ranges of sizes and the microstructures were characterised by means of X-ray diffraction, scanning and transmission electron microscopy, and energy dispersive of X-ray analysis. Mechanical properties have been measured by compression tests at room temperature and at 250 C. It was observed that a very high temperature is required to produce these alloys by gas atomization; the icosahedral quasicrystalline phase can be retained after the atomization in powder sizes typically under 75 lm, and also after the extrusion at 375 C. The extruded bars were able to retain a very high strength at elevated temperature, around 60% of the yield stress at room temperature, in contrast with the 10–30% typically obtained for many commercial Al alloysengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALNanoquasicrystallineAlloysProduced_PERES_2013.pdfNanoquasicrystallineAlloysProduced_PERES_2013.pdfapplication/pdf1635189https://repositorio.ufrn.br/bitstream/123456789/33164/1/NanoquasicrystallineAlloysProduced_PERES_2013.pdfa690e809e1cee30e3486c421d8f6b099MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/33164/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/33164/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52123456789/331642021-08-16 11:28:20.184oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-08-16T14:28:20Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Nanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgy |
title |
Nanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgy |
spellingShingle |
Nanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgy Peres, Maurício Mirdhaui Aluminium alloys Quasicrystals Rapid solidification Powder metallurgy |
title_short |
Nanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgy |
title_full |
Nanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgy |
title_fullStr |
Nanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgy |
title_full_unstemmed |
Nanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgy |
title_sort |
Nanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgy |
author |
Peres, Maurício Mirdhaui |
author_facet |
Peres, Maurício Mirdhaui Audebert, Fernando E. Galano, Marina L. Rios, C. Triveño Kasama, H. Kiminami, Claudio Shyinti Botta, Walter Jose Bolfarini, Claudemiro |
author_role |
author |
author2 |
Audebert, Fernando E. Galano, Marina L. Rios, C. Triveño Kasama, H. Kiminami, Claudio Shyinti Botta, Walter Jose Bolfarini, Claudemiro |
author2_role |
author author author author author author author |
dc.contributor.author.fl_str_mv |
Peres, Maurício Mirdhaui Audebert, Fernando E. Galano, Marina L. Rios, C. Triveño Kasama, H. Kiminami, Claudio Shyinti Botta, Walter Jose Bolfarini, Claudemiro |
dc.subject.por.fl_str_mv |
Aluminium alloys Quasicrystals Rapid solidification Powder metallurgy |
topic |
Aluminium alloys Quasicrystals Rapid solidification Powder metallurgy |
description |
Nano-quasicrystalline Al–Fe–Cr based alloys produced by rapid solidification processes exhibit high strength at elevated temperatures. Nevertheless, the quasicrystalline particles in these systems become unstable at high temperature limiting the industrial applications. In early works, it was observed that the use of Nb or Ta increases the stability of the Al–Fe–Cr quasicrystalline phase delaying the microstructural transformation to higher temperatures. Thus, these nano-quasicrystalline Al-based alloys have become promising new high strength material to be used at elevated temperatures in the automotive and aero-nautical industries. In previous works, nano-quasicrystalline Al–Fe–Cr–Nb based alloys were obtained by rapid solidification using the melt-spinning technique. In order to obtain bulk alloys for industrial applications other fabrication routes such as powder production by gas atomization followed by compaction and extrusion are required. In the present work, the production of Al–Fe–Cr–Nb based alloys by powder atomization at laboratory scale was investigated. The powders obtained were sieved in different ranges of sizes and the microstructures were characterised by means of X-ray diffraction, scanning and transmission electron microscopy, and energy dispersive of X-ray analysis. Mechanical properties have been measured by compression tests at room temperature and at 250 C. It was observed that a very high temperature is required to produce these alloys by gas atomization; the icosahedral quasicrystalline phase can be retained after the atomization in powder sizes typically under 75 lm, and also after the extrusion at 375 C. The extruded bars were able to retain a very high strength at elevated temperature, around 60% of the yield stress at room temperature, in contrast with the 10–30% typically obtained for many commercial Al alloys |
publishDate |
2013 |
dc.date.issued.fl_str_mv |
2013-11-15 |
dc.date.accessioned.fl_str_mv |
2021-08-16T14:28:19Z |
dc.date.available.fl_str_mv |
2021-08-16T14:28:19Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
AUDEBERT, F.; GALANO, M.; RIOS, C. Triveño; KASAMA, H.; PERES, M.; KIMINAMI, C.; BOTTA, W.J.; BOLFARINI, C.. Nanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgy. Journal Of Alloys And Compounds, [S.L.], v. 577, p. 650-657, nov. 2013. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0925838813015600?via%3Dihub. Acesso em: 02 mar. 2021. http://dx.doi.org/10.1016/j.jallcom.2013.06.162. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/33164 |
dc.identifier.issn.none.fl_str_mv |
0925-8388 |
dc.identifier.doi.none.fl_str_mv |
10.1016/j.jallcom.2013.06.162 |
identifier_str_mv |
AUDEBERT, F.; GALANO, M.; RIOS, C. Triveño; KASAMA, H.; PERES, M.; KIMINAMI, C.; BOTTA, W.J.; BOLFARINI, C.. Nanoquasicrystalline Al–Fe–Cr–Nb alloys produced by powder metallurgy. Journal Of Alloys And Compounds, [S.L.], v. 577, p. 650-657, nov. 2013. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0925838813015600?via%3Dihub. Acesso em: 02 mar. 2021. http://dx.doi.org/10.1016/j.jallcom.2013.06.162. 0925-8388 10.1016/j.jallcom.2013.06.162 |
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https://repositorio.ufrn.br/handle/123456789/33164 |
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Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ |
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openAccess |
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Elsevier |
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Elsevier |
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