Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleo
Autor(a) principal: | |
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Data de Publicação: | 2016 |
Tipo de documento: | Trabalho de conclusão de curso |
Idioma: | por |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/38792 |
Resumo: | In the current days, oil and gas still being the principal source of global energy which makes the production field rate of the oil fields around the world near to the decline period. Given the growing interest of the oil industry in optimizing EOR methods, systems at the nanoscale have been widely used as thickening agents and controllers of fluid rheology. It has been proven that the appropriate addition of nanoparticles in the polymer can increase performance of certain systems, viscosity and enhancing the rheological behavior, as well as providing increased thermal and chemical resistance when compared to systems containing only traditional polymers. One factor which favors this recovery is related to improvement in mobility ratio between the displacement fluid and the displaced fluid in relation to conventional recovery with water injection. The objective of this work was the study of the application of polymeric nanoemulsionated systems in enhanced oil recovery. The systems were prepared following the spontaneous method in which the constituents that make up such systems favor its own formation. The constituents used were: a mixture of surfactants, co-surfactant (n-butanol), oil phase (kerosene) and salt polymer aqueous solution (NaCl 3,5% e polyacrylamide 0,08%), resulting in systems with compositions of: 2,0 (Nano1) and 2,5% (Nano2) of surfactant. The systems were characterized with regard to appearance, surface tension, density, pH, particle size, half width and polydispersity index, and rheology. After all the characterization, the system with the composition of 2,5% surfactant (Nano2) was used in an oil recovery test to analyze its potential in EOR. The recovery experiments were performed in a machine that simulates the conditions of an oil reservoir, using plugs of Jandaíra limestone rock and oil from the Potiguar oil field Ubarana. |
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Barros, Ana Tereza Queiroz deAfonso Avelino Dantas NetoChiavone Filho, OsvaldoOliveira, Humberto Maia deDantas, Tereza Neuma de Castro2016-08-10T14:43:03Z2021-09-27T12:21:22Z2016-08-10T14:43:03Z2021-09-27T12:21:22Z2016-02-232010081211BARROS, Ana Tereza Quieroz de. Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleo. 2016. 41f. Trabalho de Conclusão de Curso (Graduação em Engenharia Química), Departamento em Engenharia Química, Universidade Federal do Rio Grande do Norte, Natal, 2016.https://repositorio.ufrn.br/handle/123456789/38792In the current days, oil and gas still being the principal source of global energy which makes the production field rate of the oil fields around the world near to the decline period. Given the growing interest of the oil industry in optimizing EOR methods, systems at the nanoscale have been widely used as thickening agents and controllers of fluid rheology. It has been proven that the appropriate addition of nanoparticles in the polymer can increase performance of certain systems, viscosity and enhancing the rheological behavior, as well as providing increased thermal and chemical resistance when compared to systems containing only traditional polymers. One factor which favors this recovery is related to improvement in mobility ratio between the displacement fluid and the displaced fluid in relation to conventional recovery with water injection. The objective of this work was the study of the application of polymeric nanoemulsionated systems in enhanced oil recovery. The systems were prepared following the spontaneous method in which the constituents that make up such systems favor its own formation. The constituents used were: a mixture of surfactants, co-surfactant (n-butanol), oil phase (kerosene) and salt polymer aqueous solution (NaCl 3,5% e polyacrylamide 0,08%), resulting in systems with compositions of: 2,0 (Nano1) and 2,5% (Nano2) of surfactant. The systems were characterized with regard to appearance, surface tension, density, pH, particle size, half width and polydispersity index, and rheology. After all the characterization, the system with the composition of 2,5% surfactant (Nano2) was used in an oil recovery test to analyze its potential in EOR. The recovery experiments were performed in a machine that simulates the conditions of an oil reservoir, using plugs of Jandaíra limestone rock and oil from the Potiguar oil field Ubarana.Nos dias atuais, óleo e gás continuam sendo a principal fonte global de energia, o que faz com que a taxa de produção dos campos petrolíferos ao redor do mundo esteja próxima ao período de declínio. Dado o crescente interesse da indústria de petróleo na otimização de métodos de EOR, sistemas em nanoescala têm sido utilizados como agentes de espessamento e controladores de reologia. Foi comprovado que a adição apropriada de nanopartículas em polímeros podem melhorar a performance de certos sistemas, sua viscosidade e otimizar o comportamento reológico, assim como providenciar uma melhoria na resistência térmica e química destes sistemas quando comparados a sistemas contendo apenas polímeros. Um dos fatores que favorecem esta recuperação está relacionado com a melhoria do fator de mobilidade entre o fluido deslocante e o fluido deslocado. O objetivo deste trabalho foi o estudo da aplicação de sistemas poliméricos nanoemulsionados na recuperação avançada de petróleo. Os sistemas foram preparados seguindo o método espontâneo, no qual os constituintes que compõem tais sistemas, favorecem sua formação. Os constituintes utilizados foram: uma mistura de surfactantes, co-surfactante (n-butanol), fase óleo (querosene) e solução salina polimérica (NaCl a 3,5% e poliacrilamida a 0,08%), resultando em sistemas com composição de 2,0 (Nano1) e 2,5% (Nano2) de tensoativo. Os sistemas foram caracterizados com respeito à aparência, tensão superficial, densidade, pH, tamanho de partícula, largura à meia altura e índice de polidispersão e reologia. Após todas as caracterizações, o sistema com a composição de 2,5% de tensoativo (Nano 2) foi utilizado no teste de recuperação de petróleo para analisar seu potencial em EOR. Os experimentos foram realizados em um equipamento que simula as condições de um reservatório de petróleo, utilizando plugs de rocha calcária da formação Jandaíra e petróleo do campo Potiguar de Ubarana.PetrobrasUniversidade Federal do Rio Grande do NorteUFRNBrasilEngenharia QuímicaEORInjeção de polímeroNanoemulsõesEngenharias.Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleoPreparation, characterization and application of a polymeric nanoemulsified systems with emphasis on enhanced oil recoveryinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/openAccessporreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNTEXTPreparocaracterizacao_Monografia.txtExtracted texttext/plain78240https://repositorio.ufrn.br/bitstream/123456789/38792/1/Preparocaracterizacao_Monografia.txt12149c9b7cbe33cf950cbb174e84f064MD51ORIGINALPreparocaracterizacao_MonografiaTrabalho de Conclusão de Cursoapplication/octet-stream1091625https://repositorio.ufrn.br/bitstream/123456789/38792/2/Preparocaracterizacao_Monografiaa779cdb4900ec51b3fdedce93ecb7198MD52CC-LICENSElicense_urlapplication/octet-stream46https://repositorio.ufrn.br/bitstream/123456789/38792/3/license_url6f1da3ff281999354d4abd56d1551468MD53license_textapplication/octet-stream0https://repositorio.ufrn.br/bitstream/123456789/38792/4/license_textd41d8cd98f00b204e9800998ecf8427eMD54license_rdfapplication/octet-stream0https://repositorio.ufrn.br/bitstream/123456789/38792/5/license_rdfd41d8cd98f00b204e9800998ecf8427eMD55LICENSElicense.txttext/plain756https://repositorio.ufrn.br/bitstream/123456789/38792/6/license.txta80a9cda2756d355b388cc443c3d8a43MD56123456789/387922021-09-27 09:21:22.805oai:https://repositorio.ufrn.br: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ório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-09-27T12:21:22Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pr_BR.fl_str_mv |
Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleo |
dc.title.alternative.pr_BR.fl_str_mv |
Preparation, characterization and application of a polymeric nanoemulsified systems with emphasis on enhanced oil recovery |
title |
Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleo |
spellingShingle |
Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleo Barros, Ana Tereza Queiroz de EOR Injeção de polímero Nanoemulsões Engenharias. |
title_short |
Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleo |
title_full |
Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleo |
title_fullStr |
Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleo |
title_full_unstemmed |
Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleo |
title_sort |
Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleo |
author |
Barros, Ana Tereza Queiroz de |
author_facet |
Barros, Ana Tereza Queiroz de |
author_role |
author |
dc.contributor.referees2.none.fl_str_mv |
Chiavone Filho, Osvaldo |
dc.contributor.referees3.none.fl_str_mv |
Oliveira, Humberto Maia de |
dc.contributor.author.fl_str_mv |
Barros, Ana Tereza Queiroz de |
dc.contributor.advisor-co1.fl_str_mv |
Afonso Avelino Dantas Neto |
dc.contributor.advisor1.fl_str_mv |
Dantas, Tereza Neuma de Castro |
contributor_str_mv |
Afonso Avelino Dantas Neto Dantas, Tereza Neuma de Castro |
dc.subject.pr_BR.fl_str_mv |
EOR Injeção de polímero Nanoemulsões |
topic |
EOR Injeção de polímero Nanoemulsões Engenharias. |
dc.subject.cnpq.fl_str_mv |
Engenharias. |
description |
In the current days, oil and gas still being the principal source of global energy which makes the production field rate of the oil fields around the world near to the decline period. Given the growing interest of the oil industry in optimizing EOR methods, systems at the nanoscale have been widely used as thickening agents and controllers of fluid rheology. It has been proven that the appropriate addition of nanoparticles in the polymer can increase performance of certain systems, viscosity and enhancing the rheological behavior, as well as providing increased thermal and chemical resistance when compared to systems containing only traditional polymers. One factor which favors this recovery is related to improvement in mobility ratio between the displacement fluid and the displaced fluid in relation to conventional recovery with water injection. The objective of this work was the study of the application of polymeric nanoemulsionated systems in enhanced oil recovery. The systems were prepared following the spontaneous method in which the constituents that make up such systems favor its own formation. The constituents used were: a mixture of surfactants, co-surfactant (n-butanol), oil phase (kerosene) and salt polymer aqueous solution (NaCl 3,5% e polyacrylamide 0,08%), resulting in systems with compositions of: 2,0 (Nano1) and 2,5% (Nano2) of surfactant. The systems were characterized with regard to appearance, surface tension, density, pH, particle size, half width and polydispersity index, and rheology. After all the characterization, the system with the composition of 2,5% surfactant (Nano2) was used in an oil recovery test to analyze its potential in EOR. The recovery experiments were performed in a machine that simulates the conditions of an oil reservoir, using plugs of Jandaíra limestone rock and oil from the Potiguar oil field Ubarana. |
publishDate |
2016 |
dc.date.accessioned.fl_str_mv |
2016-08-10T14:43:03Z 2021-09-27T12:21:22Z |
dc.date.available.fl_str_mv |
2016-08-10T14:43:03Z 2021-09-27T12:21:22Z |
dc.date.issued.fl_str_mv |
2016-02-23 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/bachelorThesis |
format |
bachelorThesis |
status_str |
publishedVersion |
dc.identifier.pr_BR.fl_str_mv |
2010081211 |
dc.identifier.citation.fl_str_mv |
BARROS, Ana Tereza Quieroz de. Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleo. 2016. 41f. Trabalho de Conclusão de Curso (Graduação em Engenharia Química), Departamento em Engenharia Química, Universidade Federal do Rio Grande do Norte, Natal, 2016. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/38792 |
identifier_str_mv |
2010081211 BARROS, Ana Tereza Quieroz de. Preparo, caracterização e aplicação de sistemas poliméricos nanoemulsionados com ênfase em recuperação avançada de petróleo. 2016. 41f. Trabalho de Conclusão de Curso (Graduação em Engenharia Química), Departamento em Engenharia Química, Universidade Federal do Rio Grande do Norte, Natal, 2016. |
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https://repositorio.ufrn.br/handle/123456789/38792 |
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Universidade Federal do Rio Grande do Norte |
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UFRN |
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Brasil |
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Engenharia Química |
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Universidade Federal do Rio Grande do Norte |
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