Avaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleo

Detalhes bibliográficos
Autor(a) principal: Oliveira, Andrey Costa de
Data de Publicação: 2015
Tipo de documento: Trabalho de conclusão de curso
Idioma: por
Título da fonte: Repositório Institucional da UFRN
Texto Completo: https://repositorio.ufrn.br/handle/123456789/38330
Resumo: One of the main reasons that led to the development of technologies for oil recovery is the low percentage of naturally produced oil, i.e. so that the oil well itself, by pressure differential, reaches the surface. Over time, the pressure that causes the oil reach the surface decreases, leaving much of the hydrocarbons in the well. Because of this, it is important to use conventional and advanced recovery methods. This study has as objective the application of surfactant, microemulsion and nanoemulsion as advanced method in order to remove as many as possible of the remaining oil in the reservoir. The surfactant used is nonionic and liquid. Tests were performed to determine the critical micelle concentration (c.m.c.). It was also done the ternary diagram, built with components: butanol, kerosene and distilled water. The microemulsion point to be applied was chosen in a stable region of Winsor IV and with a high percentage of the aqueous phase. The nanoemulsion was obtained from a microemulsion point, the method used was the infinite dilution. Once defined the microemulsion and nanoemulsion point to be worked, the systems (microemulsion, nanoemulsion and surfactant solution) were characterized by surface tension, interfacial tense, particle diameter, polydispersity, density and viscosity. Finally, the systems were applied to oil recovery tests to determine their effect on advanced recovery. The tests were done in a reservoir Simulator with controlled temperatures and pressures, where it was possible to calculate the percentage of the injected fluid recovery to move the oil impregnated in the pores of the rock and the efficiency of the ending offset. Because the characteristics of systems that determine the interactions occurring in the reservoir, was observed that the microemulsion had the best oil recovery, with 85% of oil recovered, followed by the nanoemulsion and surfactant solution, with 70% and 60% of oil recovered, respectively.
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spelling Oliveira, Andrey Costa deTamyris Thaise Costa de SouzaSoares, Ana Paula JustinoMedeiros, Ana Catarina da RochaDantas, Tereza Neuma de Castro2016-09-21T19:26:52Z2021-09-27T11:47:42Z2016-09-21T19:26:52Z2021-09-27T11:47:42Z2015-12-212012960381OLIVEIRA, Andrey Costa de. Avaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleo. 2015. 63f. Trabalho de Conclusão de Curso (Graduação em Química do Petróleo), Instituto de Química, Universidade Federal do Rio Grande do Norte, Natal, 2015.https://repositorio.ufrn.br/handle/123456789/38330One of the main reasons that led to the development of technologies for oil recovery is the low percentage of naturally produced oil, i.e. so that the oil well itself, by pressure differential, reaches the surface. Over time, the pressure that causes the oil reach the surface decreases, leaving much of the hydrocarbons in the well. Because of this, it is important to use conventional and advanced recovery methods. This study has as objective the application of surfactant, microemulsion and nanoemulsion as advanced method in order to remove as many as possible of the remaining oil in the reservoir. The surfactant used is nonionic and liquid. Tests were performed to determine the critical micelle concentration (c.m.c.). It was also done the ternary diagram, built with components: butanol, kerosene and distilled water. The microemulsion point to be applied was chosen in a stable region of Winsor IV and with a high percentage of the aqueous phase. The nanoemulsion was obtained from a microemulsion point, the method used was the infinite dilution. Once defined the microemulsion and nanoemulsion point to be worked, the systems (microemulsion, nanoemulsion and surfactant solution) were characterized by surface tension, interfacial tense, particle diameter, polydispersity, density and viscosity. Finally, the systems were applied to oil recovery tests to determine their effect on advanced recovery. The tests were done in a reservoir Simulator with controlled temperatures and pressures, where it was possible to calculate the percentage of the injected fluid recovery to move the oil impregnated in the pores of the rock and the efficiency of the ending offset. Because the characteristics of systems that determine the interactions occurring in the reservoir, was observed that the microemulsion had the best oil recovery, with 85% of oil recovered, followed by the nanoemulsion and surfactant solution, with 70% and 60% of oil recovered, respectively.Um dos principais motivos que levou ao desenvolvimento de tecnologias para recuperação de petróleo é a baixa porcentagem de petróleo produzido de forma natural, ou seja, de forma que o próprio reservatório, por diferencial de pressão, faça com que este óleo chegue a superfície. Pois, ao passar do tempo, essa pressão que faz com que o petróleo alcance a superfície diminui, deixando grande parte do hidrocarboneto ainda dentro do poço. Em virtude disto, faz-se uso dos métodos de recuperação convencional e avançado. Esse trabalho tem como objetivo a aplicação de tensoativo em solução, sistemas microemulsionados e nanoemulsionados, como método avançado, afim de retirar a maior quantidade possível do petróleo remanescente no reservatório. O tensoativo utilizado é comercial de caráter não iônico e o seu estado físico é liquido. Foi realizado ensaio para determinar a concentração micelar crítica (c.m.c.) deste. Também foi obtido diagrama pseudoternário, construído com os componentes: butanol (cotensoativo), tensoativo, querosene (fase óleo) e água (fase aquosa), onde o ponto de microemulsão a ser aplicado foi escolhido na região de Winsor IV e com elevado percentual de fase aquosa. A nanoemulsão foi obtida a partir de um ponto microemulsionado, pelo método de diluição infinita. Uma vez definido todos os sistemas (microemulsão, nanoemulsão e solução de tensoativo) a serem trabalhados, estes foram caracterizados por tensão superficial, tensão interfacial, diâmetro de partícula e índice de polidispersão, viscosidade e densidade, todos os ensaios a temperatura de 25ºC. Por fim, os sistemas foram aplicados a ensaios de recuperação de petróleo com o objetivo de determinar o seu efeito sobre a recuperação avançada. Os testes foram feitos em um simulador de reservatório com temperaturas e pressões controladas, onde foi possível calcular o percentual de recuperação do fluido injetado para deslocar o óleo impregnado nos poros da rocha e a eficiência do deslocamento final. Devido as características dos sistemas, que determinam as interações ocorridas no reservatório, observou-se que aquele que apresentou maior poder de deslocamento foi a microemulsão, 85% de óleo deslocado, seguido pela nanoemulsão e a solução de tensoativo alcançando 70% e 60% de recuperação total de petróleo, respectivamente.Universidade Federal do Rio Grande do NorteUFRNBrasilQuímica do PetróleoTensoativoMicroemulsãoNanoemulsãoRecuperação avançada de petróleoSurfactantMicroemulsionSurfactantMicroemulsionNanoemulsionAdvanced oil recoveryQuímica de InterfacesAvaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleoinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/openAccessporreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNTEXTAvaliacaoAplicacaoMicroemulsao_Oliveira_2015.pdf.txtExtracted texttext/plain114727https://repositorio.ufrn.br/bitstream/123456789/38330/1/AvaliacaoAplicacaoMicroemulsao_Oliveira_2015.pdf.txt17b34cd2a5fea33020af654ccfd89985MD51ORIGINALAvaliacaoAplicacaoMicroemulsao_Oliveira_2015.pdfapplication/pdf1315461https://repositorio.ufrn.br/bitstream/123456789/38330/2/AvaliacaoAplicacaoMicroemulsao_Oliveira_2015.pdf07a2bfc47687ddb7c28a925233e4e916MD52LICENSElicense.txttext/plain756https://repositorio.ufrn.br/bitstream/123456789/38330/3/license.txta80a9cda2756d355b388cc443c3d8a43MD53123456789/383302023-05-17 10:48:53.777oai:https://repositorio.ufrn.br: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ório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2023-05-17T13:48:53Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false
dc.title.pr_BR.fl_str_mv Avaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleo
title Avaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleo
spellingShingle Avaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleo
Oliveira, Andrey Costa de
Tensoativo
Microemulsão
Nanoemulsão
Recuperação avançada de petróleo
Surfactant
Microemulsion
Surfactant
Microemulsion
Nanoemulsion
Advanced oil recovery
Química de Interfaces
title_short Avaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleo
title_full Avaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleo
title_fullStr Avaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleo
title_full_unstemmed Avaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleo
title_sort Avaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleo
author Oliveira, Andrey Costa de
author_facet Oliveira, Andrey Costa de
author_role author
dc.contributor.referees1.none.fl_str_mv Soares, Ana Paula Justino
dc.contributor.referees2.none.fl_str_mv Medeiros, Ana Catarina da Rocha
dc.contributor.author.fl_str_mv Oliveira, Andrey Costa de
dc.contributor.advisor-co1.fl_str_mv Tamyris Thaise Costa de Souza
dc.contributor.advisor1.fl_str_mv Dantas, Tereza Neuma de Castro
contributor_str_mv Tamyris Thaise Costa de Souza
Dantas, Tereza Neuma de Castro
dc.subject.pr_BR.fl_str_mv Tensoativo
Microemulsão
Nanoemulsão
Recuperação avançada de petróleo
Surfactant
Microemulsion
Surfactant
Microemulsion
Nanoemulsion
Advanced oil recovery
topic Tensoativo
Microemulsão
Nanoemulsão
Recuperação avançada de petróleo
Surfactant
Microemulsion
Surfactant
Microemulsion
Nanoemulsion
Advanced oil recovery
Química de Interfaces
dc.subject.cnpq.fl_str_mv Química de Interfaces
description One of the main reasons that led to the development of technologies for oil recovery is the low percentage of naturally produced oil, i.e. so that the oil well itself, by pressure differential, reaches the surface. Over time, the pressure that causes the oil reach the surface decreases, leaving much of the hydrocarbons in the well. Because of this, it is important to use conventional and advanced recovery methods. This study has as objective the application of surfactant, microemulsion and nanoemulsion as advanced method in order to remove as many as possible of the remaining oil in the reservoir. The surfactant used is nonionic and liquid. Tests were performed to determine the critical micelle concentration (c.m.c.). It was also done the ternary diagram, built with components: butanol, kerosene and distilled water. The microemulsion point to be applied was chosen in a stable region of Winsor IV and with a high percentage of the aqueous phase. The nanoemulsion was obtained from a microemulsion point, the method used was the infinite dilution. Once defined the microemulsion and nanoemulsion point to be worked, the systems (microemulsion, nanoemulsion and surfactant solution) were characterized by surface tension, interfacial tense, particle diameter, polydispersity, density and viscosity. Finally, the systems were applied to oil recovery tests to determine their effect on advanced recovery. The tests were done in a reservoir Simulator with controlled temperatures and pressures, where it was possible to calculate the percentage of the injected fluid recovery to move the oil impregnated in the pores of the rock and the efficiency of the ending offset. Because the characteristics of systems that determine the interactions occurring in the reservoir, was observed that the microemulsion had the best oil recovery, with 85% of oil recovered, followed by the nanoemulsion and surfactant solution, with 70% and 60% of oil recovered, respectively.
publishDate 2015
dc.date.issued.fl_str_mv 2015-12-21
dc.date.accessioned.fl_str_mv 2016-09-21T19:26:52Z
2021-09-27T11:47:42Z
dc.date.available.fl_str_mv 2016-09-21T19:26:52Z
2021-09-27T11:47:42Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/bachelorThesis
format bachelorThesis
status_str publishedVersion
dc.identifier.pr_BR.fl_str_mv 2012960381
dc.identifier.citation.fl_str_mv OLIVEIRA, Andrey Costa de. Avaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleo. 2015. 63f. Trabalho de Conclusão de Curso (Graduação em Química do Petróleo), Instituto de Química, Universidade Federal do Rio Grande do Norte, Natal, 2015.
dc.identifier.uri.fl_str_mv https://repositorio.ufrn.br/handle/123456789/38330
identifier_str_mv 2012960381
OLIVEIRA, Andrey Costa de. Avaliação da aplicação de microemulsão, nanoemulsão e solução de tensoativo na recuperação avançada de petróleo. 2015. 63f. Trabalho de Conclusão de Curso (Graduação em Química do Petróleo), Instituto de Química, Universidade Federal do Rio Grande do Norte, Natal, 2015.
url https://repositorio.ufrn.br/handle/123456789/38330
dc.language.iso.fl_str_mv por
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dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
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dc.publisher.none.fl_str_mv Universidade Federal do Rio Grande do Norte
dc.publisher.initials.fl_str_mv UFRN
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv Química do Petróleo
publisher.none.fl_str_mv Universidade Federal do Rio Grande do Norte
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFRN
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