Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida

Detalhes bibliográficos
Autor(a) principal: Menezes, Nadja Nayara Fonseca de
Data de Publicação: 2017
Tipo de documento: Trabalho de conclusão de curso
Idioma: por
Título da fonte: Repositório Institucional da UFRN
Texto Completo: https://repositorio.ufrn.br/handle/123456789/38709
Resumo: Water produced is the most common and the largest by-product of the oil industry and its non-treatment leads to possible operational and environmental damage. It is an effluent of complex composition, containing, among other pollutants, heavy metals, sulfides and emulsion oil. The most common and effective treatment is by Dissolved Air Flotation (DAF), which has a preliminary stage, called flocculation, where is used a polyelectrolyte (or flocculant). The polyelectrolyte ensures optimum flocculation through the neutralization of the particles’ charges, present on the effluent, making possible the agglutination of these particles and their consequent extraction. A natural polyelectrolyte alternative is obtained through the seeds of Moringa oleifera, which causes less environmental and human health impacts. Moringa is a multifunctional plant, with varied applicability studies of all its parts. The oil extracted from its seeds, for example, has been studied as an alternative source for the production of biodiesel. This study, therefore, evaluated the impact of oil extraction on the coagulant activity of moringa seeds, as well as the efficiency of the removal of total oil and grease content (TOG) when using a natural flocculant like moringa seeds with oil (MCO) and without oil (MSO). The physical-chemical characterization of both seeds demonstrated that the oil extraction represents a considerable impact on its properties, such as isoelectric point (PI), pH, chemical composition and cationic protein concentration. The PI for the MCO was 4.8, while for the MSO it was 9.8. In the treatment trials of water produced by DAF, the MCO flocculant presented a higher concentration of the coagulant protein at pH 9.5, with a yield of 75.15 ± 1.04% in the removal of TOG. For MSO, this pH was 11, yield 56.36 ± 2.57%. The maximum efficiency obtained when using MCO was 78.25 ± 2.23%, at pH 4.8. With MSO, 77.58 ± 2.78% of TOG removal was achieved at a pH of 5.2.
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spelling Menezes, Nadja Nayara Fonseca deEmilianny Rafaely Batista MagalhãesSilva, Francinaldo Leite daSousa, Magna Angélica dos Santos Bezerra2017-12-08T11:27:05Z2021-09-27T12:19:20Z2017-12-08T11:27:05Z2021-09-27T12:19:20Z2017-12-062012941027MENEZES, Nadja Nayara Fonseca de. Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida. 2017. 42f. Trabalho de Conclusão de Curso (Graduação em Engenharia Química), Universidade Federal do Rio Grande do Norte, Natal, 2017https://repositorio.ufrn.br/handle/123456789/38709Water produced is the most common and the largest by-product of the oil industry and its non-treatment leads to possible operational and environmental damage. It is an effluent of complex composition, containing, among other pollutants, heavy metals, sulfides and emulsion oil. The most common and effective treatment is by Dissolved Air Flotation (DAF), which has a preliminary stage, called flocculation, where is used a polyelectrolyte (or flocculant). The polyelectrolyte ensures optimum flocculation through the neutralization of the particles’ charges, present on the effluent, making possible the agglutination of these particles and their consequent extraction. A natural polyelectrolyte alternative is obtained through the seeds of Moringa oleifera, which causes less environmental and human health impacts. Moringa is a multifunctional plant, with varied applicability studies of all its parts. The oil extracted from its seeds, for example, has been studied as an alternative source for the production of biodiesel. This study, therefore, evaluated the impact of oil extraction on the coagulant activity of moringa seeds, as well as the efficiency of the removal of total oil and grease content (TOG) when using a natural flocculant like moringa seeds with oil (MCO) and without oil (MSO). The physical-chemical characterization of both seeds demonstrated that the oil extraction represents a considerable impact on its properties, such as isoelectric point (PI), pH, chemical composition and cationic protein concentration. The PI for the MCO was 4.8, while for the MSO it was 9.8. In the treatment trials of water produced by DAF, the MCO flocculant presented a higher concentration of the coagulant protein at pH 9.5, with a yield of 75.15 ± 1.04% in the removal of TOG. For MSO, this pH was 11, yield 56.36 ± 2.57%. The maximum efficiency obtained when using MCO was 78.25 ± 2.23%, at pH 4.8. With MSO, 77.58 ± 2.78% of TOG removal was achieved at a pH of 5.2.A água produzida é o subproduto mais comum e de grande volume da indústria de petróleo e o seu não tratamento acarreta em possíveis danos operacionais e ambientais. É um efluente de composição complexa, contendo, dentre outros poluentes, metais pesados, sulfetos e óleo em emulsão. O tratamento mais comum e eficaz é o da flotação por ar dissolvido (FAD), que possui uma etapa preliminar, denominada floculação, na qual se utiliza um polieletrólito (ou floculante). O polieletrólito garante uma floculação ótima através da neutralização de cargas das partículas presentes no efluente, tornando possível a aglutinação dessas partículas e sua consequente extração. Uma alternativa de polieletrólito natural é o obtido através das sementes da Moringa oleifera, que causa menores impactos ambientais e à saúde humana. A moringa é uma planta multifuncional, com variados estudos de aplicabilidade de todas as suas partes constituintes. O óleo extraído de suas sementes, por exemplo, vem sendo estudando como fonte alternativa para a produção de biodiesel. Este trabalho, portanto, avaliou o impacto da extração do óleo na atividade coagulante das sementes de moringa, assim como a eficiência da remoção do teor de óleos e graxas (TOG) ao utilizar o floculante natural com sementes de moringa com óleo (MCO) e sem óleo (MSO). A caracterização físico-química de ambas as sementes demonstraram que a extração do óleo representa um impacto considerável em suas propriedades, como ponto isoelétrico (PI), pH, composição química e concentração da proteína catiônica. O PI para a MCO foi de 4,8, enquanto para a MSO foi de 9,8. Nos ensaios de tratamento de água produzida por FAD, o floculante com MCO apresentou uma maior concentração da proteína coagulante no pH de 9,5, com o rendimento de 75,15 ± 1,04 % na remoção de TOG. Para a MSO, esse pH foi o de 11, com rendimento de 56,36 ± 2,57 %. A eficiência máxima obtida, ao se utilizar MCO, foi de 78,25 ± 2,23 %, no pH 4,8. Já com MSO, atingiu-se 77,58 ± 2,78 % de remoção de TOG a um pH de 5,2.Universidade Federal do Rio Grande do NorteUFRNBrasilEngenharia Químicaágua produzidamoringa oleiferaflotaçãocoagulantetogproduced waterflotationcoagulantEngenharias.Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzidainfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/openAccessporreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNTEXTImpactodaextracao_Monografia.pdf.txtExtracted texttext/plain57445https://repositorio.ufrn.br/bitstream/123456789/38709/1/Impactodaextracao_Monografia.pdf.txtaf1e76bf6590f792a5486a16b806b746MD51LICENSElicense.txttext/plain756https://repositorio.ufrn.br/bitstream/123456789/38709/2/license.txta80a9cda2756d355b388cc443c3d8a43MD52ORIGINALImpactodaextracao_Monografia.pdfMonografiaapplication/pdf1245712https://repositorio.ufrn.br/bitstream/123456789/38709/3/Impactodaextracao_Monografia.pdfa54b73d80399060111bb9f31d7a8f4e9MD53123456789/387092021-09-27 09:19:20.867oai:https://repositorio.ufrn.br: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ório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-09-27T12:19:20Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false
dc.title.pr_BR.fl_str_mv Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida
title Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida
spellingShingle Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida
Menezes, Nadja Nayara Fonseca de
água produzida
moringa oleifera
flotação
coagulante
tog
produced water
flotation
coagulant
Engenharias.
title_short Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida
title_full Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida
title_fullStr Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida
title_full_unstemmed Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida
title_sort Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida
author Menezes, Nadja Nayara Fonseca de
author_facet Menezes, Nadja Nayara Fonseca de
author_role author
dc.contributor.referees1.none.fl_str_mv Silva, Francinaldo Leite da
dc.contributor.author.fl_str_mv Menezes, Nadja Nayara Fonseca de
dc.contributor.advisor-co1.fl_str_mv Emilianny Rafaely Batista Magalhães
dc.contributor.advisor1.fl_str_mv Sousa, Magna Angélica dos Santos Bezerra
contributor_str_mv Emilianny Rafaely Batista Magalhães
Sousa, Magna Angélica dos Santos Bezerra
dc.subject.pr_BR.fl_str_mv água produzida
moringa oleifera
flotação
coagulante
tog
produced water
flotation
coagulant
topic água produzida
moringa oleifera
flotação
coagulante
tog
produced water
flotation
coagulant
Engenharias.
dc.subject.cnpq.fl_str_mv Engenharias.
description Water produced is the most common and the largest by-product of the oil industry and its non-treatment leads to possible operational and environmental damage. It is an effluent of complex composition, containing, among other pollutants, heavy metals, sulfides and emulsion oil. The most common and effective treatment is by Dissolved Air Flotation (DAF), which has a preliminary stage, called flocculation, where is used a polyelectrolyte (or flocculant). The polyelectrolyte ensures optimum flocculation through the neutralization of the particles’ charges, present on the effluent, making possible the agglutination of these particles and their consequent extraction. A natural polyelectrolyte alternative is obtained through the seeds of Moringa oleifera, which causes less environmental and human health impacts. Moringa is a multifunctional plant, with varied applicability studies of all its parts. The oil extracted from its seeds, for example, has been studied as an alternative source for the production of biodiesel. This study, therefore, evaluated the impact of oil extraction on the coagulant activity of moringa seeds, as well as the efficiency of the removal of total oil and grease content (TOG) when using a natural flocculant like moringa seeds with oil (MCO) and without oil (MSO). The physical-chemical characterization of both seeds demonstrated that the oil extraction represents a considerable impact on its properties, such as isoelectric point (PI), pH, chemical composition and cationic protein concentration. The PI for the MCO was 4.8, while for the MSO it was 9.8. In the treatment trials of water produced by DAF, the MCO flocculant presented a higher concentration of the coagulant protein at pH 9.5, with a yield of 75.15 ± 1.04% in the removal of TOG. For MSO, this pH was 11, yield 56.36 ± 2.57%. The maximum efficiency obtained when using MCO was 78.25 ± 2.23%, at pH 4.8. With MSO, 77.58 ± 2.78% of TOG removal was achieved at a pH of 5.2.
publishDate 2017
dc.date.accessioned.fl_str_mv 2017-12-08T11:27:05Z
2021-09-27T12:19:20Z
dc.date.available.fl_str_mv 2017-12-08T11:27:05Z
2021-09-27T12:19:20Z
dc.date.issued.fl_str_mv 2017-12-06
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dc.identifier.citation.fl_str_mv MENEZES, Nadja Nayara Fonseca de. Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida. 2017. 42f. Trabalho de Conclusão de Curso (Graduação em Engenharia Química), Universidade Federal do Rio Grande do Norte, Natal, 2017
dc.identifier.uri.fl_str_mv https://repositorio.ufrn.br/handle/123456789/38709
identifier_str_mv 2012941027
MENEZES, Nadja Nayara Fonseca de. Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida. 2017. 42f. Trabalho de Conclusão de Curso (Graduação em Engenharia Química), Universidade Federal do Rio Grande do Norte, Natal, 2017
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dc.publisher.department.fl_str_mv Engenharia Química
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