Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Tipo de documento: | Trabalho de conclusão de curso |
Idioma: | por |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/38709 |
Resumo: | Water produced is the most common and the largest by-product of the oil industry and its non-treatment leads to possible operational and environmental damage. It is an effluent of complex composition, containing, among other pollutants, heavy metals, sulfides and emulsion oil. The most common and effective treatment is by Dissolved Air Flotation (DAF), which has a preliminary stage, called flocculation, where is used a polyelectrolyte (or flocculant). The polyelectrolyte ensures optimum flocculation through the neutralization of the particles’ charges, present on the effluent, making possible the agglutination of these particles and their consequent extraction. A natural polyelectrolyte alternative is obtained through the seeds of Moringa oleifera, which causes less environmental and human health impacts. Moringa is a multifunctional plant, with varied applicability studies of all its parts. The oil extracted from its seeds, for example, has been studied as an alternative source for the production of biodiesel. This study, therefore, evaluated the impact of oil extraction on the coagulant activity of moringa seeds, as well as the efficiency of the removal of total oil and grease content (TOG) when using a natural flocculant like moringa seeds with oil (MCO) and without oil (MSO). The physical-chemical characterization of both seeds demonstrated that the oil extraction represents a considerable impact on its properties, such as isoelectric point (PI), pH, chemical composition and cationic protein concentration. The PI for the MCO was 4.8, while for the MSO it was 9.8. In the treatment trials of water produced by DAF, the MCO flocculant presented a higher concentration of the coagulant protein at pH 9.5, with a yield of 75.15 ± 1.04% in the removal of TOG. For MSO, this pH was 11, yield 56.36 ± 2.57%. The maximum efficiency obtained when using MCO was 78.25 ± 2.23%, at pH 4.8. With MSO, 77.58 ± 2.78% of TOG removal was achieved at a pH of 5.2. |
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Menezes, Nadja Nayara Fonseca deEmilianny Rafaely Batista MagalhãesSilva, Francinaldo Leite daSousa, Magna Angélica dos Santos Bezerra2017-12-08T11:27:05Z2021-09-27T12:19:20Z2017-12-08T11:27:05Z2021-09-27T12:19:20Z2017-12-062012941027MENEZES, Nadja Nayara Fonseca de. Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida. 2017. 42f. Trabalho de Conclusão de Curso (Graduação em Engenharia Química), Universidade Federal do Rio Grande do Norte, Natal, 2017https://repositorio.ufrn.br/handle/123456789/38709Water produced is the most common and the largest by-product of the oil industry and its non-treatment leads to possible operational and environmental damage. It is an effluent of complex composition, containing, among other pollutants, heavy metals, sulfides and emulsion oil. The most common and effective treatment is by Dissolved Air Flotation (DAF), which has a preliminary stage, called flocculation, where is used a polyelectrolyte (or flocculant). The polyelectrolyte ensures optimum flocculation through the neutralization of the particles’ charges, present on the effluent, making possible the agglutination of these particles and their consequent extraction. A natural polyelectrolyte alternative is obtained through the seeds of Moringa oleifera, which causes less environmental and human health impacts. Moringa is a multifunctional plant, with varied applicability studies of all its parts. The oil extracted from its seeds, for example, has been studied as an alternative source for the production of biodiesel. This study, therefore, evaluated the impact of oil extraction on the coagulant activity of moringa seeds, as well as the efficiency of the removal of total oil and grease content (TOG) when using a natural flocculant like moringa seeds with oil (MCO) and without oil (MSO). The physical-chemical characterization of both seeds demonstrated that the oil extraction represents a considerable impact on its properties, such as isoelectric point (PI), pH, chemical composition and cationic protein concentration. The PI for the MCO was 4.8, while for the MSO it was 9.8. In the treatment trials of water produced by DAF, the MCO flocculant presented a higher concentration of the coagulant protein at pH 9.5, with a yield of 75.15 ± 1.04% in the removal of TOG. For MSO, this pH was 11, yield 56.36 ± 2.57%. The maximum efficiency obtained when using MCO was 78.25 ± 2.23%, at pH 4.8. With MSO, 77.58 ± 2.78% of TOG removal was achieved at a pH of 5.2.A água produzida é o subproduto mais comum e de grande volume da indústria de petróleo e o seu não tratamento acarreta em possíveis danos operacionais e ambientais. É um efluente de composição complexa, contendo, dentre outros poluentes, metais pesados, sulfetos e óleo em emulsão. O tratamento mais comum e eficaz é o da flotação por ar dissolvido (FAD), que possui uma etapa preliminar, denominada floculação, na qual se utiliza um polieletrólito (ou floculante). O polieletrólito garante uma floculação ótima através da neutralização de cargas das partículas presentes no efluente, tornando possível a aglutinação dessas partículas e sua consequente extração. Uma alternativa de polieletrólito natural é o obtido através das sementes da Moringa oleifera, que causa menores impactos ambientais e à saúde humana. A moringa é uma planta multifuncional, com variados estudos de aplicabilidade de todas as suas partes constituintes. O óleo extraído de suas sementes, por exemplo, vem sendo estudando como fonte alternativa para a produção de biodiesel. Este trabalho, portanto, avaliou o impacto da extração do óleo na atividade coagulante das sementes de moringa, assim como a eficiência da remoção do teor de óleos e graxas (TOG) ao utilizar o floculante natural com sementes de moringa com óleo (MCO) e sem óleo (MSO). A caracterização físico-química de ambas as sementes demonstraram que a extração do óleo representa um impacto considerável em suas propriedades, como ponto isoelétrico (PI), pH, composição química e concentração da proteína catiônica. O PI para a MCO foi de 4,8, enquanto para a MSO foi de 9,8. Nos ensaios de tratamento de água produzida por FAD, o floculante com MCO apresentou uma maior concentração da proteína coagulante no pH de 9,5, com o rendimento de 75,15 ± 1,04 % na remoção de TOG. Para a MSO, esse pH foi o de 11, com rendimento de 56,36 ± 2,57 %. A eficiência máxima obtida, ao se utilizar MCO, foi de 78,25 ± 2,23 %, no pH 4,8. Já com MSO, atingiu-se 77,58 ± 2,78 % de remoção de TOG a um pH de 5,2.Universidade Federal do Rio Grande do NorteUFRNBrasilEngenharia Químicaágua produzidamoringa oleiferaflotaçãocoagulantetogproduced waterflotationcoagulantEngenharias.Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzidainfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/openAccessporreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNTEXTImpactodaextracao_Monografia.pdf.txtExtracted texttext/plain57445https://repositorio.ufrn.br/bitstream/123456789/38709/1/Impactodaextracao_Monografia.pdf.txtaf1e76bf6590f792a5486a16b806b746MD51LICENSElicense.txttext/plain756https://repositorio.ufrn.br/bitstream/123456789/38709/2/license.txta80a9cda2756d355b388cc443c3d8a43MD52ORIGINALImpactodaextracao_Monografia.pdfMonografiaapplication/pdf1245712https://repositorio.ufrn.br/bitstream/123456789/38709/3/Impactodaextracao_Monografia.pdfa54b73d80399060111bb9f31d7a8f4e9MD53123456789/387092021-09-27 09:19:20.867oai:https://repositorio.ufrn.br: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ório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-09-27T12:19:20Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pr_BR.fl_str_mv |
Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida |
title |
Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida |
spellingShingle |
Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida Menezes, Nadja Nayara Fonseca de água produzida moringa oleifera flotação coagulante tog produced water flotation coagulant Engenharias. |
title_short |
Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida |
title_full |
Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida |
title_fullStr |
Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida |
title_full_unstemmed |
Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida |
title_sort |
Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida |
author |
Menezes, Nadja Nayara Fonseca de |
author_facet |
Menezes, Nadja Nayara Fonseca de |
author_role |
author |
dc.contributor.referees1.none.fl_str_mv |
Silva, Francinaldo Leite da |
dc.contributor.author.fl_str_mv |
Menezes, Nadja Nayara Fonseca de |
dc.contributor.advisor-co1.fl_str_mv |
Emilianny Rafaely Batista Magalhães |
dc.contributor.advisor1.fl_str_mv |
Sousa, Magna Angélica dos Santos Bezerra |
contributor_str_mv |
Emilianny Rafaely Batista Magalhães Sousa, Magna Angélica dos Santos Bezerra |
dc.subject.pr_BR.fl_str_mv |
água produzida moringa oleifera flotação coagulante tog produced water flotation coagulant |
topic |
água produzida moringa oleifera flotação coagulante tog produced water flotation coagulant Engenharias. |
dc.subject.cnpq.fl_str_mv |
Engenharias. |
description |
Water produced is the most common and the largest by-product of the oil industry and its non-treatment leads to possible operational and environmental damage. It is an effluent of complex composition, containing, among other pollutants, heavy metals, sulfides and emulsion oil. The most common and effective treatment is by Dissolved Air Flotation (DAF), which has a preliminary stage, called flocculation, where is used a polyelectrolyte (or flocculant). The polyelectrolyte ensures optimum flocculation through the neutralization of the particles’ charges, present on the effluent, making possible the agglutination of these particles and their consequent extraction. A natural polyelectrolyte alternative is obtained through the seeds of Moringa oleifera, which causes less environmental and human health impacts. Moringa is a multifunctional plant, with varied applicability studies of all its parts. The oil extracted from its seeds, for example, has been studied as an alternative source for the production of biodiesel. This study, therefore, evaluated the impact of oil extraction on the coagulant activity of moringa seeds, as well as the efficiency of the removal of total oil and grease content (TOG) when using a natural flocculant like moringa seeds with oil (MCO) and without oil (MSO). The physical-chemical characterization of both seeds demonstrated that the oil extraction represents a considerable impact on its properties, such as isoelectric point (PI), pH, chemical composition and cationic protein concentration. The PI for the MCO was 4.8, while for the MSO it was 9.8. In the treatment trials of water produced by DAF, the MCO flocculant presented a higher concentration of the coagulant protein at pH 9.5, with a yield of 75.15 ± 1.04% in the removal of TOG. For MSO, this pH was 11, yield 56.36 ± 2.57%. The maximum efficiency obtained when using MCO was 78.25 ± 2.23%, at pH 4.8. With MSO, 77.58 ± 2.78% of TOG removal was achieved at a pH of 5.2. |
publishDate |
2017 |
dc.date.accessioned.fl_str_mv |
2017-12-08T11:27:05Z 2021-09-27T12:19:20Z |
dc.date.available.fl_str_mv |
2017-12-08T11:27:05Z 2021-09-27T12:19:20Z |
dc.date.issued.fl_str_mv |
2017-12-06 |
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info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/bachelorThesis |
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bachelorThesis |
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publishedVersion |
dc.identifier.pr_BR.fl_str_mv |
2012941027 |
dc.identifier.citation.fl_str_mv |
MENEZES, Nadja Nayara Fonseca de. Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida. 2017. 42f. Trabalho de Conclusão de Curso (Graduação em Engenharia Química), Universidade Federal do Rio Grande do Norte, Natal, 2017 |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/38709 |
identifier_str_mv |
2012941027 MENEZES, Nadja Nayara Fonseca de. Impacto da extração do óleo na atividade coagulante das sementes de moringa oleifera no tratamento de água produzida. 2017. 42f. Trabalho de Conclusão de Curso (Graduação em Engenharia Química), Universidade Federal do Rio Grande do Norte, Natal, 2017 |
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Universidade Federal do Rio Grande do Norte |
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Brasil |
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Engenharia Química |
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Universidade Federal do Rio Grande do Norte |
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