Magnetic Properties of the Granular Alloy Fe10Ag90 as a Function of Annealing Temperature

• Autor(a) principal: Araújo, José Humberto de
• Data de Publicação: 2005
• Outros Autores: Soares, João Maria, Cabral, Francisco de Assis Olímpio, Dumelow, Thomas, Xavier Júnior, Milton Morais, Sasaki, José Marcos
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Institucional da UFRN
• Texto Completo: https://repositorio.ufrn.br/jspui/handle/123456789/28984
• topic: Superparamagnetism; Granular alloy; Size distribution

Fe10Ag90 granular alloys have been prepared using a sol-gel process, sintered at 300 °C and annealed at temperatures between 400 °C and 700 °C. The mean size of the iron particles, obtained from X-ray diffraction, is 30.0 ± 0.7 nm. Due to the existence of a distribution of particle sizes in these samples, both blocked (BL) and superparamagnetic (SPM) particles are present simultaneously, as confirmed by magnetization measurements at room temperature. AC susceptibility measurements as a function of temperature reveal a magnetic phase transition at about 770 °C, indicating the presence of particles exhibiting bulk behavior, in the samples annealed above 550 °C. The presence of these particles has been attributed to an atomic diffusion process between the grains, forming bulk-like multiple-domain Fe particles having Curie temperatures near that of bulk a-Fe phase (TC = 770 °C).