Removal study of the hormone17 alpha‐ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin flms
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/31992 |
Resumo: | The disposal of pollutants in the surface, underground, and public water supply is an important problem, which is why it is necessary to study more efcient photocatalysts in the treatment of wastewater. In this context, thin flms of TiO2, Mn2O3 and TiO2/Mn2O3 were prepared by the hydrolysis of precursors in the presence of citric acid and ethylene glycol, to evaluate the photocatalytic performance in the degradation of methylene blue dye and the hormone 17a-ethinylestradiol (EE2), the measurements were repeated 10 times in a period of 300 min. Thin flms were deposited by spin-coating on Si (100) substrates and calcined at 500 °C and 600 °C for 2 h. Nanocomposites were characterized by X-ray difraction, atomic force microscopy, scanning electron microscopy, UV–visible spectroscopy, photocatalytic activity, and photoluminescence. X-ray difraction results revealed that no other phase was formed besides anatase and bixbite, indicating that there was no chemical interaction between the TiO2 and Mn2O3 layers. The results show the degradation values of methylene blue in approximately 57% and for the 17a-ethinylestradiol a degradation around 82%, showing that the studied photocatalysts are promising, mainly for the degradation of 17a-ethinylestradiol |
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Paskocimas, Carlos AlbertoRezende, T. T. A.Garcia, L. M. P.Ferreira, T. L. B.Godinho, M. J.Nascimento, Rubens Maribondo doDelmonte, Maurício Roberto BomioMotta, Fabiana Villela da2021-03-24T14:49:12Z2021-03-24T14:49:12Z2020-05-08REZENDE, T. T. A.; GARCIA, L. M. P.; FERREIRA, T. L. B.; GODINHO, M. J.; NASCIMENTO, R. M.; PASKOCIMAS, C. A.; BOMIO, M. R. D.; MOTTA, F. V.. Removal study of the hormone17 alpha-ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin films. Journal of Materials Science: Materials in Electronics, [S.L.], v. 31, n. 12, p. 9260-9269, 8 maio 2020. Disponível em: https://link.springer.com/article/10.1007%2Fs10854-020-03466-9. Acesso em: 02 dez. 2020. http://dx.doi.org/10.1007/s10854-020-03466-9.0957-45221573-482Xhttps://repositorio.ufrn.br/handle/123456789/3199210.1007/s10854-020-03466-9SpringerAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessHormone17Alpha‐ethynylestradiolMethylene blue dyeTiO2Mn2O3TiO2/Mn2O3Thin flmsRemoval study of the hormone17 alpha‐ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin flmsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleThe disposal of pollutants in the surface, underground, and public water supply is an important problem, which is why it is necessary to study more efcient photocatalysts in the treatment of wastewater. In this context, thin flms of TiO2, Mn2O3 and TiO2/Mn2O3 were prepared by the hydrolysis of precursors in the presence of citric acid and ethylene glycol, to evaluate the photocatalytic performance in the degradation of methylene blue dye and the hormone 17a-ethinylestradiol (EE2), the measurements were repeated 10 times in a period of 300 min. Thin flms were deposited by spin-coating on Si (100) substrates and calcined at 500 °C and 600 °C for 2 h. Nanocomposites were characterized by X-ray difraction, atomic force microscopy, scanning electron microscopy, UV–visible spectroscopy, photocatalytic activity, and photoluminescence. X-ray difraction results revealed that no other phase was formed besides anatase and bixbite, indicating that there was no chemical interaction between the TiO2 and Mn2O3 layers. The results show the degradation values of methylene blue in approximately 57% and for the 17a-ethinylestradiol a degradation around 82%, showing that the studied photocatalysts are promising, mainly for the degradation of 17a-ethinylestradiolengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALRemovalStudyHormone_PASKOCIMAS_2020.pdfRemovalStudyHormone_PASKOCIMAS_2020.pdfapplication/pdf1367831https://repositorio.ufrn.br/bitstream/123456789/31992/1/RemovalStudyHormone_PASKOCIMAS_2020.pdfc8b14400e33dfd6e8456650a6df9647eMD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/31992/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/31992/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53TEXTRemovalStudyHormone_PASKOCIMAS_2020.pdf.txtRemovalStudyHormone_PASKOCIMAS_2020.pdf.txtExtracted texttext/plain38382https://repositorio.ufrn.br/bitstream/123456789/31992/4/RemovalStudyHormone_PASKOCIMAS_2020.pdf.txt0b935c29239bf7a1b95736f7dadc4084MD54THUMBNAILRemovalStudyHormone_PASKOCIMAS_2020.pdf.jpgRemovalStudyHormone_PASKOCIMAS_2020.pdf.jpgGenerated Thumbnailimage/jpeg1864https://repositorio.ufrn.br/bitstream/123456789/31992/5/RemovalStudyHormone_PASKOCIMAS_2020.pdf.jpga52c2a6deca5959ba8ed17c6beb36772MD55123456789/319922021-10-04 17:17:10.953oai:https://repositorio.ufrn.br:123456789/31992Tk9OLUVYQ0xVU0lWRSBESVNUUklCVVRJT04gTElDRU5TRQoKCkJ5IHNpZ25pbmcgYW5kIGRlbGl2ZXJpbmcgdGhpcyBsaWNlbnNlLCBNci4gKGF1dGhvciBvciBjb3B5cmlnaHQgaG9sZGVyKToKCgphKSBHcmFudHMgdGhlIFVuaXZlcnNpZGFkZSBGZWRlcmFsIFJpbyBHcmFuZGUgZG8gTm9ydGUgdGhlIG5vbi1leGNsdXNpdmUgcmlnaHQgb2YKcmVwcm9kdWNlLCBjb252ZXJ0IChhcyBkZWZpbmVkIGJlbG93KSwgY29tbXVuaWNhdGUgYW5kIC8gb3IKZGlzdHJpYnV0ZSB0aGUgZGVsaXZlcmVkIGRvY3VtZW50IChpbmNsdWRpbmcgYWJzdHJhY3QgLyBhYnN0cmFjdCkgaW4KZGlnaXRhbCBvciBwcmludGVkIGZvcm1hdCBhbmQgaW4gYW55IG1lZGl1bS4KCmIpIERlY2xhcmVzIHRoYXQgdGhlIGRvY3VtZW50IHN1Ym1pdHRlZCBpcyBpdHMgb3JpZ2luYWwgd29yaywgYW5kIHRoYXQKeW91IGhhdmUgdGhlIHJpZ2h0IHRvIGdyYW50IHRoZSByaWdodHMgY29udGFpbmVkIGluIHRoaXMgbGljZW5zZS4gRGVjbGFyZXMKdGhhdCB0aGUgZGVsaXZlcnkgb2YgdGhlIGRvY3VtZW50IGRvZXMgbm90IGluZnJpbmdlLCBhcyBmYXIgYXMgaXQgaXMKdGhlIHJpZ2h0cyBvZiBhbnkgb3RoZXIgcGVyc29uIG9yIGVudGl0eS4KCmMpIElmIHRoZSBkb2N1bWVudCBkZWxpdmVyZWQgY29udGFpbnMgbWF0ZXJpYWwgd2hpY2ggZG9lcyBub3QKcmlnaHRzLCBkZWNsYXJlcyB0aGF0IGl0IGhhcyBvYnRhaW5lZCBhdXRob3JpemF0aW9uIGZyb20gdGhlIGhvbGRlciBvZiB0aGUKY29weXJpZ2h0IHRvIGdyYW50IHRoZSBVbml2ZXJzaWRhZGUgRmVkZXJhbCBkbyBSaW8gR3JhbmRlIGRvIE5vcnRlIHRoZSByaWdodHMgcmVxdWlyZWQgYnkgdGhpcyBsaWNlbnNlLCBhbmQgdGhhdCB0aGlzIG1hdGVyaWFsIHdob3NlIHJpZ2h0cyBhcmUgb2YKdGhpcmQgcGFydGllcyBpcyBjbGVhcmx5IGlkZW50aWZpZWQgYW5kIHJlY29nbml6ZWQgaW4gdGhlIHRleHQgb3IKY29udGVudCBvZiB0aGUgZG9jdW1lbnQgZGVsaXZlcmVkLgoKSWYgdGhlIGRvY3VtZW50IHN1Ym1pdHRlZCBpcyBiYXNlZCBvbiBmdW5kZWQgb3Igc3VwcG9ydGVkIHdvcmsKYnkgYW5vdGhlciBpbnN0aXR1dGlvbiBvdGhlciB0aGFuIHRoZSBVbml2ZXJzaWRhZGUgRmVkZXJhbCBkbyBSaW8gR3JhbmRlIGRvIE5vcnRlLCBkZWNsYXJlcyB0aGF0IGl0IGhhcyBmdWxmaWxsZWQgYW55IG9ibGlnYXRpb25zIHJlcXVpcmVkIGJ5IHRoZSByZXNwZWN0aXZlIGFncmVlbWVudCBvciBhZ3JlZW1lbnQuCgpUaGUgVW5pdmVyc2lkYWRlIEZlZGVyYWwgZG8gUmlvIEdyYW5kZSBkbyBOb3J0ZSB3aWxsIGNsZWFybHkgaWRlbnRpZnkgaXRzIG5hbWUgKHMpIGFzIHRoZSBhdXRob3IgKHMpIG9yIGhvbGRlciAocykgb2YgdGhlIGRvY3VtZW50J3MgcmlnaHRzCmRlbGl2ZXJlZCwgYW5kIHdpbGwgbm90IG1ha2UgYW55IGNoYW5nZXMsIG90aGVyIHRoYW4gdGhvc2UgcGVybWl0dGVkIGJ5CnRoaXMgbGljZW5zZQo=Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-10-04T20:17:10Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Removal study of the hormone17 alpha‐ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin flms |
title |
Removal study of the hormone17 alpha‐ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin flms |
spellingShingle |
Removal study of the hormone17 alpha‐ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin flms Paskocimas, Carlos Alberto Hormone17 Alpha‐ethynylestradiol Methylene blue dye TiO2 Mn2O3 TiO2/Mn2O3 Thin flms |
title_short |
Removal study of the hormone17 alpha‐ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin flms |
title_full |
Removal study of the hormone17 alpha‐ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin flms |
title_fullStr |
Removal study of the hormone17 alpha‐ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin flms |
title_full_unstemmed |
Removal study of the hormone17 alpha‐ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin flms |
title_sort |
Removal study of the hormone17 alpha‐ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin flms |
author |
Paskocimas, Carlos Alberto |
author_facet |
Paskocimas, Carlos Alberto Rezende, T. T. A. Garcia, L. M. P. Ferreira, T. L. B. Godinho, M. J. Nascimento, Rubens Maribondo do Delmonte, Maurício Roberto Bomio Motta, Fabiana Villela da |
author_role |
author |
author2 |
Rezende, T. T. A. Garcia, L. M. P. Ferreira, T. L. B. Godinho, M. J. Nascimento, Rubens Maribondo do Delmonte, Maurício Roberto Bomio Motta, Fabiana Villela da |
author2_role |
author author author author author author author |
dc.contributor.author.fl_str_mv |
Paskocimas, Carlos Alberto Rezende, T. T. A. Garcia, L. M. P. Ferreira, T. L. B. Godinho, M. J. Nascimento, Rubens Maribondo do Delmonte, Maurício Roberto Bomio Motta, Fabiana Villela da |
dc.subject.por.fl_str_mv |
Hormone17 Alpha‐ethynylestradiol Methylene blue dye TiO2 Mn2O3 TiO2/Mn2O3 Thin flms |
topic |
Hormone17 Alpha‐ethynylestradiol Methylene blue dye TiO2 Mn2O3 TiO2/Mn2O3 Thin flms |
description |
The disposal of pollutants in the surface, underground, and public water supply is an important problem, which is why it is necessary to study more efcient photocatalysts in the treatment of wastewater. In this context, thin flms of TiO2, Mn2O3 and TiO2/Mn2O3 were prepared by the hydrolysis of precursors in the presence of citric acid and ethylene glycol, to evaluate the photocatalytic performance in the degradation of methylene blue dye and the hormone 17a-ethinylestradiol (EE2), the measurements were repeated 10 times in a period of 300 min. Thin flms were deposited by spin-coating on Si (100) substrates and calcined at 500 °C and 600 °C for 2 h. Nanocomposites were characterized by X-ray difraction, atomic force microscopy, scanning electron microscopy, UV–visible spectroscopy, photocatalytic activity, and photoluminescence. X-ray difraction results revealed that no other phase was formed besides anatase and bixbite, indicating that there was no chemical interaction between the TiO2 and Mn2O3 layers. The results show the degradation values of methylene blue in approximately 57% and for the 17a-ethinylestradiol a degradation around 82%, showing that the studied photocatalysts are promising, mainly for the degradation of 17a-ethinylestradiol |
publishDate |
2020 |
dc.date.issued.fl_str_mv |
2020-05-08 |
dc.date.accessioned.fl_str_mv |
2021-03-24T14:49:12Z |
dc.date.available.fl_str_mv |
2021-03-24T14:49:12Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
REZENDE, T. T. A.; GARCIA, L. M. P.; FERREIRA, T. L. B.; GODINHO, M. J.; NASCIMENTO, R. M.; PASKOCIMAS, C. A.; BOMIO, M. R. D.; MOTTA, F. V.. Removal study of the hormone17 alpha-ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin films. Journal of Materials Science: Materials in Electronics, [S.L.], v. 31, n. 12, p. 9260-9269, 8 maio 2020. Disponível em: https://link.springer.com/article/10.1007%2Fs10854-020-03466-9. Acesso em: 02 dez. 2020. http://dx.doi.org/10.1007/s10854-020-03466-9. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/31992 |
dc.identifier.issn.none.fl_str_mv |
0957-4522 1573-482X |
dc.identifier.doi.none.fl_str_mv |
10.1007/s10854-020-03466-9 |
identifier_str_mv |
REZENDE, T. T. A.; GARCIA, L. M. P.; FERREIRA, T. L. B.; GODINHO, M. J.; NASCIMENTO, R. M.; PASKOCIMAS, C. A.; BOMIO, M. R. D.; MOTTA, F. V.. Removal study of the hormone17 alpha-ethynylestradiol and methylene blue dye from water using TiO2, Mn2O3 and TiO2/Mn2O3 thin films. Journal of Materials Science: Materials in Electronics, [S.L.], v. 31, n. 12, p. 9260-9269, 8 maio 2020. Disponível em: https://link.springer.com/article/10.1007%2Fs10854-020-03466-9. Acesso em: 02 dez. 2020. http://dx.doi.org/10.1007/s10854-020-03466-9. 0957-4522 1573-482X 10.1007/s10854-020-03466-9 |
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https://repositorio.ufrn.br/handle/123456789/31992 |
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eng |
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eng |
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Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ info:eu-repo/semantics/openAccess |
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Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ |
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openAccess |
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Springer |
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Springer |
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