Thermal study of CoxZn7-xSb2O12 spinel obtained by pechini method using different alcohols

• Autor(a) principal: Gouveia, Deiby Santos
• Data de Publicação: 2004
• Outros Autores: Rosenhaim, R., Maurera, M. A. M. A. de, Lima, Severino Jackson Guedes, Paskocimas, Carlos Alberto, Silva, Elson Longo da, Souza, Antônio Gouveia de, Santos, Ieda Maria Garcia dos
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Institucional da UFRN
• DOI: 10.1023/b:jtan.0000027132.98057.ac
• Texto Completo: https://repositorio.ufrn.br/handle/123456789/32296
• topic: DTA; Pechini; Spinel; Thermogravimetry

With the aim of obtaining materials with applications in pigments, CoxZn7–xSb2O12 spinels were synthesized using the Pechini method. This method consists in the formation of a polymeric net, where the metallic cations are homogeneously distributed. In this work, two types of alcohol (ethyl glycol and ethylene glycol) were used for the synthesis of a zinc antimoniate spinel, CoxZn7–xSb2O12 (x=0–7). The materials were characterized by termogravimetry (TG) and differential thermal analysis (DTA). TG results indicated a decrease in total mass loss when cobalt was added to the solution substituting zinc, for samples prepared using the two different alcohols. Decomposition temperatures, obtained by TG and DTA, presented a decreasing behavior as cobalt was added to the material. In relation to the alcohols, all results indicated a better polymerization of the resin when ethylene glycol was used, being the most indicated one for cation immobilization. X-ray diffraction did not show differences between the two alcohols – both presented the spinel phase (Co, Zn)2.33Sb0.67O4. Samples with higher quantity of cobalt also presented ilmenite phase (Co, Zn)Sb2O6