Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds: Saturated fatty acids

Detalhes bibliográficos
Autor(a) principal: Chiavone Filho, Osvaldo
Data de Publicação: 2012
Outros Autores: Belting, Patrícia Castro, Rarey, Jürgen, Gmehling, Jürgen, Ceriani, Roberta, Meirelles, Antonio José de Almeida
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRN
Texto Completo: https://repositorio.ufrn.br/handle/123456789/44967
Resumo: The activity coefficients at infinite dilution , c113 (the subscript 1 and 3 correspond to solute and solvent, respectively), for 21 solutes, including alkane, cycloalkane, alkene, aromatic compounds, alcohol, ester, ketone, and halogenated hydrocarbons, in four solvents, that are the saturated fatty acids: capric (decanoic) acid, lauric (dodecanoic) acid, myristic (tetradecanoic) acid, and palmitic (hexadecanoic) acid, were determined by gas–liquid chromatography at temperatures from 314.10 K to 358.33 K. Comparison with previously published for selected solutes in palmitic (hexadecanoic) acid were also performed. The values of the partial molar excess Gibbs free energy, DG113, enthalpy, DH113, and entropy, DS113, at infinite dilution were calculated from experimental c113 values obtained over the temperature range. Results obtained in this work allow a more accurate description of the real behavior of fatty systems
id UFRN_a700651dcf94804ccad74da827edd5cb
oai_identifier_str oai:https://repositorio.ufrn.br:123456789/44967
network_acronym_str UFRN
network_name_str Repositório Institucional da UFRN
repository_id_str
spelling Chiavone Filho, OsvaldoBelting, Patrícia CastroRarey, JürgenGmehling, JürgenCeriani, RobertaMeirelles, Antonio José de Almeida2021-11-22T18:53:14Z2021-11-22T18:53:14Z2012-12BELTING, P. C.; RAREY, J.; GMEHLING, J.; CERIANI, R.; CHIAVONE-FILHO, Osvaldo; MEIRELLES, A. J. A. . Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds - Part II: C18 fatty acids. Journal of Chemical Thermodynamics, v. 60, p. 142-149, 2013. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0021961412004661?via%3Dihub Acesso em: 23 jun. 2021. https://doi.org/10.1016/j.jct.2012.06.009.0021-9614https://repositorio.ufrn.br/handle/123456789/4496710.1016/j.jct.2012.06.009ElsevierAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessCapric acidLauric acidMyristic acidPalmitic acidLimiting activity coefficientGas–liquid chromatography methodActivity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds: Saturated fatty acidsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleThe activity coefficients at infinite dilution , c113 (the subscript 1 and 3 correspond to solute and solvent, respectively), for 21 solutes, including alkane, cycloalkane, alkene, aromatic compounds, alcohol, ester, ketone, and halogenated hydrocarbons, in four solvents, that are the saturated fatty acids: capric (decanoic) acid, lauric (dodecanoic) acid, myristic (tetradecanoic) acid, and palmitic (hexadecanoic) acid, were determined by gas–liquid chromatography at temperatures from 314.10 K to 358.33 K. Comparison with previously published for selected solutes in palmitic (hexadecanoic) acid were also performed. The values of the partial molar excess Gibbs free energy, DG113, enthalpy, DH113, and entropy, DS113, at infinite dilution were calculated from experimental c113 values obtained over the temperature range. Results obtained in this work allow a more accurate description of the real behavior of fatty systemsengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNCC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/44967/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52ORIGINALActivityCoefficientInfiniteDilution_ChiavoneFilho_2012 (2).pdfActivityCoefficientInfiniteDilution_ChiavoneFilho_2012 (2).pdfapplication/pdf385188https://repositorio.ufrn.br/bitstream/123456789/44967/1/ActivityCoefficientInfiniteDilution_ChiavoneFilho_2012%20%282%29.pdf35332bb1154ffe8db7817a6472a33fd8MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/44967/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53123456789/449672021-11-22 15:53:16.181oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-11-22T18:53:16Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false
dc.title.pt_BR.fl_str_mv Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds: Saturated fatty acids
title Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds: Saturated fatty acids
spellingShingle Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds: Saturated fatty acids
Chiavone Filho, Osvaldo
Capric acid
Lauric acid
Myristic acid
Palmitic acid
Limiting activity coefficient
Gas–liquid chromatography method
title_short Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds: Saturated fatty acids
title_full Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds: Saturated fatty acids
title_fullStr Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds: Saturated fatty acids
title_full_unstemmed Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds: Saturated fatty acids
title_sort Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds: Saturated fatty acids
author Chiavone Filho, Osvaldo
author_facet Chiavone Filho, Osvaldo
Belting, Patrícia Castro
Rarey, Jürgen
Gmehling, Jürgen
Ceriani, Roberta
Meirelles, Antonio José de Almeida
author_role author
author2 Belting, Patrícia Castro
Rarey, Jürgen
Gmehling, Jürgen
Ceriani, Roberta
Meirelles, Antonio José de Almeida
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Chiavone Filho, Osvaldo
Belting, Patrícia Castro
Rarey, Jürgen
Gmehling, Jürgen
Ceriani, Roberta
Meirelles, Antonio José de Almeida
dc.subject.por.fl_str_mv Capric acid
Lauric acid
Myristic acid
Palmitic acid
Limiting activity coefficient
Gas–liquid chromatography method
topic Capric acid
Lauric acid
Myristic acid
Palmitic acid
Limiting activity coefficient
Gas–liquid chromatography method
description The activity coefficients at infinite dilution , c113 (the subscript 1 and 3 correspond to solute and solvent, respectively), for 21 solutes, including alkane, cycloalkane, alkene, aromatic compounds, alcohol, ester, ketone, and halogenated hydrocarbons, in four solvents, that are the saturated fatty acids: capric (decanoic) acid, lauric (dodecanoic) acid, myristic (tetradecanoic) acid, and palmitic (hexadecanoic) acid, were determined by gas–liquid chromatography at temperatures from 314.10 K to 358.33 K. Comparison with previously published for selected solutes in palmitic (hexadecanoic) acid were also performed. The values of the partial molar excess Gibbs free energy, DG113, enthalpy, DH113, and entropy, DS113, at infinite dilution were calculated from experimental c113 values obtained over the temperature range. Results obtained in this work allow a more accurate description of the real behavior of fatty systems
publishDate 2012
dc.date.issued.fl_str_mv 2012-12
dc.date.accessioned.fl_str_mv 2021-11-22T18:53:14Z
dc.date.available.fl_str_mv 2021-11-22T18:53:14Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.citation.fl_str_mv BELTING, P. C.; RAREY, J.; GMEHLING, J.; CERIANI, R.; CHIAVONE-FILHO, Osvaldo; MEIRELLES, A. J. A. . Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds - Part II: C18 fatty acids. Journal of Chemical Thermodynamics, v. 60, p. 142-149, 2013. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0021961412004661?via%3Dihub Acesso em: 23 jun. 2021. https://doi.org/10.1016/j.jct.2012.06.009.
dc.identifier.uri.fl_str_mv https://repositorio.ufrn.br/handle/123456789/44967
dc.identifier.issn.none.fl_str_mv 0021-9614
dc.identifier.doi.none.fl_str_mv 10.1016/j.jct.2012.06.009
identifier_str_mv BELTING, P. C.; RAREY, J.; GMEHLING, J.; CERIANI, R.; CHIAVONE-FILHO, Osvaldo; MEIRELLES, A. J. A. . Activity coefficient at infinite dilution measurements for organic solutes (polar and non-polar) in fatty compounds - Part II: C18 fatty acids. Journal of Chemical Thermodynamics, v. 60, p. 142-149, 2013. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0021961412004661?via%3Dihub Acesso em: 23 jun. 2021. https://doi.org/10.1016/j.jct.2012.06.009.
0021-9614
10.1016/j.jct.2012.06.009
url https://repositorio.ufrn.br/handle/123456789/44967
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv Attribution 3.0 Brazil
http://creativecommons.org/licenses/by/3.0/br/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution 3.0 Brazil
http://creativecommons.org/licenses/by/3.0/br/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFRN
instname:Universidade Federal do Rio Grande do Norte (UFRN)
instacron:UFRN
instname_str Universidade Federal do Rio Grande do Norte (UFRN)
instacron_str UFRN
institution UFRN
reponame_str Repositório Institucional da UFRN
collection Repositório Institucional da UFRN
bitstream.url.fl_str_mv https://repositorio.ufrn.br/bitstream/123456789/44967/2/license_rdf
https://repositorio.ufrn.br/bitstream/123456789/44967/1/ActivityCoefficientInfiniteDilution_ChiavoneFilho_2012%20%282%29.pdf
https://repositorio.ufrn.br/bitstream/123456789/44967/3/license.txt
bitstream.checksum.fl_str_mv 4d2950bda3d176f570a9f8b328dfbbef
35332bb1154ffe8db7817a6472a33fd8
e9597aa2854d128fd968be5edc8a28d9
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
MD5
repository.name.fl_str_mv Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)
repository.mail.fl_str_mv
_version_ 1814832958483202048

Registros relacionados