Themo-oxidative stability ald cold flow properties of babassu biodiesel by PDSC ans TMDSC techniques
Autor(a) principal: | |
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Data de Publicação: | 2009 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/30366 |
Resumo: | The babassu (Orbignya PhalerataMart.) biodiesel has lauric esters as main constituents, resulting in high oxidative stability and low cloud and freezing points. In order to reduce these side effects, the saturated ethyl esters content was reduced by means of winterization process. The TMDSC and PDSC techniques were used to verify the thermal and oxidative stabilities of the ethyl babassu biodiesel. During the heating stage, the winterized solid phase of ethyl esters presented an endothermic transition associated to the solidification process. This behavior was not observed for the liquid winterized FAEE, confirming the efficiency of the winterization process |
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Bicudo, Tatiana de CamposSantos, N. A.Santos, J. R. J.Sinfrônio, F. S. M.Santos, I. M. G.Antoniosi Filho, N. R.Fernandes Jr, V. J.Souza, A. G.2020-10-09T19:41:42Z2020-10-09T19:41:42Z2009-04-27SANTOS, N. A.; SANTOS, J. R. J.; SINFRÔNIO, F. S. M.; BICUDO, T. C.; SANTOS, I. M. G.; ANTONIOSI FILHO, N. R.; FERNANDES, V. J.; SOUZA, A. G.. Thermo-oxidative stability and cold flow properties of babassu biodiesel by PDSC and TMDSC techniques. Journal Of Thermal Analysis And Calorimetry, [S.L.], v. 97, n. 2, p. 611-614, 27 abr. 2009. Disponível em: https://link.springer.com/article/10.1007%2Fs10973-008-9719-2. Acesso em: 08 set. 2020. http://dx.doi.org/10.1007/s10973-008-9719-21572-8943https://repositorio.ufrn.br/handle/123456789/3036610.1007/s10973-008-9719-2SpringerAttribution-NonCommercial 3.0 Brazilhttp://creativecommons.org/licenses/by-nc/3.0/br/info:eu-repo/semantics/openAccessBiodieselPDSCTMDSCThemo-oxidative stability ald cold flow properties of babassu biodiesel by PDSC ans TMDSC techniquesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleThe babassu (Orbignya PhalerataMart.) biodiesel has lauric esters as main constituents, resulting in high oxidative stability and low cloud and freezing points. In order to reduce these side effects, the saturated ethyl esters content was reduced by means of winterization process. The TMDSC and PDSC techniques were used to verify the thermal and oxidative stabilities of the ethyl babassu biodiesel. During the heating stage, the winterized solid phase of ethyl esters presented an endothermic transition associated to the solidification process. This behavior was not observed for the liquid winterized FAEE, confirming the efficiency of the winterization processengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALThermooxidativeStabilityBicudo2009.pdfThermooxidativeStabilityBicudo2009.pdfapplication/pdf209827https://repositorio.ufrn.br/bitstream/123456789/30366/1/ThermooxidativeStabilityBicudo2009.pdfe58782e017e82eb7655b16f46b0a3c74MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8920https://repositorio.ufrn.br/bitstream/123456789/30366/2/license_rdf728dfda2fa81b274c619d08d1dfc1a03MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/30366/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53TEXTThermooxidativeStabilityBicudo2009.pdf.txtThermooxidativeStabilityBicudo2009.pdf.txtExtracted texttext/plain13108https://repositorio.ufrn.br/bitstream/123456789/30366/4/ThermooxidativeStabilityBicudo2009.pdf.txtcedb3e42125f8a64b9c5a888c54f9a9fMD54THUMBNAILThermooxidativeStabilityBicudo2009.pdf.jpgThermooxidativeStabilityBicudo2009.pdf.jpgGenerated Thumbnailimage/jpeg1695https://repositorio.ufrn.br/bitstream/123456789/30366/5/ThermooxidativeStabilityBicudo2009.pdf.jpgb9ce188e07c39691ce4707edac681aacMD55123456789/303662020-10-11 04:38:25.462oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2020-10-11T07:38:25Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Themo-oxidative stability ald cold flow properties of babassu biodiesel by PDSC ans TMDSC techniques |
title |
Themo-oxidative stability ald cold flow properties of babassu biodiesel by PDSC ans TMDSC techniques |
spellingShingle |
Themo-oxidative stability ald cold flow properties of babassu biodiesel by PDSC ans TMDSC techniques Bicudo, Tatiana de Campos Biodiesel PDSC TMDSC |
title_short |
Themo-oxidative stability ald cold flow properties of babassu biodiesel by PDSC ans TMDSC techniques |
title_full |
Themo-oxidative stability ald cold flow properties of babassu biodiesel by PDSC ans TMDSC techniques |
title_fullStr |
Themo-oxidative stability ald cold flow properties of babassu biodiesel by PDSC ans TMDSC techniques |
title_full_unstemmed |
Themo-oxidative stability ald cold flow properties of babassu biodiesel by PDSC ans TMDSC techniques |
title_sort |
Themo-oxidative stability ald cold flow properties of babassu biodiesel by PDSC ans TMDSC techniques |
author |
Bicudo, Tatiana de Campos |
author_facet |
Bicudo, Tatiana de Campos Santos, N. A. Santos, J. R. J. Sinfrônio, F. S. M. Santos, I. M. G. Antoniosi Filho, N. R. Fernandes Jr, V. J. Souza, A. G. |
author_role |
author |
author2 |
Santos, N. A. Santos, J. R. J. Sinfrônio, F. S. M. Santos, I. M. G. Antoniosi Filho, N. R. Fernandes Jr, V. J. Souza, A. G. |
author2_role |
author author author author author author author |
dc.contributor.author.fl_str_mv |
Bicudo, Tatiana de Campos Santos, N. A. Santos, J. R. J. Sinfrônio, F. S. M. Santos, I. M. G. Antoniosi Filho, N. R. Fernandes Jr, V. J. Souza, A. G. |
dc.subject.por.fl_str_mv |
Biodiesel PDSC TMDSC |
topic |
Biodiesel PDSC TMDSC |
description |
The babassu (Orbignya PhalerataMart.) biodiesel has lauric esters as main constituents, resulting in high oxidative stability and low cloud and freezing points. In order to reduce these side effects, the saturated ethyl esters content was reduced by means of winterization process. The TMDSC and PDSC techniques were used to verify the thermal and oxidative stabilities of the ethyl babassu biodiesel. During the heating stage, the winterized solid phase of ethyl esters presented an endothermic transition associated to the solidification process. This behavior was not observed for the liquid winterized FAEE, confirming the efficiency of the winterization process |
publishDate |
2009 |
dc.date.issued.fl_str_mv |
2009-04-27 |
dc.date.accessioned.fl_str_mv |
2020-10-09T19:41:42Z |
dc.date.available.fl_str_mv |
2020-10-09T19:41:42Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
SANTOS, N. A.; SANTOS, J. R. J.; SINFRÔNIO, F. S. M.; BICUDO, T. C.; SANTOS, I. M. G.; ANTONIOSI FILHO, N. R.; FERNANDES, V. J.; SOUZA, A. G.. Thermo-oxidative stability and cold flow properties of babassu biodiesel by PDSC and TMDSC techniques. Journal Of Thermal Analysis And Calorimetry, [S.L.], v. 97, n. 2, p. 611-614, 27 abr. 2009. Disponível em: https://link.springer.com/article/10.1007%2Fs10973-008-9719-2. Acesso em: 08 set. 2020. http://dx.doi.org/10.1007/s10973-008-9719-2 |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/30366 |
dc.identifier.issn.none.fl_str_mv |
1572-8943 |
dc.identifier.doi.none.fl_str_mv |
10.1007/s10973-008-9719-2 |
identifier_str_mv |
SANTOS, N. A.; SANTOS, J. R. J.; SINFRÔNIO, F. S. M.; BICUDO, T. C.; SANTOS, I. M. G.; ANTONIOSI FILHO, N. R.; FERNANDES, V. J.; SOUZA, A. G.. Thermo-oxidative stability and cold flow properties of babassu biodiesel by PDSC and TMDSC techniques. Journal Of Thermal Analysis And Calorimetry, [S.L.], v. 97, n. 2, p. 611-614, 27 abr. 2009. Disponível em: https://link.springer.com/article/10.1007%2Fs10973-008-9719-2. Acesso em: 08 set. 2020. http://dx.doi.org/10.1007/s10973-008-9719-2 1572-8943 10.1007/s10973-008-9719-2 |
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https://repositorio.ufrn.br/handle/123456789/30366 |
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eng |
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eng |
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Attribution-NonCommercial 3.0 Brazil http://creativecommons.org/licenses/by-nc/3.0/br/ info:eu-repo/semantics/openAccess |
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Attribution-NonCommercial 3.0 Brazil http://creativecommons.org/licenses/by-nc/3.0/br/ |
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openAccess |
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Springer |
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Springer |
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