Rheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2 ) composites
Autor(a) principal: | |
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Data de Publicação: | 2014 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/33141 |
Resumo: | The search for new materials with properties suitable for specific applications has increased the number of research studies to fill the market demands. The development of polymer composites by the addition of inorganic fillers to the poly(methyl methacrylate) (PMMA) increases the potential use of this polymer in various application fields. The main objective of this work was to study the rheological and mechanical behavior of composites obtained from the addition of silica in two different types of PMMA matrix: a common (PMMAc) and an elastomeric copolymer (PMMAel). The results showed that the addition of silica particles to the PMMA matrix promoted an increase in torque, a decrease in the melt flow index of composites and an increase in hardness compared to pure polymers. The composites also showed a reduction of the maximum tensile strength for composites with PMMAc matrix and maintenance of tensile strength for composites with PMMAel matrix. The average width of scratch decreased due to a change in wear mechanism, attributed to the increase of hardness in the composites obtained |
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Nascimento, Maria Carolina Burgos Costa doSilva, Erik dos SantosRibeiro, Lourdes AparecidaIto, Edson Noriyuki2021-08-13T18:47:47Z2021-08-13T18:47:47Z2014-08-01SILVA, Erik dos Santos; RIBEIRO, Lourdes Aparecida; NASCIMENTO, Maria Carolina Burgos Costa do; ITO, Edson Noriyuki. Rheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2) composites. Materials Research, [S.L.], v. 17, n. 4, p. 926-932, 1 ago. 2014. Disponível em: https://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392014000400016&lng=en&tlng=en. Acesso em: 05 jan. 2021. http://dx.doi.org/10.1590/s1516-14392014005000114.1516-14391980-5373https://repositorio.ufrn.br/handle/123456789/3314110.1590/1516-1439.253413ABM, ABC, ABPolAttribution-NonCommercial 3.0 Brazilhttp://creativecommons.org/licenses/by-nc/3.0/br/info:eu-repo/semantics/openAccessPolymer compositesPoly (methyl methacrylate)SilicaScratchWearRheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2 ) compositesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleThe search for new materials with properties suitable for specific applications has increased the number of research studies to fill the market demands. The development of polymer composites by the addition of inorganic fillers to the poly(methyl methacrylate) (PMMA) increases the potential use of this polymer in various application fields. The main objective of this work was to study the rheological and mechanical behavior of composites obtained from the addition of silica in two different types of PMMA matrix: a common (PMMAc) and an elastomeric copolymer (PMMAel). The results showed that the addition of silica particles to the PMMA matrix promoted an increase in torque, a decrease in the melt flow index of composites and an increase in hardness compared to pure polymers. The composites also showed a reduction of the maximum tensile strength for composites with PMMAc matrix and maintenance of tensile strength for composites with PMMAel matrix. The average width of scratch decreased due to a change in wear mechanism, attributed to the increase of hardness in the composites obtainedengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALRheologicalMechanicalCharacterization _NASCIMENTO_2015.pdfRheologicalMechanicalCharacterization _NASCIMENTO_2015.pdfapplication/pdf2603755https://repositorio.ufrn.br/bitstream/123456789/33141/1/RheologicalMechanicalCharacterization%20_NASCIMENTO_2015.pdf554b2b705a5747c7e7ef525716f8810dMD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8920https://repositorio.ufrn.br/bitstream/123456789/33141/2/license_rdf728dfda2fa81b274c619d08d1dfc1a03MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/33141/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53123456789/331412021-08-13 15:47:49.338oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-08-13T18:47:49Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Rheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2 ) composites |
title |
Rheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2 ) composites |
spellingShingle |
Rheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2 ) composites Nascimento, Maria Carolina Burgos Costa do Polymer composites Poly (methyl methacrylate) Silica Scratch Wear |
title_short |
Rheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2 ) composites |
title_full |
Rheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2 ) composites |
title_fullStr |
Rheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2 ) composites |
title_full_unstemmed |
Rheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2 ) composites |
title_sort |
Rheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2 ) composites |
author |
Nascimento, Maria Carolina Burgos Costa do |
author_facet |
Nascimento, Maria Carolina Burgos Costa do Silva, Erik dos Santos Ribeiro, Lourdes Aparecida Ito, Edson Noriyuki |
author_role |
author |
author2 |
Silva, Erik dos Santos Ribeiro, Lourdes Aparecida Ito, Edson Noriyuki |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Nascimento, Maria Carolina Burgos Costa do Silva, Erik dos Santos Ribeiro, Lourdes Aparecida Ito, Edson Noriyuki |
dc.subject.por.fl_str_mv |
Polymer composites Poly (methyl methacrylate) Silica Scratch Wear |
topic |
Polymer composites Poly (methyl methacrylate) Silica Scratch Wear |
description |
The search for new materials with properties suitable for specific applications has increased the number of research studies to fill the market demands. The development of polymer composites by the addition of inorganic fillers to the poly(methyl methacrylate) (PMMA) increases the potential use of this polymer in various application fields. The main objective of this work was to study the rheological and mechanical behavior of composites obtained from the addition of silica in two different types of PMMA matrix: a common (PMMAc) and an elastomeric copolymer (PMMAel). The results showed that the addition of silica particles to the PMMA matrix promoted an increase in torque, a decrease in the melt flow index of composites and an increase in hardness compared to pure polymers. The composites also showed a reduction of the maximum tensile strength for composites with PMMAc matrix and maintenance of tensile strength for composites with PMMAel matrix. The average width of scratch decreased due to a change in wear mechanism, attributed to the increase of hardness in the composites obtained |
publishDate |
2014 |
dc.date.issued.fl_str_mv |
2014-08-01 |
dc.date.accessioned.fl_str_mv |
2021-08-13T18:47:47Z |
dc.date.available.fl_str_mv |
2021-08-13T18:47:47Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
SILVA, Erik dos Santos; RIBEIRO, Lourdes Aparecida; NASCIMENTO, Maria Carolina Burgos Costa do; ITO, Edson Noriyuki. Rheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2) composites. Materials Research, [S.L.], v. 17, n. 4, p. 926-932, 1 ago. 2014. Disponível em: https://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392014000400016&lng=en&tlng=en. Acesso em: 05 jan. 2021. http://dx.doi.org/10.1590/s1516-14392014005000114. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/33141 |
dc.identifier.issn.none.fl_str_mv |
1516-1439 1980-5373 |
dc.identifier.doi.none.fl_str_mv |
10.1590/1516-1439.253413 |
identifier_str_mv |
SILVA, Erik dos Santos; RIBEIRO, Lourdes Aparecida; NASCIMENTO, Maria Carolina Burgos Costa do; ITO, Edson Noriyuki. Rheological and mechanical characterization of poly (methyl methacrylate)/silica (PMMA/SiO2) composites. Materials Research, [S.L.], v. 17, n. 4, p. 926-932, 1 ago. 2014. Disponível em: https://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392014000400016&lng=en&tlng=en. Acesso em: 05 jan. 2021. http://dx.doi.org/10.1590/s1516-14392014005000114. 1516-1439 1980-5373 10.1590/1516-1439.253413 |
url |
https://repositorio.ufrn.br/handle/123456789/33141 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
Attribution-NonCommercial 3.0 Brazil http://creativecommons.org/licenses/by-nc/3.0/br/ info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Attribution-NonCommercial 3.0 Brazil http://creativecommons.org/licenses/by-nc/3.0/br/ |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
ABM, ABC, ABPol |
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ABM, ABC, ABPol |
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Universidade Federal do Rio Grande do Norte (UFRN) |
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UFRN |
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UFRN |
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