Effect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blends

Detalhes bibliográficos
Autor(a) principal: Ito, Edson Noriyuki
Data de Publicação: 2018
Outros Autores: Reinaldo, Juciklécia da Silva, Pereira, Laurenice Martins, Silva, Erik dos Santos, Ueki, Marcelo Massayoshi
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRN
Texto Completo: https://repositorio.ufrn.br/handle/123456789/41542
Resumo: It was investigated the influence of chemical structure on the linear viscoelastic rheological behavior of polymer blends comprising acrylic and styrenic polymers. Fourier transform infrared spectroscopy revealed a different bands characteristic of the chemical structures of the polymers. The chemical compositions of the styrenic co- polymers contain acrylonitrile at levels of 25 and 21%, respectively, which are within the miscibility window for PMMA/SAN and PMMA/ABS blends. Differential scanning calorimetry revealed the glass transition temperature for the polymers and for the elastomeric phase present in an elastomeric-particle-containing poly (methyl methacrylate) that are different to that of the elastomeric phase of ABS. The rheological data obtained at low frequencies in the linear viscoelasticity region, revealed significant changes in the rheological behavior of acrylic homopolymer, when compared to an acrylic polymer containing elastomeric particles (core-shell type). It was possible to indicate the miscibility of polymer blends by means of the linear viscoelastic rheological behavior
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spelling Ito, Edson NoriyukiReinaldo, Juciklécia da SilvaPereira, Laurenice MartinsSilva, Erik dos SantosUeki, Marcelo Massayoshi2021-10-04T18:34:06Z2021-10-04T18:34:06Z2018-05REINALDO, Juciklécia S.; PEREIRA, Laurenice Martins; SILVA, Erik dos Santos; UEKI, Marcelo M.; ITO, Edson N. Effect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blends. Polymer Testing, [S.L.], v. 67, p. 257-265, maio 2018. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0142941818300412?via%3Dihub. Acesso em: 04 jan. 2021. http://dx.doi.org/10.1016/j.polymertesting.2018.03.013.0142-9418https://repositorio.ufrn.br/handle/123456789/4154210.1016/j.polymertesting.2018.03.013ElsevierAttribution-NonCommercial-NoDerivs 3.0 Brazilhttp://creativecommons.org/licenses/by-nc-nd/3.0/br/info:eu-repo/semantics/openAccessPolymer blendsAcrilicStyrenicLinear viscoelasticityCore-shellEffect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blendsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleIt was investigated the influence of chemical structure on the linear viscoelastic rheological behavior of polymer blends comprising acrylic and styrenic polymers. Fourier transform infrared spectroscopy revealed a different bands characteristic of the chemical structures of the polymers. The chemical compositions of the styrenic co- polymers contain acrylonitrile at levels of 25 and 21%, respectively, which are within the miscibility window for PMMA/SAN and PMMA/ABS blends. Differential scanning calorimetry revealed the glass transition temperature for the polymers and for the elastomeric phase present in an elastomeric-particle-containing poly (methyl methacrylate) that are different to that of the elastomeric phase of ABS. The rheological data obtained at low frequencies in the linear viscoelasticity region, revealed significant changes in the rheological behavior of acrylic homopolymer, when compared to an acrylic polymer containing elastomeric particles (core-shell type). It was possible to indicate the miscibility of polymer blends by means of the linear viscoelastic rheological behaviorengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALEffectChemicalStructure_ITO_2018.pdfEffectChemicalStructure_ITO_2018.pdfapplication/pdf1140789https://repositorio.ufrn.br/bitstream/123456789/41542/1/EffectChemicalStructure_ITO_2018.pdfc0450c7e5f9199a5cde6db3989d11cb7MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8811https://repositorio.ufrn.br/bitstream/123456789/41542/2/license_rdfe39d27027a6cc9cb039ad269a5db8e34MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/41542/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53123456789/415422021-10-04 15:34:07.268oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-10-04T18:34:07Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false
dc.title.pt_BR.fl_str_mv Effect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blends
title Effect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blends
spellingShingle Effect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blends
Ito, Edson Noriyuki
Polymer blends
Acrilic
Styrenic
Linear viscoelasticity
Core-shell
title_short Effect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blends
title_full Effect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blends
title_fullStr Effect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blends
title_full_unstemmed Effect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blends
title_sort Effect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blends
author Ito, Edson Noriyuki
author_facet Ito, Edson Noriyuki
Reinaldo, Juciklécia da Silva
Pereira, Laurenice Martins
Silva, Erik dos Santos
Ueki, Marcelo Massayoshi
author_role author
author2 Reinaldo, Juciklécia da Silva
Pereira, Laurenice Martins
Silva, Erik dos Santos
Ueki, Marcelo Massayoshi
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Ito, Edson Noriyuki
Reinaldo, Juciklécia da Silva
Pereira, Laurenice Martins
Silva, Erik dos Santos
Ueki, Marcelo Massayoshi
dc.subject.por.fl_str_mv Polymer blends
Acrilic
Styrenic
Linear viscoelasticity
Core-shell
topic Polymer blends
Acrilic
Styrenic
Linear viscoelasticity
Core-shell
description It was investigated the influence of chemical structure on the linear viscoelastic rheological behavior of polymer blends comprising acrylic and styrenic polymers. Fourier transform infrared spectroscopy revealed a different bands characteristic of the chemical structures of the polymers. The chemical compositions of the styrenic co- polymers contain acrylonitrile at levels of 25 and 21%, respectively, which are within the miscibility window for PMMA/SAN and PMMA/ABS blends. Differential scanning calorimetry revealed the glass transition temperature for the polymers and for the elastomeric phase present in an elastomeric-particle-containing poly (methyl methacrylate) that are different to that of the elastomeric phase of ABS. The rheological data obtained at low frequencies in the linear viscoelasticity region, revealed significant changes in the rheological behavior of acrylic homopolymer, when compared to an acrylic polymer containing elastomeric particles (core-shell type). It was possible to indicate the miscibility of polymer blends by means of the linear viscoelastic rheological behavior
publishDate 2018
dc.date.issued.fl_str_mv 2018-05
dc.date.accessioned.fl_str_mv 2021-10-04T18:34:06Z
dc.date.available.fl_str_mv 2021-10-04T18:34:06Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.citation.fl_str_mv REINALDO, Juciklécia S.; PEREIRA, Laurenice Martins; SILVA, Erik dos Santos; UEKI, Marcelo M.; ITO, Edson N. Effect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blends. Polymer Testing, [S.L.], v. 67, p. 257-265, maio 2018. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0142941818300412?via%3Dihub. Acesso em: 04 jan. 2021. http://dx.doi.org/10.1016/j.polymertesting.2018.03.013.
dc.identifier.uri.fl_str_mv https://repositorio.ufrn.br/handle/123456789/41542
dc.identifier.issn.none.fl_str_mv 0142-9418
dc.identifier.doi.none.fl_str_mv 10.1016/j.polymertesting.2018.03.013
identifier_str_mv REINALDO, Juciklécia S.; PEREIRA, Laurenice Martins; SILVA, Erik dos Santos; UEKI, Marcelo M.; ITO, Edson N. Effect of the chemical structure on the linear viscoelastic behavior of acrylic and styrenic polymer blends. Polymer Testing, [S.L.], v. 67, p. 257-265, maio 2018. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0142941818300412?via%3Dihub. Acesso em: 04 jan. 2021. http://dx.doi.org/10.1016/j.polymertesting.2018.03.013.
0142-9418
10.1016/j.polymertesting.2018.03.013
url https://repositorio.ufrn.br/handle/123456789/41542
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv Attribution-NonCommercial-NoDerivs 3.0 Brazil
http://creativecommons.org/licenses/by-nc-nd/3.0/br/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivs 3.0 Brazil
http://creativecommons.org/licenses/by-nc-nd/3.0/br/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFRN
instname:Universidade Federal do Rio Grande do Norte (UFRN)
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instname_str Universidade Federal do Rio Grande do Norte (UFRN)
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reponame_str Repositório Institucional da UFRN
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