One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates

Detalhes bibliográficos
Autor(a) principal: Nascimento, Rubens Maribondo do
Data de Publicação: 2013
Outros Autores: Rajesh, Surendran, Macedo, Daniel Araújo de, Souza, Graziele Lopes de, Figueiredo, Filipe Miguel Henriques Lebre Ramos, Marques, Fernando M. B.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRN
Texto Completo: https://repositorio.ufrn.br/handle/123456789/46476
Resumo: Europium-doped ceria (EDC, Ce0.9Eu0.1O2 d)/alkaline carbonate (LNC, (Li,Na)2CO3) composite ceramics prepared through a one-step citrate-based route were analyzed by powder X-ray diffraction, infrared and laser Raman spectroscopies as well as scanning and transmission electron microscopy. The electrochemical behavior of the electrolyte material was studied by impedance spectroscopy in air, CO2 and N2 þ H2 (90/10 vol%, respectively) gas mixtures, in the temperature range 300e600 C. The sub micrometric and even nanosized ceramic particles appeared as merged inside the mixed carbonates, with modest grain to grain necking. The EDC/LNC composite electrolytes showed a conductivity of 0.27 S cm 1 at 600 C in air, amongst the best ever reported, exceeding the usual requirements for fuel cell applications
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spelling Nascimento, Rubens Maribondo doRajesh, SurendranMacedo, Daniel Araújo deSouza, Graziele Lopes deFigueiredo, Filipe Miguel Henriques Lebre RamosMarques, Fernando M. B.2022-03-09T18:57:03Z2022-03-09T18:57:03Z2013-12-13RAJESH, Surendran; MACEDO, Daniel A.; NASCIMENTO, Rubens M.; SOUZA, Graziele L.; FIGUEIREDO, Filipe M. L.; MARQUES, Fernando M. B. One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates. International Journal of Hydrogen Energy, [S.L.], v. 38, n. 36, p. 16539-16545, dez. 2013. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S036031991301286X?via%3Dihub. Acesso em: 08 abr. 2021. http://dx.doi.org/10.1016/j.ijhydene.2013.05.090.0360-3199https://repositorio.ufrn.br/handle/123456789/4647610.1016/j.ijhydene.2013.05.090ElsevierComposite electrolytesCeriaElectrical conductivityOne-step synthesisOne-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonatesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleEuropium-doped ceria (EDC, Ce0.9Eu0.1O2 d)/alkaline carbonate (LNC, (Li,Na)2CO3) composite ceramics prepared through a one-step citrate-based route were analyzed by powder X-ray diffraction, infrared and laser Raman spectroscopies as well as scanning and transmission electron microscopy. The electrochemical behavior of the electrolyte material was studied by impedance spectroscopy in air, CO2 and N2 þ H2 (90/10 vol%, respectively) gas mixtures, in the temperature range 300e600 C. The sub micrometric and even nanosized ceramic particles appeared as merged inside the mixed carbonates, with modest grain to grain necking. The EDC/LNC composite electrolytes showed a conductivity of 0.27 S cm 1 at 600 C in air, amongst the best ever reported, exceeding the usual requirements for fuel cell applicationsengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNinfo:eu-repo/semantics/openAccessCC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/46476/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/46476/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53123456789/464762023-02-07 17:34:09.992oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2023-02-07T20:34:09Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false
dc.title.pt_BR.fl_str_mv One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates
title One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates
spellingShingle One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates
Nascimento, Rubens Maribondo do
Composite electrolytes
Ceria
Electrical conductivity
One-step synthesis
title_short One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates
title_full One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates
title_fullStr One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates
title_full_unstemmed One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates
title_sort One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates
author Nascimento, Rubens Maribondo do
author_facet Nascimento, Rubens Maribondo do
Rajesh, Surendran
Macedo, Daniel Araújo de
Souza, Graziele Lopes de
Figueiredo, Filipe Miguel Henriques Lebre Ramos
Marques, Fernando M. B.
author_role author
author2 Rajesh, Surendran
Macedo, Daniel Araújo de
Souza, Graziele Lopes de
Figueiredo, Filipe Miguel Henriques Lebre Ramos
Marques, Fernando M. B.
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Nascimento, Rubens Maribondo do
Rajesh, Surendran
Macedo, Daniel Araújo de
Souza, Graziele Lopes de
Figueiredo, Filipe Miguel Henriques Lebre Ramos
Marques, Fernando M. B.
dc.subject.por.fl_str_mv Composite electrolytes
Ceria
Electrical conductivity
One-step synthesis
topic Composite electrolytes
Ceria
Electrical conductivity
One-step synthesis
description Europium-doped ceria (EDC, Ce0.9Eu0.1O2 d)/alkaline carbonate (LNC, (Li,Na)2CO3) composite ceramics prepared through a one-step citrate-based route were analyzed by powder X-ray diffraction, infrared and laser Raman spectroscopies as well as scanning and transmission electron microscopy. The electrochemical behavior of the electrolyte material was studied by impedance spectroscopy in air, CO2 and N2 þ H2 (90/10 vol%, respectively) gas mixtures, in the temperature range 300e600 C. The sub micrometric and even nanosized ceramic particles appeared as merged inside the mixed carbonates, with modest grain to grain necking. The EDC/LNC composite electrolytes showed a conductivity of 0.27 S cm 1 at 600 C in air, amongst the best ever reported, exceeding the usual requirements for fuel cell applications
publishDate 2013
dc.date.issued.fl_str_mv 2013-12-13
dc.date.accessioned.fl_str_mv 2022-03-09T18:57:03Z
dc.date.available.fl_str_mv 2022-03-09T18:57:03Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.citation.fl_str_mv RAJESH, Surendran; MACEDO, Daniel A.; NASCIMENTO, Rubens M.; SOUZA, Graziele L.; FIGUEIREDO, Filipe M. L.; MARQUES, Fernando M. B. One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates. International Journal of Hydrogen Energy, [S.L.], v. 38, n. 36, p. 16539-16545, dez. 2013. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S036031991301286X?via%3Dihub. Acesso em: 08 abr. 2021. http://dx.doi.org/10.1016/j.ijhydene.2013.05.090.
dc.identifier.uri.fl_str_mv https://repositorio.ufrn.br/handle/123456789/46476
dc.identifier.issn.none.fl_str_mv 0360-3199
dc.identifier.doi.none.fl_str_mv 10.1016/j.ijhydene.2013.05.090
identifier_str_mv RAJESH, Surendran; MACEDO, Daniel A.; NASCIMENTO, Rubens M.; SOUZA, Graziele L.; FIGUEIREDO, Filipe M. L.; MARQUES, Fernando M. B. One-step synthesis of composite electrolytes of Eu-doped ceria and alkali metal carbonates. International Journal of Hydrogen Energy, [S.L.], v. 38, n. 36, p. 16539-16545, dez. 2013. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S036031991301286X?via%3Dihub. Acesso em: 08 abr. 2021. http://dx.doi.org/10.1016/j.ijhydene.2013.05.090.
0360-3199
10.1016/j.ijhydene.2013.05.090
url https://repositorio.ufrn.br/handle/123456789/46476
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFRN
instname:Universidade Federal do Rio Grande do Norte (UFRN)
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reponame_str Repositório Institucional da UFRN
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